942 resultados para <(C5ME5)2RH2(MU-SC6F5)3><(C5ME5)RH(SC6F5)3>
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This paper proposes a novel, fast lock-in, phase-locked loop (PLL) frequency synthesizer. The synthesizer includes a novel mixed-signal voltage-controlled oscillator (VCO) with a direct frequency presetting circuit. The frequency presetting circuit can greatly speed up the lock-in process by accurately the presetting oscillation frequency of the VCO. We fully integrated the synthesizer in standard 0.35 mu m, 3.3 V complementary metal-oxide-semiconductors (CMOS) process. The entire chip area is only 0.4 mm(2). The measured results demonstrate that the synthesizer can speed up the lock-in process significantly and the lock-in time is less than 10 mu s over the entire oscillation frequency range. The measured phase noise of the synthesizer is -85 dBc/Hz at 10 kHz offset. The synthesizer avoids the tradeoff between the lock-in speed and the phase noise/spurs. The synthesizer monitors the chip temperature and automatically compensates for the variation in frequency with temperature.
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This paper proposes a novel, fast lock-in, phase-locked loop (PLL) frequency synthesizer. The synthesizer includes a novel mixed-signal voltage-controlled oscillator (VCO) with a direct frequency presetting circuit. The frequency presetting circuit can greatly speed up the lock-in process by accurately the presetting oscillation frequency of the VCO. We fully integrated the synthesizer in standard 0.35 mu m, 3.3 V complementary metal-oxide-semiconductors (CMOS) process. The entire chip area is only 0.4 mm(2). The measured results demonstrate that the synthesizer can speed up the lock-in process significantly and the lock-in time is less than 10 mu s over the entire oscillation frequency range. The measured phase noise of the synthesizer is -85 dBc/Hz at 10 kHz offset. The synthesizer avoids the tradeoff between the lock-in speed and the phase noise/spurs. The synthesizer monitors the chip temperature and automatically compensates for the variation in frequency with temperature.
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An ultra low power non-volatile memory is designed in a standard CMOS process for passive RFID tags. The memory can operate in a new low power operating scheme under a wide supply voltage and clock frequency range. In the charge pump circuit the threshold voltage effect of the switch transistor is almost eliminated and the pumping efficiency of the circuit is improved. An ultra low power 192-bit memory with a register array is implemented in a 0.18 mu M standard CMOS process. The measured results indicate that, for the supply voltage of 1.2 volts and the clock frequency of 780KHz, the current consumption of the memory is 1.8 mu A (3.6 mu A) at the read (write) rate of 1.3Mb/s (0.8Kb/s).
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用线性差分径向变化仪连续监测充分灌溉条件下的仕女红桃树茎直径变化,结合同步观测的气象因子数据,分析2007年3月中旬~10月下旬的仕女红桃树茎直径变化规律,为基于果树直径变化的灌溉管理提供基础依据。结果表明:仕女红桃树茎直径具有很好的时间变化规律,日变化曲线呈均匀"U"型,日最大值出现在黎明前后,日最小值出现在下午4时左右;季节变化方面,MDS呈低—高—低变化规律,从萌芽—开花期到果实成熟期的不同生长阶段,MDS平均值依次为87μm、200.84μm、253.75μm、171.67μm、138.67μm和94.34μm,坐果—展叶期和第一次果实膨大期MDS值居全生育期最高,需水量最大。桃树直径生长呈慢—快—慢变化规律,3月中下旬,开始生长,平均日生长量从12.68μm逐渐增加大36.84μm,7月24日~8月23日之间生长最快,平均日生长量达73.67μm,然后迅速下降,到生长末期平均日生长量仅为7.36μm。3~5月和7~9月可分别采用DI和MDS作为灌溉控制指标。茎直径变化与气象因子响应强烈,但不同生长阶段对茎直径变化产生主要影响的气象因子不同,对MDS产生主要影响的气象因子依次为:Rn、Tmax、Tma...
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Reactions of zinc(II) or cadmium(II) salts with terephthalic acid (H(2)tp) and 1,3-bis(4-pyridyl) propane (bpp) have afforded four coordination polymers at room temperature, [Zn(mu-tp)(mu-bpp)](n)center dot 2nH(2)O (1), [Cd-2(mu-tp)(2)(mu-bpp)(3)](n)center dot 2nH(2)O (2), [Cd(mu-tp)(mu-bpp)(H2O)](n)center dot nH(2)O (3), and [Cd-2(mu-tp)(mu-bpp)(2)(bpp)(2)Br-2](n) (4). Single-crystal X-ray diffraction has revealed interesting topological features for these compounds.
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The synthesis and catalytic activity of lanthanide monoamido complexes supported by a beta-diketiminate ligand are described. Donor solvents, such as DME, can cleave the chloro bridges of the dinuclear beta-diketiminate ytterbium dichloride {[(DIPPh)(2)nacnac]YbCl(mu-Cl)(3)Yb[(DIPPh)(2)nacnac](THF)} (1) [(DIPPh)(2)nacnac = N,N-diisopropylphenyl-2,4-pentanediimine anion] to produce the monomeric complex [(DIPPh)(2)nacnac]YbCl2(DME) (2) in high isolated yield. Complex 2 is a useful precursor for the synthesis of beta-diketiminate-ytterbium monoamido derivatives. Reaction of complex 2 with 1 equiv of LiNPr2i in THF at room temperature, after crystallization in THF/toluene mixed solvent, gave the anionic beta-diketiminate-ytterbium amido complex [(DIPPh)(2)nacnac]Yb(NPr2i)(mu-Cl)(2)Li(THF)(2) (3), while similar reaction of complex 2 with LiNPh2 produced the neutral complex [(DIPPh)(2)nacnac]Yb(NPh2)Cl(THF) (4). Recrystallization of complex 3 from toluene solution at elevated temperature led to the neutral beta-diketiminate-lanthanide amido complex [{(DIPPh)(2)nacnac}Yb(NPr2i)(mu-Cl)](2) (5). The reaction medium has a significant effect on the outcome of the reaction.
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织纹螺(Nassarius spp.)味道鲜美,是中国及其它一些亚洲国家沿海地区居民习惯食用的一种水产品。但是,近几十年来,中国沿海频繁发生食用织纹螺中毒事件,严重威胁着人们的身体健康和生命安全。加之人们对织纹螺体内的毒素成分、来源及其毒性变化规律还没有清晰的认识,因此难以有效预防和控制食用织纹螺引起的中毒事件。本文根据文献报道,在中国沿海食用织纹螺中毒事件多发的典型区域,包括江苏省的连云港市和盐城市、浙江省的舟山市和宁波市、福建省的宁德市、厦门市和莆田市设立了监测点,于2006年和2007年间进行了连续采样,应用小鼠生物测试法调查了织纹螺毒性的消长情况,并利用高效液相色谱-质谱联用(Liquid Chromatography-Mass Spectrometry,LC-MS)和高效液相色谱技术(High Performance Liquid Chromatography,HPLC)对织纹螺体内的毒素成分进行了分析。 实验结果表明,2006年于江苏省盐城市射阳海域采集的织纹螺样品中,阳性样品检出率为56%,毒性在2-5 MU/g组织(湿重)之间变化,在2007年于同地采集的8个样品中,除一个样品毒性为3.14 MU/g组织(湿重)以外,其余样品均表现为阴性;而2007年采集自连云港市赣榆海域的织纹螺样品,在采样期间则呈现出极高的毒性,最高达到846.52 MU/g 组织(湿重),毒性在监测期间呈“M”状波动,在5月和7月下旬出现两个毒性高峰。2006年于浙江省宁波市象山港采集的织纹螺样品中,阳性样品检出率为25%,毒性均在2.5 MU/g组织(湿重)左右;而同年采集自舟山市定海的织纹螺样品中,阳性样品检出率为100%,最高毒性达18.40 MU/g组织(湿重),毒性在监测期间也呈“M”状波动,高峰期出现在6月初和7月底。2006年3-9月采集自福建省宁德霞浦、厦门同安和莆田涵江采集的织纹螺样品中,阳性样品检出率分别为20%、43%和14%,除7月中旬采集自宁德霞浦的一个样品毒性达到16.19 MU/g组织(湿重)之外,其余样品毒性均在2-5 MU/g组织(湿重)间波动。从阳性样品的时间分布规律来看,3月份和6、7月份是阳性样品集中出现的时期。根据以上调查结果可以看出,织纹螺的毒性消长呈现出较明显的地域性和季节性特征,不同地区的织纹螺毒性存在差异,而同一区域织纹螺毒性的消长则表现出明显的季节性集中趋势。除了2007年采集自连云港赣榆的织纹螺样品毒性与其平均个体组织重量有相似的变化趋势以外,其余地区的织纹螺样品毒性和个体大小无明显相关性。 利用LC-MS和HPLC技术对织纹螺样品中的毒素成分进行了分析,确定河豚毒素(tetrodotoxin, TTX)及其同系物(trideoxyTTX,4-epi-TTX,anhydroTTX,oxoTTX)是所采集织纹螺中的主要致毒成分,样品中没有检测到麻痹性贝毒毒素(Paralytic Shellfish Poison, PSP)。自不同地区采集的织纹螺中毒素成分基本一致,但组成存在一定差异。其中,采自江苏省连云港赣榆和浙江省舟山定海的织纹螺样品中,trideoxyTTX是主要的成分,其次是TTX;而从其它采样地点采集的织纹螺中,TTX都是主要的毒素成分,其次才是trideoxyTTX及其它同系物。对采集自江苏省连云港赣榆和浙江舟山定海的织纹螺体内毒素的解剖学分布进行了分析,结果表明肌肉、消化腺和剩余部分中的毒素组成基本一致,其中trideoxyTTX是主要的毒素成分,其次为TTX,但采自浙江舟山的织纹螺剩余部分中的TTX是主要的毒素成分。在监测期间,各组织中的毒素组成没有明显变化,但毒素含量随季节变化表现出了一定的差异。 综上所述,在中国沿海典型区域开展的织纹螺毒性调查结果表明其毒性消长具有一定的地域性和季节性特征。分析结果显示织纹螺体内的毒素成分是河豚毒素及其同系物,采自不同区域的织纹螺体内毒素成分基本一致,但毒素组成稍有差异。对织纹螺中毒素的解剖学分布研究显示,各组织中的毒素含量随季节变化而表现出一定差异,但毒素组成没有明显的季节性变化。这些结果显示中国沿海的织纹螺应具有相似的毒素来源,研究结果将为相关部门有效监测、预防和控制食用织纹螺中毒事件提供有力的科学依据。
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There is growing evidence that organo-nitrogen compounds may constitute a significant fraction of the aerosol nitrogen (N) budget. However, very little is known about the abundance and origin of this aerosol fraction. In this study, the concentration of organic nitrogen (ON) and major inorganic ions in PM2.5 aerosol were measured at the Duke Forest Research Facility near Chapel Hill, NC, during January and June of 2007. A novel on-line instrument was used, which is based on the Steam Jet Aerosol Collector (SJAC) coupled to an on-line total carbon/total nitrogen analyzer and two on-line ion chromatographs. The concentration of ON was determined by tracking the difference in concentrations of total nitrogen and of inorganic nitrogen (determined as the sum of N-ammonium and N-nitrate). The time resolution of the instrument was 30 min with a detection limit for major aerosol components of ∼0.1 mu;gm-3. Nitrogen in organic compounds contributed ∼33% on average to the total nitrogen concentration in PM2.5, illustrating the importance of this aerosol component. Absolute concentrations of ON, however, were relatively low (lt;1.0 mu;gm-3) with an average of 0.16 mu;gm-3. The absolute and relative contribution of ON to the total aerosol nitrogen budget was practically the same in January and June. In January, the concentration of ON tended to be higher during the night and early morning, while in June it tended to be higher during the late afternoon and evening. Back-trajectories and correlation with wind direction indicate that higher concentrations of ON occur in air masses originating over the continental US, while marine air masses are characterized by lower ON concentrations. The data presented in this study suggests that ON has a variety of sources, which are very difficult to quantify without information on chemical composition of this important aerosol fraction.
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The structure of intertidal benthic diatoms assemblages in the Tagus estuary was investigated during a 2-year survey, carried out in six stations with different sediment texture. Nonparametric multivariate analyses were used to characterize spatial and temporal patterns of the assemblages and to link them to the measured environmental variables. In addition, diversity and other features related to community physiognomy, such as size-class or life-form distributions, were used to describe the diatom assemblages. A total of 183 diatom taxa were identified during cell counts and their biovolume was determined. Differences between stations (analysis of similarity (ANOSIM), R=0.932) were more evident than temporal patterns (R=0.308) and mud content alone was the environmental variable most correlated to the biotic data (BEST, rho=0.863). Mudflat stations were typically colonized by low diversity diatom assemblages (H' similar to 1.9), mainly composed of medium-sized motile epipelic species (250-1,000 mu m(3)), that showed species-specific seasonal blooms (e.g., Navicula gregaria Donkin). Sandy stations had more complex and diverse diatom assemblages (H' similar to 3.2). They were mostly composed by a large set of minute epipsammic species (<250 mu m(3)) that, generally, did not show temporal patterns. The structure of intertidal diatom assemblages was largely defined by the interplay between epipelon and epipsammon, and its diversity was explained within the framework of the Intermediate Disturbance Hypothesis. However, the spatial distribution of epipelic and epipsammic life-forms showed that the definition of both functional groups should not be over-simplified.
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We report the serendipitous discovery of a new, very low luminosity, cool degenerate in the region of Taurus. The object was found as a very high proper-motion star (mu = 1.'' 3 yr(-1)) on seven I-band UK Schmidt Telescope plates, dating from 1987 to 1994, via digitized scans from the new, fast, high-precision microdensitometer SuperCOSMOS. Photometry and spectrophotometry indicate that the object has a temperature comparable to those of the handful of coolest white dwarfs currently known (T similar to 3900 K). We discuss the relevance of this discovery to current research concerning Galactic structure and evolution.
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We present the Pan-STARRS1 discovery of PS1-10afx, a unique hydrogen-deficient superluminous supernova (SLSN) at redshift z = 1.388. The light curve peaked at z P1 = 21.7 mag, making PS1-10afx comparable to the most luminous known SNe, with Mu = -22.3 mag. Our extensive optical and near-infrared observations indicate that the bolometric light curve of PS1-10afx rose on the unusually fast timescale of ~12 days to the extraordinary peak luminosity of 4.1 × 1044 erg s-1 (M bol = -22.8 mag) and subsequently faded rapidly. Equally important, the spectral energy distribution is unusually red for an SLSN, with a color temperature of ~6800 K near maximum light, in contrast to previous hydrogen-poor SLSNe, which are bright in the ultraviolet (UV). The spectra more closely resemble those of a normal SN Ic than any known SLSN, with a photospheric velocity of ~11, 000 km s-1 and evidence for line blanketing in the rest-frame UV. Despite the fast rise, these parameters imply a very large emitting radius (gsim 5 × 1015 cm). We demonstrate that no existing theoretical model can satisfactorily explain this combination of properties: (1) a nickel-powered light curve cannot match the combination of high peak luminosity with the fast timescale; (2) models powered by the spindown energy of a rapidly rotating magnetar predict significantly hotter and faster ejecta; and (3) models invoking shock breakout through a dense circumstellar medium cannot explain the observed spectra or color evolution. The host galaxy is well detected in pre-explosion imaging with a luminosity near L*, a star formation rate of ~15 M ⊙ yr-1, and is fairly massive (~2 × 1010 M ⊙), with a stellar population age of ~108 yr, also in contrast to the young dwarf hosts of known hydrogen-poor SLSNe. PS1-10afx is distinct from known examples of SLSNe in its spectra, colors, light-curve shape, and host galaxy properties, suggesting that it resulted from a different channel than other hydrogen-poor SLSNe.
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Adaptaci??n curricular significativa a nivel de centro que se sustenta en tres pilares: grupos flexibles, organizaci??n por talleres y trabajo sobre convivencia escolar y clima de centro.
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El cuadernillo recoge ocho relatos escritos por estudiantes de catorce años que cursan estudios de segundo de ESO; los personajes protagonistas son personajes femeninos que viven en un ambiente opresor. Los relatos forman parte de la fase de práctica escrita de un proyecto de trabajo sobre el mundo de la mujer seguido por el alumnado de primer ciclo de ESO y que, a su vez, forma parte de un proyecto más amplio titulado Literatura y educación en valores.
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Los trece relatos que aparecen recogidos en la publicación son textos literarios que contienen situaciones críticas en las que bajo la apariencia de la justicia se esconde la pobreza, la marginación y la exclusión social. Estos relatos forman parte de un proyecto de trabajo sobre expresión escrita cuyo objetivo es motivar al alumnado del área de Lengua y Literatura en la planificación, diseño, redacción y revisión de una historia literaria cuyos personajes sean portadores de una serie de valores positivos y cuyas vidas se desenvuelven en unas situaciones que denuncian la violencia social. El proyecto forma parte de otro más amplio titulado Literatura y Educación en valores.
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El curso impartido con este material fue subvencionado por el Instituto Nacional de Empleo (INEM) y el Fondo Social Europeo (FSE)