Seleção de bactérias fenololíticas para tratamento de efluentes de refinarias de petróleo

Os efluentes de indústrias, como refinarias e petroquímicas, frequentemente contém elevadas concentrações de substâncias tóxicas, dentre elas, os compostos fenólicos. Estas substâncias, mesmo em pequenas quantidades, afetam as propriedades organolépticas da água, além de que durante o processo de cloração da água potável, podem ser transformadas em clorofenóis e policlorofenóis, pela reação com o cloro, formando substâncias com características carcinogênicas. Neste sentido, o refino do petróleo produz grande variedade de poluentes cujas propriedades modificam-se em função dos processos utilizados. Os fenóis são compostos tóxicos, com características fungicida e desinfetante, sendo tóxico para a maioria dos microrganismos, além de apresentarem ação de carcinogenicidade, mutagenicidade e serem recalcitrantes, acumulam-se nos corpos receptores, gerando danos à saúde e à vida aquática. No entanto, embora o fenol possua ação bactericida, alguns microrganismos adquiriram a habilidade de se adaptar e utilizar este composto como fonte de carbono e energia. O presente trabalho pretendeu selecionar linhagens bacterianas, a partir do efluente de uma refinaria de petróleo, da região de Paulínia – SP, que sejam capazes de utilizar altos teores de fenóis como fonte de carbono e energia para seu crescimento e desenvolvimento, a fim de serem aplicadas nas estações de tratamento de efluentes industriais, com foco nas refinarias de petróleo. Foram isoladas 3 linhagens a partir das amostras enriquecidas do efluente da refinaria e, após os ensaios, constatou-se que 1 linhagem apresentou resistência à concentração de fenol de 1.000 mg.L-1. Os ensaios de biodegradação e crescimento em fenol como única fonte de carbono, demonstraram que estas linhagens são capazes de biodegradar aproximadamente 20% do fenol disponível no meio, no período de 24 horas. A quantificação do fenol residual foi realizada em...

Radiocronologia dos sedimentos do Lago de Constança

The dating of sediments in lakes, estuaries and rivers through radionuclides, when applied in association with other analitic methods (heavy metals, organic contaminants, etc.) allows analyses of the anthropogenic interference in the environment along the years. A geochronology of a sediment core from Untersee in Lake Constance, one of the most important hydric resources of Europe, was established through the Pb-210 method and adopting the CRS parameter (Constant Rate of Supply). The Cs-137 was successfully used to give basis to the results, as its additional input occurred in Chernobyl’s accident can be used as a marker to the year 1986. Associating the dating with the cores depth, the average mass accumulation rate and the sedimentation rate for the site were assessed (0,14 g/cm²/year and 4 mm/year respectively).

Produção e caracterização físico-mecânica de painel de compensado de Eucalyptus sp. e adesivo PVA

Studies on new adhesives and resins for bonding wood and wood products are being conducted with the intention of improving their properties, taking into account a lower environmental impact. For this reason new formulations of polyvinyl acetate (PVA) adhesives have been developed, because they have no chemicals in its composition extremely polluting and harmful to health, as is the case of formaldehyde-based resins, which in turn are the most commonly used today for wood panels production. This study tested three different formulations of PVA adhesives, with different times and temperatures of pressing for the production of Eucalyptus sp. Plywood, coming up in satisfactory results with respect to shear strength at the bondline, which was higher for the PVA adhesives compared with urea-formaldehyde and phenol. The results of MOE and MOR were lower than those values of the panels produced with urea and phenol-formaldehyde, and the results of physical tests showed to be close to the panels produced with these same adhesives

Avaliação da toxicidade do cloreto de níquel utilizando Allium cepa como organismo teste

O impacto das atividades antropogênicas sobre o meio ambiente é um tema de grande relevância atualmente, atraindo a atenção da comunidade científica em geral, visto que essas atividades têm causado alterações significativas na qualidade da água, do solo e do ar. Dentre a ampla gama de poluentes resultantes das atividades humanas, merece destaque a classe dos metais pesados, os quais possuem propriedades tóxicas e genotóxicas, constituindo fatores de risco para o desenvolvimento de desordens neurodegenerativas, artrite e câncer nas populações expostas a estes contaminantes, bem como alterações nos ecossistemas contaminados. Neste sentido, o presente trabalho teve por objetivo avaliar o potencial citotóxico, genotóxico e mutagênico do níquel como contaminante, utilizando Allium cepa (Liliaceae) como organismo-teste, a fim de detectar possíveis efeitos deletérios em seu material genético. Estas avaliações foram feitas por meio da exposição de sementes de A. cepa a três soluções, com diferentes concentrações de níquel. Os resultados obtidos no primeiro biensaio e na repetição estão apresentados na forma de artigo científico, a ser submetido para revista especializada. O estudo dos efeitos do níquel em A. cepa foram importantes, uma vez que os dados da avaliação dos danos induzidos neste organismo modelo podem ser utilizados para a comparação com modelos animais, sendo possível assim, a inferência dos perigos aos ecossistemas e à população que está exposta a esse contaminante

Aplicação de métodos computacionais no estudo das fases intermetálicas ordenadas pt-sn

Fuel cells are a very promising solution to the problems of power generation and emission of pollutant to the environment, excellent to be used in stationary application and mobile application too. The high cost of production of these devices, mainly due to the use of noble metals as anode, is a major obstacle to massive production and deployment of this technology, however the use of intermetallic phases of platinum combined with other metals less noble has been evaluated as electrodes in order to minimize production costs and still being able to significantly improve the catalytic performance of the anode. The study of intermetallic phases, exclusively done by experimental techniques is not complete and demand that other methods need to be applied to a deeper understanding of the behavior geometric properties and the electronic structure of the material, to this end the use of computer simulation methods, which have proved appropriate for a broader understanding of the geometric and electronic properties of the materials involved, so far not so well understood.. The use of computational methods provides answers to explain the behavior of the materials and allows assessing whether the intermetallic may be a good electrode. In this research project was used the Quantum-ESPRESSO package, based on the DFT theory, which provides the self-consistent field calculations with great precision, calculations of the periodic systems interatomic force, and other post-processing calculations that points to a knowledge of the geometric and electronic properties of materials, which may be related to other properties of them, even the electrocatalytic. The electronic structure is determined from the optimized geometric structure of materials by analyzing the density of states (DOS) projected onto atomic orbital, which determines the influence of the electrocatalytic properties of the material... (Complete abstract click electronic access below)

Organização e implementação de um banco de dados para a sensibilidade ambiental ao óleo e avaliaçao de ações adequadas de resposta a derramamentos - São Sebastião (SP)

The need to know and to preserve the coastal ecosystems is justified by the whole importance that those ecosystems have for our society. Then, it is big the concern in guaranteeing that those places stay free from contaminations. Among the several types of potentials pollutants that can affect the coastal systems, the petroleum-derived are the ones that cause the worst impacts, given the frequency of these accidents. Rapid actions are necessary in order to minimize the oil negative effects . This answer is faster when the most sensitive areas are known and when it presents characteristics of larger importance, as for instance, the presence of sea harvesting or the habitat of an endemic specie. Besides, it is necessary to know which cleanup methods are recommended and which are not recommended for the reached areas, so, the corrected emergency plans for each coastal environment can be applied. It is in this context that this project was developed, implementing a geographical database for the different coastal environment of São Sebastião municipality, SP, and also the data about the best cleanup techniques for each segment of the coast. This database was made available by the internet, enabling the access for several types of users.

Otimização de um método cromatográfico de análise de pesticidas organoclorados em amostras de peixes

Considering that persistent organic pollutants (POPs) including synthetic substances belonging to differents organic functions, including organochlorine pesticides (OCPs), which are the most persistent and bioaccumulative, with high toxicity to humans and animals. Accordingly environmental and biological monitoring is necessary, in order to have greater control regarding the irresponsible use of these products. Though there are several analytical methodology reported in the literature to make determinations of this pesticide, they present some difficulties, requiring several steps to make the clean up of the sample. The proposed project aims to optimize a new analytical method that allows to perform the extraction of organochlorine pesticides in fish tissues, employing acetone as solvent assisted by ultrasound bath, making the method more quickly and not requiringfurther steps to purify the sample. Were analyzed the recoveries of pesticides in study in samples of tilapia average values: Heptachlor=84,7±9,8%; Aldrin=87,3±3,5%; Endosulfan=101,4±18,6%; DDE= 90,5± 3,3%, Endrin=102,2±13,8%., DDD=92,1±19,9%; DDT=90,8±6,8%. The real samples showed values granted for our legislation and low values of error

Smart Grid e Carros Elétricos - Influência da Carga de Carros Elétricos Sobre o Sistema Elétrico

The technologies are advancing at a pace so expressive that allow the increase of the power quality from generation until the distribution to end customers. This improvement has been made possible through the automation of the energy that follows to a better quality of the energy provided, a lower energy supply disruptions and a very short recovery time. The trend of today and the near future is the distributed energy generation. To keep the automated control of the chain, the presence of Smart Grids is needed and that will be the most efficient and economical way to manage the entire system. Within this theme, is going to be necessary analyze the electric cars that promise to promote a more sustainable transport because it doesn’t uses fossil fuels, and more healthy because it does not emit pollutants into the atmosphere. The popularization of this type of vehicle is estimated to happen in a few decades and the case study analyzing its influence on the demand of the electrical system is something that will be very important in the near future. This paper presents a study of the influence of the inclusion of charges refering to electric cars

Estudo da concentração de material particulado em ambientes internos e externos de bibliotecas

Our twenty-first century society and the rhythm of life and work we have to face in our daily routine compel us to spend most of our lifetime in closed environments, in our houses, educational institutions, hospitals, airports, amongst as many others. The study of the air quality in internal environments (IAQ) is very important for monitoring people’s health effects and their environmental comfort in these locations. One essential parameter to analyze this measure is to evaluate the concentration of dispersed particulates in the air, specially focusing on those thinner particles (below the diameter of 2,5 μm), they can pose serious risks for human being because they can remain in the lungs, penetrate through the pores of our skin, amongst other harmful effects on human’s health. In this work the air quality inside the public library Profª Josina Vasques Ferrari and at Unesp public state library was evaluated, both located in Itapeva, as well as a third one, inside the Communitarian Library of the Federal University in Carlos (UFSCar) from march to may in 2012. In those environments it was analyzed if the concentration of particulates pose any real treat to the users. The equipment used for particle sampling in real time was DataRam 4 (Model DR 4000). The results given for those concentrations of particulates in both internal and external environments revealed figures within the safe standard established by the WHO (World Health Organization), from 25 to μg/m³, the only exception occurred on the fifth floor of the UFSCar library, where the average for concentration stayed at 25,30 of μg/m³

Estudo do efeito da ayahuasca sobre a agressividade de ratos submetidos ao estresse por contenção

Agressividade humana e animal acima dos padrões comportamentais esperados têm sido noticiados constantemente pela mídia e revistas especializadas na área de neurociência e neurocomportamento, sendo que várias causas tem sido atribuídas a este desvio, incluindo modificações dos padrões de relações sociais, situações levando a aumento do estresse (ES), substâncias químicas poluentes ambientais, etc. Em toxicologia já se conhece bem o fato de que aumento do estresse pode levar a aumento de comportamentos como ansiedade e agressividade. A Ayahuasca (Ay) é uma beberagem indígena que foi liberada no Brasil e em alguns outros países, para utilização em rituais religiosos. Vários estudos observacionais com humanos têm informado que a Ay poderia diminuir a agressividade, mas não existem dados experimentais concretos sobre esta possibilidade. Neste estudo objetivou-se avaliar o efeito da Ay na agressividade de animais experimentais recebendo estresse por contenção. Para os experimentos três grupos de animais (N=8), respectivamente controle (Ct), recebendo estresse por contenção (ES) e recebendo estresse por contenção mais Ayahuasca (ES+Ay), foram testados para o comportamento de agressividade utilizando o paradigma do animal residente/intruso. Os resultados obtidos demonstram que o grupo ES apresentou alterações dos parâmetros testados para agressividade e que no grupo ES+Ay estes parâmetros estavam normalizados. Conclui-se que a Ayahuasca conseguiu impedir a agressividade aumentada provocada pelo estresse por imobilização.

Análise comparativa entre Brasil e Alemanha sobre autoprodução de energia elétrica residencial

The energy crisis has affected many countries. With the growing warning with the emission in the atmosphere and the lack of resources, the seek for sustainable sources for energy genaration have become even bigger. Some Countries, as Germany, started first in this journey, creating an incentive program to self-generation with renewable sources (wind, photovoltaics, biomass, etc.), giving priority for smaller plants. In Germany the program called EEG started in 2004. In Brazil, since the beggining of 2012, the self-generators did not know how they could be beneficted for self-generation, and self-generation didn't become commun in the country. However, with NR 482, of April 17th, 2012, the parameters were defined, and the self-generator could have a guideline. Therewith, studyies can be redirected for a better knowlegde of the conditions the self-generator will be sujected, in addition to Germany's case as reference to compare with Brazil's case. In this paper these studies are made, focused in wind power (wind turbines) and photovoltaic panels

Poluição atmosférica e paisagem urbana no município de São Paulo

This paper proposes an analysis of two major polluting elements of the atmosphere of São Paulo city, carbon monoxide (CO) and sulfur dioxide (SO2). This study was performed through analysis of data on the quality of air, by means of published reports and records obtained by experiment using measuring rate monitor for CO2. Atmospheric data were collected and sorted. From this work it was possible to identify the concentration of carbon dioxide in the center of São Paulo on September 14, 2012 using the infrared gas analyzer (IRGA). From the ratios of carbon monoxide and sulfur dioxide spatially analyzed could identify major emitters by comparing records of pollutants and their origin. The analysis makes it possible to map the intensity of air pollution in urban areas, identifying the polluting elements, their issuers and thereby contributes to the current understanding of atmospheric features, bringing a geographical spatial analysis of air pollutants in São Paulo, contributing to awareness of vulnerabilities, enabling a useful tool for planning and maintenance of the urban environment related public policies

A obsolescência deliberada dos produtos e sua relação com o meio ambiente

A preocupação ambiental é crescente em praticamente todas as áreas do conhecimento. A miríade de abordagens do tema “meio ambiente” dentro da Ciência Econômica revela a premência do assunto bem como a distância do consenso. Assim, apesar da complexidade intrínseca ao sistema capitalista quando da sua inter-relação com os recursos naturais, poluição e biodiversidade, o presente trabalho propõe a análise da obsolescência prematura deliberada dos produtos como estratégia para impulsionar as vendas e sua relação com o meio ambiente bem como a observação de estratégias para a inibição dessa prática que promove o aumento do consumo - nem sempre consciente - dos recursos naturais em nome do lucro imediatista e gera quantidades cada vez maiores de resíduos e poluentes

Desafios ambientais na indústria automobiliística: uma análise do processo de reciclagem e reutilização de materiais

This research has as main objective the analysis of the auto industry has done to reduce disposal of solid waste in its production process as much as to facilitate the recycling of cars after they complete their life cycle. Despite the auto industry is not one of the most polluting in terms of its production process, it produces a good that is causing major pollution. In despite of the great current concern in seeking to reduce the emissions of pollutants by vehicles, as important as the quest for cleaner fuels is the study of how to dispose of old cars. Even if the car production does not increase significantly each year in relative terms, we must consider the fleet of used cars that still circulates in the world. Ending the mammoth “cemeteries” of automobiles, however, it is not so easy, even because the car is composed of various materials, which in many cases are not easily separable. In addition to an overview, the research seeks to examine the possible advances in Brazil related to the process of auto recycling

Aspectos técnicos e ambientais da incorporação de novas tecnologias no setor sucroalcooleiro: produção de hidrogênio e gaseificação do bagaço

The purpose of this work is to study the incorporation of hydrogen production (Case A) and the process of gasification of sugarcane bagasse associated with combined cycle gas turbine and steam turbine (Case B) for Distillery Pioneers process. These technologies can be used to improve the energy supply in the sugarcane mill. Initially the processes for obtaining sugar and ethanol from sugarcane is discussed, with a theoretical introduction to hydrogen, the process of steam reforming and gasification of biomass (bagasse) by inserting a turbine associated with the recovery boiler gas. Subsequently makes up the energy and exergy analysis of the incorporation of the above technologies. In end stage makes it an ecological analysis considering or not the carbon cycle (photosynthesis), to determine the levels of emissions of pollutants, carbon dioxide equivalent, indicators of pollution and ecological efficiencies associated with technological developments proposed. It is concluded that hydrogen production by steam reforming of ethanol and gasification of bagasse are viable alternatives from the point of view of technical and environmental applications in the biofuels industry, contributing to the development of the sector in the country