Distribution of tripylean radiolarians from ODP Leg 114 (Table 2)

The occurrence of tripylean radiolarians is reported for the first time from subsurface sediments of the subantarctic Atlantic Ocean. Although their occurrence is rare as well as sporadic, seven species belonging to four genera are recognized from Upper Cenozoic sediments drilled at Sites 699, 700, and 701 of ODP Leg 114 in 1987.

Pore-water chemistry of ODP Leg 114 holes

Pore-water samples were recovered at five sites from ODP Leg 114 in the subantarctic South Atlantic Ocean and analyzed for pH, alkalinity, chloride, sulfate, fluoride, silica, magnesium, calcium, strontium, potassium, lithium, and barium. At sites in the East Georgia Basin and on the Islas Orcadas Rise, Ca increases and Mg decreases linearly downhole with a DeltaMg/DeltaCa ratio reflecting conservative diffusive exchange and basalt basement reactions. At sites on the west flank of the Mid-Atlantic Ridge and on the Meteor Rise, Ca gradients are nonlinear, and nonconservative DeltaMg/DeltaCa ratios reflect alteration reactions of abundant silicic volcanic ash in the sediment. K decreases linearly downhole at all sites, reflecting uptake by basement and the absence of significant sediment-hosted reactions. SO4 decreases and alkalinity increases downhole are due to a slight sulfate reduction at all sites except at Site 701. Sr increases downhole at all sites except Site 701, with DeltaSr/DeltaCa ratios reflecting diffusive exchange with basement. At Site 704 on the Meteor Rise, there is intense Sr production during carbonate recrystallization in the upper 200 mbsf. Below 200 mbsf at Site 704, the ion concentration product of SrSO4 is constant, suggesting Sr control by celestite solubility. Li and F concentrations display complex behavior related to sedimentary reactions, probably calcite recrystallization (Li uptake and F release).

Trace element concentrations and Li isotope composition in DSDP and ODP sediments from island arcs

We have studied the sedimentary and basaltic inputs of lithium to subduction zones. Various sediments from DSDP and ODP drill cores in front of the Mariana, South Sandwich, Banda, East Sunda and Lesser Antilles island arcs have been analysed and show highly variable Li contents and d7Li values. The sediment piles in front of the Mariana and South Sandwich arcs largely consist of pelagic sediments (clays and oozes). The pelagic clays have high Li contents (up to 57.3 ppm) and Li isotope compositions ranging from +1.3? to +4.1?. The oozes have lower Li contents (7.3-16 ppm) with d7Li values of the diatom oozes from the South Sandwich lower (+2.8? to +3.2?) than those of the radiolarian oozes from the Mariana arc (+8.1? to +14.5?). Mariana sediment also contains a significant portion of volcanogenic material, which is characterised by a moderate Li content (14 ppm) and a relatively heavy isotope composition (+6.4?). Sediments from the Banda and Lesser Antilles contain considerable amounts of continental detritus, and have high Li contents (up to 74.3 ppm) and low d7Li values (around 0?), caused by weathering of continental bedrock. East Sunda sediments largely consist of calcareous oozes. These carbonate sediments display intermediate to high Li contents (2.4-41.9 ppm) and highly variable d7Li values (-1.6? to +12.8?). Basaltic oceanic crust samples from worldwide DSDP and ODP drill cores are characterised by enrichment of Li compared to fresh MORB (6.6-33.1 vs. 3.6-7.5 ppm, respectively), and show a large range in Li isotope compositions (+1.7? to +11.8?). The elemental and isotopic enrichment of Li in altered basalts is due to the uptake of isotopically heavy seawater Li during weathering. However, old oceanic crust samples from Sites 417/418 exhibit lighter Li isotope compositions compared to young basaltic crust samples from Sites 332B and 504B. This lighter Li isotope signature in old crust is unexpected and further research is needed to explore this issue.

Siliceous components of Pliocene-Holocene sediments of the South Atlantic

The Pliocene-Holocene sediments recovered on ODP Leg 114 from Holes 699A, 701C, and 704B are the subject of a detailed investigation to interpret changes in the Oceanographic environment of the South Atlantic in the vicinity of the Polar Front Zone (PFZ). The cores sample sediments at shallow (Hole 704B, 2532 m), intermediate (Hole 699A, 3716 m), and basinal (Hole 701C, 4647 m) depths. Sites 699 and 704 come under the influence of the Antarctic Circumpolar Current (ACC) and Circumpolar Deep Water. It is possible that the upper reaches of Antarctic Bottom Water (AABW) may also affect Hole 699A. Site 701 is influenced by AABW. Closely spaced samples were analyzed for grain-size distribution, sand fraction components, biosiliceous microfossils, organic carbon, and water content. PFZ migrations are traced using changes in bulk sedimentaccumulation rates and the abundance of the diatoms Actiniscus ssp. and Genus et species indet. 1 Fenner (1991), as well as changes in sediment grain size and composition. Diatomaceous sediments of Gilbert age in Hole 699A indicate that the PFZ was positioned over this site, but during the Gauss it migrated north, bringing in less productive Antarctic Surface Water. All cores document a very gradual southerly movement of the PFZ throughout the Matuyama (with some sharp fluctuations of the northen PFZ border over Site 704 between 1.45 and 1.83 m.y.). This regressive shift culminated in the late Matuyama. The latest Matuyama to earliest Brunhes record in Hole 699A has been removed by a hiatus lasting from 1.0 to 0.6 m.y., which was probably caused by intensification of the deep-reaching ACC. The corresponding interval in Hole 704B, the shallowest core, contains evidence of winnowing. Sharp fluctuations of large amplitude and high frequency in the lithology of the sediments from Hole 704B in the eastern South Atlantic, starting at about 0.75 m.y. and characterizing the whole Brunhes Epoch, record the rapid movement of the northern border of the PFZ over the site. These reflect strong glacial/interglacial alternations in climate. To a lesser extent, lithologic fluctuations in Hole 701C reflect the same phenomenon, whereas in Hole 699A the lithology does not vary as dramatically.

Late Miocene to Holocene planktonic foraminifers from the subantarctic South Atlantic

Late Miocene to Holocene planktonic foraminifers from the subantarctic South Atlantic were investigated for their biostratigraphic and environmental significance. The calcareous planktonic microfauna are of low diversity and are very rare or absent at sites located below the CCD. The sediments recovered from Sites 703 and 704 on the Meteor Rise at about 47°S are useful for biostratigraphic and environmental studies. In the whole sequence 16 species or varieties of planktonic foraminifers were recognized. Two species occur in the uppermost Miocene. In the Pliocene the Globorotalia puncticulata population can be used to separate the early from the late Pliocene. The Pliocene/Quaternary boundary does not appear to be well distinguished in the foraminiferal assemblage. A faunal change noted at 2.5 Ma could correspond to the development of glaciation in the Northern Hemisphere and its Antarctic counterpart. At about 5.2 Ma the first increase in polar fauna near the Meteor Rise occurs. Two other cooling periods are indicated in these sequences at about 4 and 3 Ma. Moreover, the hydrologic environment became more productive at about 2.1 Ma and close to the Brunhes/Matuyama boundary.