Contaminação das águas subterrâneas por resíduos de postos de combustíveis: uma abordagem no município de Rio Claro

The contamination of underground waters is a subject of great importance, since a lot of people use this kind of source for public supply. This paperwork manages with how gas stations can contaminate these waters and what are some remediation techniques, used nowadays to solve this problem. The contamination caused by the gas stations can have its origin in the underground storage tanks when they suffer corrosion and show leaking problems. It’s a topic of great relevance, because the hydrocarbons derivated from petroleum present in the fuels can stay for a long time in the environment. Besides that, an analyses of the risk of contamination by gas stations in the city of Rio Claro was made based on three parameters: density of the gas stations, depth of the underground water and hydraulic conductivity. To achieve such goal, maps were elaborated considering those parameters individually and considering the three of them together. Analyzing those maps, it was concluded see that the spots that represent the biggest risks of contamination in Rio Claro are located southeast and center-west.

Classificação hidroquímica das águas subterrâneas do Aquífero Serra Geral na porção centro norte do estado de São Paulo

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Simulação numérica de fluxo de águas subterrâneas na bacia do Rio Grande (BA)

The Urucuia Aquifer System represents a strategic water source in western Bahia. Its baseflow is responsible for the flow rate of the main tributaries of São Francisco river left bank in the dry season, including the Rio Grande, its main tributary in Bahia state. This river has a hydrological regime heavily affected by groundwater and is located in a region with conflicts about water resources. The aquifers geology is constituted by neocretacious sandstones of Urucuia Group subdivided in Posse Formation and Serra das Araras Formation. The embasement is formed by neoproterozoic rocks of Bambuí Group. This work focuses on an important tool application, the mathematical model, whose function is represent approximately and suitably the reality so that can assist in different scenarios simulations and make predictions. Many studies developed in this basin provided the conceptual model basis including a full free aquifer, lithological and hydraulical homogeneity in entire basin, null flux at plateau borders and aquifer base. The finite element method is the numerical method used and FEFLOW the computational algorithm. The simulated area was discretized in a single layer with 27.357,6 km² (314.432 elements and 320.452 nodes) totaling a 4.249,89 km³ volume. Were utilized 21 observation wells from CERB to calibrate the model. The terrain topography was obtained by SRTM data and the impermeable base was generated by interpolation of descriptive profiles from wells and electric vertical drilling from previous studies. Works in this area obtained mean recharge rates varying approximately from 20% to 25% of average precipitation, thus the values of model recharge zones varying in this range. Were distributed 4 hydraulic conductivity zones: (K1) west zone with K=6x10-5 m/s; (K2) center-east zone with K=3x10-4 m/s; (K3) far east zone with K=5x10-4 m/s; e (K4) east-north zone with K=1x10-5 m/s. Thereby was incorporated to the final conceptual model...

Avaliação da vulnerabilidade a contaminação das águas subterrâneas do aquífero Rio Claro na mineração Mandu, distrito de Ajapi - Rio Claro-SP

Groundwater in the Rio Claro district is predominantly extracted from low productivity wells on the Itararé Aquifer, from depths greater than 150 m. These factors in conjunction with increasing demand for water supply have stimulated many industries to exploit the Rio Claro Aquifer, constituted by Cenozoic sediments of the Rio Claro Formation, where hydraulic properties are poorly known. For this reason, it is necessary to study the possible vulnerable to contamination punctual locations of the aquifer, in order to enable proper management of these groundwater reserves and to allow continuity of supply. Thus, this study aims to assess the vulnerability to groundwater on contamination Rio Claro Aquifer, punctually in Mandu mining site area, located in the District of Ajapi, Rio Claro - SP, the company which operates and sells industrial sand. The risk of groundwater contamination depends on the relationship between the hydrogeological characteristics of the aquifer layer (vulnerability to contamination) and the pollutant load. To evaluate the susceptibility to contamination it was applied the method GOD (FOSTER and HIRATA, 1987; FOSTER et. al., 2002) and, in addition, field and laboratory tests were performed to chacacterize the granulometry of the strata, hydraulic conductivity and some physical indices to make the evaluation more assertive and detailed. Punctual contamination vulnerability found in the aquifer Rio Claro, was moderate, which means that the aquifer is vulnerable to some contaminants, but when continuously discharged or leached. Thus, Mandu mining has a great role on preventing the emission of contaminants in the process of extraction and processing of sand... (Complete abstract click electronic access below)

Simulação numérica de fluxo de águas subterrâneas na fazenda Cara Preta - Santa Rita do Passa Quatro - SP

The term model refers to any representation of a real system. The use of models in Hydrogeology can be valuable predictive tools for management of groundwater resources. The numeric models of groundwater flow, object of this study, consist on a set of differential equations that describe the water flow in the porous medium. In this context, numeric simulations were made for a sub-basin located at Cara Preta farm – Santa Rita do Passa Quatro – SP. The aquifer at the local is composed by rocks of Pirambóia Formation, which is part of Guarani Aquifer System. It was developed a conceptual model from previous studies in the area, and from that, simulations were made through the software Visual Modflow®. The conceptual model established previously was considered consistent through the results of simulation.

Monitoramento das águas subterrâneas do aterro de resíduos da construção civil e inertes, no bairro Jd. Wenzel, em Rio Claro-SP

This work is proposed to evaluate the potential risk of an inert landfill in the city of Rio Claro (SP), and also suggest a source for the contamination. The study was proposed because it is known that there were legal technicalities greetings to guarantee the quality of groundwater. Given the requirements of the Environmental Company of São Paulo (CETESB) were installed monitoring wells in the area; sampled to groundwater and its contamination was found. In addition, we analyzed the main characteristics of the area, the arrangement and characteristics of the waste, the local geology and the hydrogeological system, so that I could find the source of contaminants, and predict the direction of dispersion even in groundwater. At the end of the work presents conclusions, recommendations and proposals for mitigating action

Radioatividade e hidroquímica em águas subterrâneas do município de Botucatu (SP)

The main objective of this study is to determine the activity of Po-210, Pb-210 and gross alpha/beta radioactivity in groundwater collected in Botucatu, municipality of the São Paulo state, Brazil. Samples were collected in wells to perform the radiochemical analysis. Most wells are registered in DAEE, Sabesp or CPRM. The activity of polonium was obtained by the method of alpha spectrometry, held in LABIDRO at UNESP, Rio Claro. All samples showed radioactivity values below the maximum allowed by WHO, that are: gross alpha radioactivity = 0,5 Bq/L, gross beta radioactivity = 1,0 Bq/L, Po210 = 0,2 Bq/L and Pb210 = 0,1 Bq/L. The results of hydrochemical analysis were compared with the 1469 Ordinance of the Health Ministry, and all values are bellow the maximum allowed. The data also allowed obtain the samples classification using the Piper diagram. The samples AAB, Quinta do Manacás, Faz. Quatro Irmãs, Sesi, Sitio São José and ITE are classified as calcic bicarbonate; the samples Staroup and Caio are potassic; the samples Banespa and BTC are bicarbonate and mixed interms of dissolved cations; Sitio das Palmeiras sample is sodium bicarbonate; the sample Faz. São Paulo is chlorinated calcic; the sample Sítio Btu-Pardinho chlorinated and mixed interms of dissolved cations

Avaliação das ocorrências de nitrato e fluoreto nas águas subterrâneas do Estado de São Paulo

Concerns about the quality of groundwater have been continuously rising, considering its importance for the public water supply in the State of São Paulo, and even more due to the impact that anthropic action has been causing to the original quality of that natural resource. It is extremely relevant to identify the contamination focuses along the aquifers of the State of São Paulo. This report aims to evaluate nitrates and fluorides concentrations along the aquifers present in the state, in order to identify places where change in the quality of groundwater is observed, through the comparison between measured concentrations and reference values, such as: “Intervention Value” (maximum allowed value) and “Alert Value” (attention required value). To perform this research, a full compilation and organization has been done on chemical analysis data from the “Sistema de Informações de Águas Subterrâneas - SIDAS”, made available by the “Divisão de Procedimentos de Outorga – DPO” of the “Departamento de Água e Energia Elétrica – DAEE”. This work has made possible the build-up of a database composed by 6,860 wells, with analytical data ready to be interpreted, containing information about water pH, electrical conductivity, hardness and chloride, iron, fluoride, nitrogen, nitrates and total dissolved solids concentrations. This database shows concentration data for nitrates (6,157 wells) and fluoride (3,316 wells). From this information, maps for nitrates and fluorides concentration distributions have been made, by each aquifer and each “Unidade de Gerenciamento de Recursos Hídricos – UGRHI”, which has enabled the identification of wells where the concentrations of these chemical compounds exceeds the reference values. Concerning nitrates, these analysis indicated the existence of contamination sources from rural and urban zones, mostly present in the west region... (Complete abstract click electronic access below)

Contribuição das águas subterrâneas para a vazão do Ribeirão Boa Vista ou Córrego do Lajeado

This paper aimed to give a contribution to improve water resources management, consists of the analysis of interaction among groundwater and streamflow, by through the analysis of the relationship between basic and total streamflow, based on measured hidrological data from Ribeirão Boa Vista or Córrego Lajeado. watershed. Comparisons among groundwaterflow in this basin with another one in Rio Corumbataí basin were made based on the specific basic flow, in order to verify the possibility of the utilization of measured hydrological data in other basins with similar geological characteristics and soil use and occupation. Based upon the comparisons that were made, specific basic flow does not represent a good tool for extrapolation of measured data, indicating that this comparison shall be weighted by others characteristics as permeability and thickness of geological formations. Finally, it was possible to conclude that basic flow may be considered as an additional parameter for analysis of hydrological and hydrogeological characteristics of a basin and to provide subsidies to release legal licenses for water resources uses. related to surface water as well as for groundwater and may also be used as a tool for consolidation of integrated management of water resources, that is considered as a necessary and essential practice to avoid conflicts between users of water resources in a river basin.

Simulação de contaminação de sedimentos e águas subterrâneas por gasolina e álcool: um estudo de monitoramento de variações das propriedades físico-químicas

Geophysics studies in areas impacted by petroleum derivatives describe abnormalities of both low and high electrical resistivity (the opposite of electrical conductivity), confirmed as contaminant phase by chemical analysis: this contradiction can be explained by degrading processes that naturally occur and create sub products that can change the environment conductivity. Monitoring the variation of the parameters mentioned serves as a comparative basis to the variation in geoelectrical parameters, which identified the correlation between the same contaminant parameters and the difference between their behavior studied apart, as well as its relations with the biodegradation process. The results are applied to the fuel distribution and storage sectors, leading to the diagnosis and monitoring of possible groundwater contamination scenarios, and the knowledge of the area exposure time to the contaminant, besides the better remediation alternative and impacts control. Among some conclusions, the most significant are the decrease in conductivity over time, so as the increase in Eh value in the gasoline contaminated tank, as well as the decrease in the pH value in the second tank with ethanol, which can be attributed to its degradation. Comparing the variations in both tanks, it is evident that Eh, pH and electrical conductivity do not behave temporally in a similar way, although some correlations between Eh and pH can be related.

Ocorrência de nitrato nas águas subterrâneas do Sistema Aquífero Bauru em áreas rurais

Pós-graduação em Geociências e Meio Ambiente - IGCE

Caracterização isotópica do CO2 dissolvido em águas subterrâneas no município de Paulínia, SP

Pós-graduação em Geociências e Meio Ambiente - IGCE

Simulação numérica de fluxo de águas subterrâneas na bacia do Rio Corrente (BA)

The numeric simulation is an important tool applied in understanding the dynamics of groundwater flow. In a hydrogeological model the processes responsible for groundwater flow are described by numerical formulations that allow the simplification, representation and understanding of the dynamics of the Aquifer System. In this work, a steady state groundwater flow simulation of Urucuia Aquifer System (UAS) part of the Corrente river basin was conducted, using the finite element method through software FEFLOW, to understand the dynamics of groundwater flow and quantify the hydrologic balance. The aquifer system Urucuia lodges in the São Francisco hydrogeological province and corresponds to a set of interconnected aquifers that occur in rocks from Urucuia group in the Urucuia sub-basin described by Campos e Dardenne (1997). The system is a porous media one, in a shape of a thick table mountain, consisting essentially of sandstones. The Corrente river basin is located in UAS in Western State of Bahia and it's one of the main units to maintaining permanent flow (Q95) and average natural flow of the São Francisco river. The simulation performed in this work obtained the following results for the modelled region: horizontal hydraulic conductivity of 3 x 10-4 m/s and vertical one 6 x 10-5 m/s; maximum recharge of 345 mm and minimum of 85 mm/a. It was concluded that: (1) regional groundwater flow has eastbound; with an exception of the extreme northeast portion, where the flow has opposite direction; (2) there are smaller water side dividers with an approximate direction EW, that guide the flow of water to the drainage that cut the aquifer; and (3) the UAS at Corrente river basin can be understood as a free regional aquifer system, isotropic and homogeneous. Regionally, the small lithological variations present in the Urucuia group can be neglected and do not exhibit significant influences on the dynamics of ground water flow

Simulação numérica de fluxo de águas subterrâneas do aquífero Rio Claro, na região do campus da UNESP - Rio Claro, SP

The water management in any area is highly important to the success of many business and also of life and the understanding of your relationship with the environment brings better control to its demand. I.e. hydrogeological studies are needed under better understanding of the behavior of an aquifer, so that its management is done so as not to deplete or harm it. The objective of this work is the numerical modeling in transient regime of a portion of the Rio Claro aquifer formation in order to get answers about its hydrogeological parameters, its main flow direction and also its most sensitive parameters. A literature review and conceptual characterization of the aquifer, combined with field campaigns and monitoring of local water level (NA), enabled the subsequent construction of the mathematical model by finite elements method, using the FEFLOW 6.1 ® computational algorithm. The study site includes the campus of UNESP and residential and industrial areas of Rio Claro city. Its area of 9.73 km ² was divided into 318040 triangular elements spread over six layers, totaling a volume of 0.25 km³. The local topography and geological contacts were obtained from previous geological and geophysical studies as well as profiles of campus wells and SIAGAS / CPRM system. The seven monitoring wells on campus were set up as observation points for calibration and checking of the simulation results. Sampling and characterization of Rio Claro sandstones shows up a high hydrological and lithological heterogeneity for the aquifer formation. The simulation results indicate values of hydraulic conductivity between 10-6 and 10-4 m / s, getting the Recharge/Rainfall simulation in transient ratio at 13%. Even with the simplifications imposed on the model, it was able to represent the fluctuations of local NA over a year of monitoring. The result was the exit of 3774770 m³ of water and the consequently NA fall. The model is considered representative for the...

Comportamento dos radioisótopos 238U, 234U e da razão de atividade 234U/238U em águas subterrâneas extraídas de corpos graníticos fraturados da Suíte Intrusiva de Itu (SP)

O uso de radionuclídeos em hidrologia, como a concentração de urânio e a razão de atividades (234U/238U), tornou-se ultimamente uma ferramenta de grande importância nas pesquisas relacionadas à água subterrânea. Estes parâmetros têm sido usados para identificar os principais mecanismos de mobilização, precipitação e transporte dos isótopos de um aquífero, ou seja, esses isótopos têm sido empregados como traçadores para água. A área de estudo deste trabalho compreende os corpos graníticos fraturados da Suíte Intrusiva de Itu, que afloram a leste do Estado de São Paulo junto à Bacia Sedimentar do Paraná, fazendo parte da Bacia Hidrográfica do Médio Tietê. Os poços de onde foram coletadas as águas subterrâneas investigadas foram perfurados nos granitos desta Suíte, localizados nos municípios de Salto (poço YVC), Itu (HND), Itupeva (poço ITUP) e Indaiatuba (poços BDN 1 e BDN 2), sendo estes utilizados no abastecimento residencial ou para irrigação. As coletas foram mensais e o tempo de amostragem foi de um ano e meio com o objetivo de avaliar a sazonalidade destas águas. A técnica utilizada, para discriminar os isótopos de urânio dissolvidos, bem como para determinar sua razão de atividade (234U/238U), nas amostras das águas subterrâneas, foi a de espectrometria alfa. Os resultados mostram que os parâmetros físico-químicos e composição química da água exercem um papel muito importante no comportamento dos isótopos analisados. As importantes variações observadas tanto entre as águas de um mesmo poço, como também entre poços diferentes, mostram que os processos de recarga e/ou de interação rocha – água ocorrem de maneira distinta.