Antioxidante em pós-colheita de Brassica aleracea var. Italica cultivada em sistema orgânico e convencional submetidos a tratamentos de sanitização e enzimas oxidativas em diferentes variedades de Chicorium intybus L

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Estudo metaloproteômico em amostras de tecido muscular de Tilápia do Nilo alimentadas com fontes de zinco orgânico e inorgânico

Pós-graduação em Zootecnia - FMVZ

Tratamento fotocatalítico de corante ácido usando filmes finos de vidro/Ti 'O IND. 2' e degradação fotoeletrocatalítica de corante vat sobre eletrodos de filmes finos de Ti/Ti 'O IND. 2'

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Impactos de sistemas de cultivo, extrato húmico e adubos orgânico e mineral sobre alguns atributos físicos e químicos de um latossolo, cultivado com cana-de-açúcar

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Desenvolvimento de sistemas multifuncionais baseados em híbridos orgânico-inorgânicos dopados

Pós-graduação em Química - IQ

Estudo do potencial de associações de ZnO com os produtos naturais ácido cafeico e ferúlico como filtros solares híbridos: [recurso eletrônico]

In this work were studied associations of ZnO with the natural products caffeic and feluric acids. Two preparation methods were used, that is, the sol-gel and a reflux procedure. In the sol-gel method, ZnO is produced by the basics hydrolysis of precursors in the presence of the organic filters (caffeic and feluric acids), which results in 30 nm (or less) ZnO particles with the organic filters (in dissociated form) bonded to the surface of ZnO. In the reflux method, a dispersion of ZnO in a water/ethanol mixture was kept under reflux (50oC/4h) in the presence of the organic acids. The ZnO particles used in the reflux method have a higher diameter than sol-gel ZnO particles, but the prepared associated product ZnO/Organic acids were similar. Despite of the difference in relation to crystallinity between the products, the preparation methods resulted in analogous associations with respect to the interaction of the organic filters with the ZnO surface. The caffeic/ZnO associations presented low photostability, which lead to the degradation of the organic filter. The other associations (feluric acid/ZnO) presented satisfactory results. The FT-IR spectroscopy confirmed the formation of the association, and the nature of the bond formed compared with the Zn-O bond in Zn2+/Felutic acid complexes. The isolated organic and inorganic filters, along with the associations were analyzed by diffuse reflectance spectroscopy and Uv-vis spectroscopy. The absorption edges and the critical wavelengths were analyzed and the effects of Zn-O bonds in feluric acid/ZnO associations described as a function of the relative position of the π/π* system of the organic filter. Finally the performance of the hybrid filters were investigated in terms of the absorption of UVA and UVB radiations, with the UVA/UVB ratio, an efficiency parameter largely used in the description of solar filters, sunscreen and suncare products

Propriedades térnicas de géis e xerogéis híbridos de sílica/orgânico à base de GPTS-TEOS com diferentes concentrações de GPTS

In the present work the thermal characteristics of gels and xerogels of Silica/organic hybrids derived from different concentrations of GPTS-TEOS were investigated by thermal analysis (TG, DTA, and DSC). The preparation of gels of the Silica/organic hybrid matrix was held through the sol-gel process, consisting by the hydrolysis of alkoxides GPTS and TEOS in proportion (1:1) and (1:2) that was promoted in acidic conditions under reflux and stirring at 80oC/2h, producing the matrix in the colloidal state (sol). Gels were prepared by addition of NH4OH to the sol, promoting gelation of sol in sealed plastics containers. Part of the gels samples was analyzed by TG, DTS and DSC techniques in order to characterize water loss and degradation of the polymeric “epoxy” groups present in the structure of the silica derived from the GPTS alkoxide. Another set of samples was dried at 80oC/48h to obtain xerogels (dried gels) and analyzed by the same techniques. We obtained the characteristics temperatures of the matrix by the techniques DTA, DSC and TG, under measurements of thermal analysis until 800oC and 600oC in case of DSC. By thermal analysis (TG, DTA, and DSC) the main endothermic events (loss of water, melting, pyrolysis) and exothermic events (burning of the polymer) of the GPTS-TEOS matrix were determined

Diodo planar orgânico Schottky: construção e caracterização

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Tipos de condução de hastes na produção e na qualidade de mini tomate em manejo orgânico

Pós-graduação em Agronomia (Horticultura) - FCA

Fabricação e caracterização de diodo Schottky orgânico com arquitetura planar

Usually organic polymeric diodes are made with a semiconductor layer placed between two electrodes in a sandwich-like architecture, where the electrodes are deposited on the surfaces of a polymeric semiconductor film. This methodology leads to two main problems: i) the polymeric film top surface is rough and irregular, resulting in non-uniform electric field into the device; ii) during the deposition of metallic electrode in the top surface polymeric film, by thermal evaporation, occurs the diffusion of metal atoms into the polymeric film, changing the material electronic structure. Thus, the metal-semiconductor junction is not well defined, which is essential for the production of good quality Schottky diode, which exhibits ideality factor close to the unity and low turn-on voltage. In order to avoid these two problems, in the present research was proposed to manufacture an organic diode with the semiconductor polymeric layer deposited over bimetallic (gold and aluminum) interdigitated electrodes. The doping of the active layer was performed by immersing the device in hydrochloric acid solution with pH 2 during different times in order to promote different doping levels of the semiconductor polymer. Was verified that the proposed diode, which exhibits well-defined metal-semiconductor junction, operates as a Schottky diode, with good ideality factor, 10 ± 3, and low turn-on voltage, 1,2 ± 0,2 V, in comparison with conventional organic polymeric diodes. Contrasting with the ideality factor and turn-on voltage, the diode rectification ratio was obtained as 7, a value lower than the expected for a good organic diode. Was also showed that the diode characteristics were dependent on the semiconductor polymer doping level, and that the diode characteristics were optimized with doping promoted by immersion in the acid solution for times longer than 50 s. Furthermore, as was showed that the diodes properties are dependent on the semiconductor...

Formas de N-orgânico em latossolo em função de nitrogênio e de plantas de cobertura em pré-safra do milho

Pós-graduação em Agronomia (Produção Vegetal) - FCAV

Ácido fumárico e quelato de cálcio e fósforo na ração de leitões desmamados

Two experiments (E) were carried out with the objective of evaluating the effects of fumaric acid and carbo-amino-fosfo-quelato of calcium diets of weaned pigs on performance (E1) and intestinal morphology (E2). A total of 96 and 32 pigs with initial mean weights of 5,66 kg ± 0,44kg and 5,34 ± 0,45kg , in E1 and in E2, were used respectively. Randomized block designs were used in both experiments, with a 2 X 2 factorial arrangement in E1 and a 2 X 2 X 2 factorial arrangement in E2. No interaction between acidifier, source of calcium and phosphorus were found for the variables studied in the two experiments. No treatment effects were found on daily feed intake in evaluating periods. Feed conversion from 0 to 17 days was better (P<0.05) when inorganic sources of Ca and P were fed; however, no difference was observed in other periods. The averages of villus height (AV), crypt depth (PC), AV: PC relationship and mucous membrane of the duodenum and of the jejunum didn’t differ among treatments. Considering the total nursery period, no benefit was found in using an acidifier, however the carbo-amino-fosfo-quelato of calcium studied may replace the inorganic sources in the diets of piglets, with no damage to performance and to intestinal morphology.

Citotoxicidade do ácido peracético: avaliação metabólica, estrutural e de morte em fibroblastos L929

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Evaluación del comportamiento de falso roble (Tabebuia rosea (Bertol.) DC.), Genízaro (Pithecellobium saman (Jacq.) Benth.) y Guanacaste negro (Enterolobium cyclocarpum (Jacq.) Griseb.) en ensayo de germinación y sembrados en dos tipos de sustrato orgánico

Las etapas de este trabajo de investigación se llevaron a cabo en las instalaciones del invernadero y vivero de la Universidad Nacional Agraria, ubicada a la altura del kilómetro 12 carretera norte en la ciudad de Managua. Se realizó un ensayo de germinación con semillas falso roble Tabebuia rosea (Bertol.) DC., genízaro Phitecellobium saman (Jacq.) Benth. y guanacaste negro Enterolobium cyclocarpum (Jacq.) Griseb., para cuantificar el porcentaje, energía y valor de la germinación aplicando tratamientos pre germinativos. Posteriormente, en vivero, se establecieron dichas especies en un diseño de bloques completos al azar con tres bloques por especie, tres tratamientos por bloque y noventa repeticiones por tratamiento, realizando un ANDEVA y aplicando una prueba de separación de medias. Las variables evaluadas en el ANDEVA fueron altura total y diámetro basal. Separadamente se evaluó la mortalidad y sobrevivencia de las plantas en el vivero. El tratamiento pre germinativo que dio mejores resultados fue el rompimiento de la testa en el extremo donde se encuentra el micrópilo, con porcentajes de germinación superiores al 90%. No se encontraron diferencias significativas entre tratamientos, por lo cual no hubo efecto de los sustratos sobre los incrementos de las plantas de genízaro Phitecellobium saman (Jacq.) Benth. y se encontraron diferencias significativas entre tratamientos y variables para guanancaste negro Enterolobium cyclocarpum (Jacq.) Griseb. con los mayores incrementos en compostaje con 29,32 cm y los menores en tierra común 18,82 cm. El compostaje fue el sustrato donde ocurrió la mayor sobrevivencia de guanacaste negro Phitecellobium saman (Jacq.) Benth. con 85% y genízaro Phitecellobium saman (Jacq.) Benth. con 66%. Los valores de mortalidad fueron menores al 26% en todos los sustratos.

Estudio sobre la conservación del subproducto del camarón con dos niveles de inclusión [5 10] de ácido sulfúrico

Nicaragua produce 147,000 lb/mes de subproducto de la pesca del camarón y del pescado los cuales son destinados a la basura. Con e l objetivo de proporcionar un método de conservación que conlleve a utilizar estos desperdicios en la alimentación animal se realizó el presente estudio que consistió camarón, en elaborar tratados microensilajes con subproducto con ácido sulfúrico (5%, del 10%) volumen/peso utilizando de 2 Kg cada uno. 20 microsilos de PVC con capacidad se dividieron en 2 tratamientos evaluándolos a diferentes periodos de tiempo (7, 15, 30, 45 y 60 días), realizándose un DCA con arreglo unifactorial, análisis bromatológicos, determinación de AGV y pH. Todos los ensilados presentaron predominancia de la fermentación láctica, los contenidos de proteína bruta variaron en un rango de 40.70 a 50.20% según los tratamientos. Todos los ensilajes se pueden utilizar a los 7 días después de ensilarse. El tratamiento de menor costo resulto ser el T1 (5% H2so4 ) con 0.56 USA/Kg.