Geochemistry and mineralogy of sediments from the Atlantis II Fracture Zone

Thirteen sediment samples, including calcareous ooze, sandy clay, volcanic sand, gravel, and volcanic breccia, from Ocean Drilling Program (ODP) Sites 732B, 734B, 734G and Conrad Cruise 27-9, Station 17, were examined. Contents of major and trace elements were determined using XRF or ICP (on samples <0.5 g). Determinations of rare earth elements (REE) were performed using ICP-MS. Mineralogy was determined using XRD. On the basis of the samples studied, the sediments accumulating in the Atlantis II Fracture Zone are characterized by generally high MgO, Cr, and Ni contents compared with other deep-sea sediments. A variety of sources are reflected in the mineralogy and geochemistry of these sediments. Serpentine, brucite, magnetite, and high MgO, Cr, and Ni contents indicate derivation from ultramafic basement. The occurrence of albite, analcime, primary mafic minerals, and smectite/chlorite in some samples, coupled with high SiO2, Al2O3, TiO2, Fe2O3, V, and Y indicate contribution from basaltic basement. A third major sediment source is characterized as biogenic material and is reflected primarily in the presence of carbonate minerals, and high CaO, Sr, Pb, and Zn in certain samples. Kaolinite, illite, quartz, and some chlorite are most likely derived from continental areas or other parts of the ocean by long-distance sediment transport in surface or other ocean currents. Proportions of source materials in the sediments reflect the thickness of the sediment cover, slope of the seafloor, and the nature of and proximity to basement lithologies. REE values are low compared to other deep-sea sediments and indicate no evidence of hydrothermal activity in the Atlantis II Fracture Zone sediments. This is supported by major- and trace-element data.

Grain-size and bulk and clay mineralogy of ODP Leg 204 sediments

We present grain size, granulometric statistical parameters, and calcium carbonate content of sediment samples from the summit and east and west flanks of southern Hydrate Ridge (Sites 1244-1250). These data are compared with magnetic susceptibility measurements from the same intervals. Bulk and clay mineralogy from Sites 1244 (east flank), 1247 (west flank), and 1250 (summit) are also presented. The integration of these data allows us to characterize the main sedimentary facies and composition of the Quaternary age sediments from southern Hydrate Ridge.

Mineral composition and geochemistry of sediments from ODP Leg 127 sites

The lithostratigraphy of Neogene hemipelagic sediments recovered from the Japan Sea during Leg 127 was revised to improve intersite consistency and to remove confusion stemming from diagenetic modification of the lithology through the opal-A to opal-CT transformation. Special emphasis was put on the presence and nature of dark-light cycles in revising the lithostratigraphy. Mineral composition analysis was conducted for samples from Sites 794, 795, and 797. In addition, major element chemical composition analysis was conducted for these same sample sets from Site 794. The result of mineral composition analysis suggests that the detrital component, which consists of such minerals as quartz, plagioclase, illite, and kaolinite plus chlorite, is diluted to various degrees by biogenic silica (opal-A) and its diagenetic equivalents (opal-CT and quartz). Smectite, on the other hand, may be a diagenetic or hydrothermal alteration product of volcanic material, although more study is necessary to confirm its origin. As a whole, vertical variation in the sediment composition is consistent with the revised lithostratigraphy and helps to characterize the redefined lithologic units quantitatively.

Aerosols over the East Atlantic in spring and summer 2001

Data on the concentration and mineral composition of aerosols collected by nets in Cruise 18 of R/V Akadernik Fedorov on a submeridional section in the East Atlantic are presented. An empirical curve for calculating efficiency factor of a net is given for different concentrations of mineral part of aerosols. Fluxes of lithogenic part of aerosols to the sea surface are calculated. A comparison of lithogenic fluxes from the atmosphere and in the water column of the ocean showed that values of fluxes practically coincide in areas with dominating supply of dry atmospheric material. These fluxes strongly differ in the intratropical convergence zone, where deposition of aerosols depends on atmospheric precipitation, or in regions, where sedimentary material is supplied to the ocean mainly by river run-off. Residence time of aerosol lithogenic matter in the euphotic layer is calculated.

Mineral XRD peak areas and ratios of ODP Site 184-1146 clays, South China Sea

Site 1146 (19°27.40'N, 116°16.37'E) was drilled in ~2092 m water depth in a rift basin on the continental slope of the South China Sea. A total of 607 m of sediment was cored in Hole 1146A, and a composite section from three holes extends down to 640 meters composite depth (mcd). Three stratigraphic sedimentary units were recognized at this site: late Pliocene to Pleistocene nannofossil clay (Unit I), middle Miocene to late Pliocene foraminifer and nannofossil clay mixed sediment (Unit II), and early to middle Miocene nannofossil clay (Unit III). This study reports the mineralogy from the late Miocene through early Pleistocene, 150-440 mcd.

Mineralogy and geochemistry of latest Miocene deposits in the Tyrrhenian Sea

Late Miocene sediments from ODP Sites 652 and 654, drilled on the Sardinian margin in the Western Tyrrhenian Sea, are investigated through mineralogical, micromorphological, geochemical, and microgeochemical analyses. Clay associations appear to be little controlled by conditions of deposition, and largely depend on pre- and post-depositional conditions. The sedimentary series from Central Mediterranean gives very different geodynamic information, according to the sector considered. While relatively stable conditions, like those encountered in Caltanissetta Basin, Sicily, favor the mineralogical expression of warm-temperate and subarid Messinian climate, the Eastern Sardinia margin (Site 654) clay suites mainly reflect the transition from tectonically active to relaxed conditions. The series deposited at the foot of the same margin above a thinner crust (Site 652) experienced the effects of burial diagenesis, enhanced by strong geothermal gradient.