998 resultados para 201-1228A


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Early diagenetic dolomite beds were sampled during the Ocean Drilling Programme (ODP) Leg 201 at four reoccupied ODP Leg 112 sites on the Peru continental margin (Sites 1227/684, 1228/680, 1229/681 and 1230/685) and analysed for petrography, mineralogy, d13C, d18O and 87Sr/86Sr values. The results are compared with the chemistry, and d13C and 87Sr/86Sr values of the associated porewater. Petrographic relationships indicate that dolomite forms as a primary precipitate in porous diatom ooze and siliciclastic sediment and is not replacing the small amounts of precursor carbonate. Dolomite precipitation often pre-dates the formation of framboidal pyrite. Most dolomite layers show 87Sr/86Sr-ratios similar to the composition of Quaternary seawater and do not indicate a contribution from the hypersaline brine, which is present at a greater burial depth. Also, the d13C values of the dolomite are not in equilibrium with the d13C values of the dissolved inorganic carbon in the associated modern porewater. Both petrography and 87Sr/86Sr ratios suggest a shallow depth of dolomite formation in the uppermost sediment (<30 m below the seafloor). A significant depletion in the dissolved Mg and Ca in the porewater constrains the present site of dolomite precipitation, which co-occurs with a sharp increase in alkalinity and microbial cell concentration at the sulphate-methane interface. It has been hypothesized that microbial 'hot-spots', such as the sulphate-methane interface, may act as focused sites of dolomite precipitation. Varying d13C values from -15 per mil to +15 per mil for the dolomite are consistent with precipitation at a dynamic sulphate-methane interface, where d13C of the dissolved inorganic carbon would likewise be variable. A dynamic deep biosphere with upward and downward migration of the sulphate-methane interface can be simulated using a simple numerical diffusion model for sulphate concentration in a sedimentary sequence with variable input of organic matter. Thus, the study of dolomite layers in ancient organic carbon-rich sedimentary sequences can provide a useful window into the palaeo-dynamics of the deep biosphere.

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Organic matter deposited and buried under the seafloor is one of the major carbon sources for microbial life in the deep subsurface of the ocean. In this report, we present a compilation of all available total organic carbon (TOC) and total inorganic carbon (TIC) data for the sites drilled during Ocean Drilling Program (ODP) Leg 201. We include the TOC and TIC data from sites of Deep Sea Drilling (DSDP) Leg 34 and ODP Legs 112 and 138 (Yeats, Hart, et al., 1976, doi:10.2973/dsdp.proc.34.1976; Suess, von Huene, et al., 1988, doi:10.2973/odp.proc.ir.112.1988; Mayer, Pisias, Janecek, et al., 1992, doi:10.2973/odp.proc.ir.138.1992), which were reoccupied during ODP Leg 201. Additional data from Leg 201 shore-based analyses are also included in the compilation.

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The first experimentally determined temperature dependent oxygen-18 fractionation factor between dolomite and water at low temperatures [Vasconcelos et al. 1995 doi:10.1130/G20992.1] allows now the precise calculation of temperatures during early diagenetic dolomite precipitation. We use d18O values of early diagenetic dolomite beds sampled during ODP Legs 112 and 201 on the Peru continental margin (Sites 1227, 1228 and 1229) [Meister et al. 2007, doi:10.1111/j.1365-3091.2007.00870.x] to calculate paleo-porewater temperatures at the time of dolomite precipitation. We assumed unaltered seawater d18O values in the porewater, which is supported by d18O values of the modern porewater presented in this study. The dolomite layers in the Pleistocene part of the sedimentary columns showed oxygen isotope temperatures up to 5 °C lower than today. Since Sites 1228 and 1229 are located at 150 and 250 m below sealevel, respectively, their paleo-porewater temperatures would be influenced by considerably colder surface water during glacial sealevel lowstands. Thus, Pleistocene dolomite layers in the Peru Continental margin probably formed during glacial times. This finding is consistent with a model for dolomite precipitation in the Peru Margin recently discussed by Meister et al. [Meister et al. 2007, doi:10.1111/j.1365-3091.2007.00870.x], where dolomite forms episodically at the sulphate methane interface. It was shown that the sulphate methane interface migrates upwards and downwards within the sedimentary column, but dolomite layers may only form when the sulphate-methane interface stays at a fixed depth for a sufficient amount of time. We hypothesize that the sulphate-methane interface persists within TOC-rich interglacial sediments, while this zone is buried by TOC-poor sedimentation during glacial times. Thus, the presented oxygen isotope data provide additional information on the timing of early diagenetic dolomite formation and a possible link between episodicity in dolomite formation and sealevel variations. A similar link between early diagenesis and oceanography may also explain spacing of dolomite layers in a Milankovitch type pattern observed in the geological record, such as in the Miocene Monterey Formation.

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Contenido: El aristotelismo y el tomismo frente al egoísmo psicológico / María L. Lukac de Stier – El deseo natural de ver a Dios en la Summa contra Gentiles / Guillermo Jorge Cambiasso – La creación como encuentro del ser y de la nada en la teología del maestro Eckhart de Hochheim O.P. (1260-1327) / Brian J. Farrelly – Malebranche y el libertinage érudit / Francisco Leocata – The problem of person and Jean Mouroux / John M. McDermott ; Glenn J. Comandini – Los fundamentos de la Bioética de H. Tristram Engelhardt / Jorge Martínez Barrera – Cuando las contradictorias son verdaderas / Marisa Villalba de Tablón – Examen del escepticismo moral y del relativismo moral / Camilo Tale – Saint Thomas et le mystère de la création : une réponse aux interrogations de l’homme d’aujourd’hui / Marie-Dominique Philippe – La finalidad de la naturaleza humana : alcance y actualidad de la cuestión / Beatriz Eugenia Reyes Oribe – La providencia y el gobierno del mundo / Alberto Caturelli – Saint Thomas et le problème de la possibilité d’un univers créé éternel / Alain-Marie de Lassus – La causalidad material de los elementos en la generación de los cuerpos mixtos / Mario Enrique Sacchi -- Bibliografía

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Consultoria Legislativa - Área I - Direito Constitucional, Eleitoral, Municipal, Direito Administrativo, Processo Legislativo e Poder Judiciário.

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No Plenário da Assembleia Nacional Constituinte (ANC), discussão de emendas populares que tratam dos direitos e da aposentadoria dos trabalhadores e da reforma urbana. O representante da Arquidiocese do Rio de Janeiro, Carlos Roberto Castro, defende uma emenda em favor do usucapião nas favelas cariocas, após cinco anos, e em terrenos urbanos abandonados, após dois anos. Adib Jorge, representante sindical, defende emenda popular que prevê aposentadoria mais justa aos trabalhadores. O Deputado Farabulini Júnior (PTB-SP) defende a paridade dos salários entre os trabalhadores da ativa e os aposentados e pensionistas. Em nome da CUT (Central Única dos Trabalhadores), o Deputado Paulo Paim (PT-RS) fala em defesa da emenda popular dos direitos dos trabalhadores e declara que o eixo dessa emenda é a estabilidade no emprego, as quarenta horas semanais e o direito de greve. Na próxima Sessão Extraordinária serão discutidas emendas populares que tratam da estabilidade no emprego, participação nos lucros e democratização da administração das empresas, reforma urbana, transporte coletivo e moradia popular. O projeto de Constituição do Relator Bernardo Cabral permite o pluralismo sindical. O Deputado Juarez Antunes (PDT-RJ) considera que o pluralismo sindical só favorece a classe empresarial. Marival Campos, Presidente do Sindicato dos Petroleiros-BA, informa que é uma tentativa do patronato de dividir os trabalhadores cada vez mais. Luiz Machado, Presidente do Sindicato dos Urbanitários-RJ, afirma que será desenvolvido um trabalho junto aos parlamentares para que esse dispositivo não seja aprovado. O Deputado Mario Lima (PMDB-BA) informa que só deve haver um sindicato de cada categoria em cada base territorial. O Deputado Afif Domingos (PL-SP) considera que nada impede a coexistência de mais de um sindicato dentro da mesma base, contanto que apenas um seja o representante nos dissídios da categoria perante a lei. O Deputado Paes Landim (PFL-PI) afirma que tanto faz a unicidade ou pluralismo, desde que os sindicatos tenham liberdade e possam atuar livres da interferência do Estado. O Deputado Augusto Carvalho (PCB-DF) declara que só se os trabalhadores se unirem em um único sindicato terão força suficiente para poder enfrentar o patronato.