Hydrothermal synthesis of Gd2O3:Eu3+ nanophosphors: Effect of surfactant on structural and luminescence properties

Various morphologies of Eu3+ activated gadolinium oxide have been prepared by hydrothermal method using hexadecylamine (HDA) as surfactant at different experimental conditions. The powder X-ray diffraction studies reveal as-formed product is hexagonal Gd(OH)(3):Eu3+ phase and subsequent heat treatment at 350 and 600 degrees C transforms to monoclinic GdOOH:Eu3+ and cubic Gd2O3:Eu3+ phases respectively. SEM pictures of without surfactant show irregular shaped rods along with flakes. However, in the presence of HDA surfactant, the particles are converted into rods of various sizes. The temperature dependent morphological evolution of Gd2O3:Eu3+ without and with HDA surfactant is studied. TEM micrographs of Gd(OH)(3):Eu3+ sample with HDA confirms smooth nanorods with various diameters in the range 20-100 nm. FTIR studies reveal that HDA surfactant plays an important role in conversion of cubic to hexagonal phases. Among these three phases, cubic phase Gd2O3:Eu3+ (lambda(ex) = 254 nm) show red emission at 612 nm corresponding to D-5(0)-> F-7(2) and is more efficient host than the monoclinic counterpart. The band gap for hexagonal Gd(OH)(3):Eu3+ is more when compared to monoclinic GdOOH:Eu3+ and cubic Gd2O3:Eu3+. (C) 2013 Elsevier B. V. All rights reserved.

Mechanical properties of CNT-Bisphenol E cyanate ester-based CFRP nanocomposite developed through VARTM process

This paper reports on the effect of multiwall carbon nanotubes (CNTs) without and with chemical functionalization on the mechanical properties of Bisphenol E cyanate ester resin (BECy) based carbon fibre reinforced plastic (CFRP) laminated composites. BECy with its low viscosity, low moisture uptake and superior mechanical properties is selected for its application in CFRP laminates through the cost-effective Vacuum Assisted Resin Transfer Moulding (VARTM) process. However, unlike CNT-epoxy-CFRP composites, processing and performance issues such as dispersion of CNTs, chemical bonding with resin, functionalization effects, effects on mechanical properties, etc. for BECy-CNT-CFRP composite system are not well reported. The objective of this study is to improve the mechanical properties of BECy resin with small additions of CNTs and functionalized CNTs in CFRP laminates. CNTs and fCNTs are infused into BECy using ultrasonication and standard mixing methods. Improvements in Young's modulus and strength in tension, compression, shear, flexure and interlaminar shear strength are analysed. It is observed that addition of 0.5wt% CNTs effected for maximum mechanical properties of the resin and 1wt% CNTs for the mechanical properties of CNT-CFRP nanocomposite. Further, improvements obtained with fCNTs are marginal. Dispersion behaviour and effect of CNTs/fCNTs in load transfer corroborated with SEM pictures are presented. The enhanced mechanical properties realized in VARTM processing of BECy-CFRP laminate indicate clear advantage of CNT based modification of the process.

Human Action Recognition in Compressed Domain using PBL-McRBFN Approach

Large variations in human actions lead to major challenges in computer vision research. Several algorithms are designed to solve the challenges. Algorithms that stand apart, help in solving the challenge in addition to performing faster and efficient manner. In this paper, we propose a human cognition inspired projection based learning for person-independent human action recognition in the H.264/AVC compressed domain and demonstrate a PBL-McRBEN based approach to help take the machine learning algorithms to the next level. Here, we use gradient image based feature extraction process where the motion vectors and quantization parameters are extracted and these are studied temporally to form several Group of Pictures (GoP). The GoP is then considered individually for two different bench mark data sets and the results are classified using person independent human action recognition. The functional relationship is studied using Projection Based Learning algorithm of the Meta-cognitive Radial Basis Function Network (PBL-McRBFN) which has a cognitive and meta-cognitive component. The cognitive component is a radial basis function network while the Meta-Cognitive Component(MCC) employs self regulation. The McC emulates human cognition like learning to achieve better performance. Performance of the proposed approach can handle sparse information in compressed video domain and provides more accuracy than other pixel domain counterparts. Performance of the feature extraction process achieved more than 90% accuracy using the PTIL-McRBFN which catalyzes the speed of the proposed high speed action recognition algorithm. We have conducted twenty random trials to find the performance in GoP. The results are also compared with other well known classifiers in machine learning literature.

In-doped multifilled n-type skutterudites with ZT=1.8

In this paper we maximize the thermoelectric (TE) figure of merit, ZT, of n-type skutterudites, (In,Sr,Ba,Yb)(y)Co4Sb12, via three different routes: (i) find the optimum fraction of In as fourth filler (ii) check the influence of powder particle, grain, and crystallite size on the TE properties and (iii) check thermal stability. Filled n-type (Sr, Ba, Yb)(y)Co4Sb12 was mixed in three different proportions with In0.4Co4Sb12, ball milled (regular or high-energy (HB) ball milling) and hot-pressed. Particle size analyses and SEM pictures of the broken surfaces of the hot pressed samples document that only HB produces uniform particles/grains with average crystallite sizes similar to 100 nm, proven by transmission electron microscopy. X-ray Rietveld refinements combined with EDX indicate that in all cases indium entered the icosahedral voids of the skutterudite. Temperature dependent physical properties of all three regularly ball-milled samples show that increasing In-content infers an increasing electrical resistivity, increasing Seebeck coefficient but a decreasing total thermal conductivity. Although ZT (823 K) is in the same range as for the sample without In, the ZT values in the whole temperature range are higher and consequently the TE-conversion efficiency, eta is at least 10% higher. Annealing the samples at 600 degrees C for three days shows minor changes in structure and thermoelectric properties, indicating TE stability. The HB sample, due to uniformly small particles, equally sized grains and crystallites, exhibits a high power factor (4.4 mW/m K-2 at 730 K) and a very low thermal conductivity leading to an outstanding high ZT = 1.8 at 823 K (eta(max) = 17.5%). (C) 2015 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.

Human action recognition in H.264/AVC compressed domain using meta-cognitive radial basis function network

In this paper, we propose a H.264/AVC compressed domain human action recognition system with projection based metacognitive learning classifier (PBL-McRBFN). The features are extracted from the quantization parameters and the motion vectors of the compressed video stream for a time window and used as input to the classifier. Since compressed domain analysis is done with noisy, sparse compression parameters, it is a huge challenge to achieve performance comparable to pixel domain analysis. On the positive side, compressed domain allows rapid analysis of videos compared to pixel level analysis. The classification results are analyzed for different values of Group of Pictures (GOP) parameter, time window including full videos. The functional relationship between the features and action labels are established using PBL-McRBFN with a cognitive and meta-cognitive component. The cognitive component is a radial basis function, while the meta-cognitive component employs self-regulation to achieve better performance in subject independent action recognition task. The proposed approach is faster and shows comparable performance with respect to the state-of-the-art pixel domain counterparts. It employs partial decoding, which rules out the complexity of full decoding, and minimizes computational load and memory usage. This results in reduced hardware utilization and increased speed of classification. The results are compared with two benchmark datasets and show more than 90% accuracy using the PBL-McRBFN. The performance for various GOP parameters and group of frames are obtained with twenty random trials and compared with other well-known classifiers in machine learning literature. (C) 2015 Elsevier B.V. All rights reserved.

Entropy Constrained Exemplar-based Image Inpainting

Image inpainting is the process of filling the unwanted region in an image marked by the user. It is used for restoring old paintings and photographs, removal of red eyes from pictures, etc. In this paper, we propose an efficient inpainting algorithm which takes care of false edge propagation. We use the classical exemplar based technique to find out the priority term for each patch. To ensure that the edge content of the nearest neighbor patch found by minimizing L-2 distance between patches, we impose an additional constraint that the entropy of the patches be similar. Entropy of the patch acts as a good measure of edge content. Additionally, we fill the image by considering overlapping patches to ensure smoothness in the output. We use structural similarity index as the measure of similarity between ground truth and inpainted image. The results of the proposed approach on a number of examples on real and synthetic images show the effectiveness of our algorithm in removing objects and thin scratches or text written on image. It is also shown that the proposed approach is robust to the shape of the manually selected target. Our results compare favorably to those obtained by existing techniques

Heating characteristics of blunt swept fin-induced shock wave turbulent boundary layer interaction

An experimental study was conducted on shock wave turbulent boundary layer interactions caused by a blunt swept fin-plate configuration at Mach numbers of 5.0, 7.8, 9.9 for a Reynolds number range of (1.0.similar to 4.7) x 10(7)/m. Detailed heat transfer and pressure distributions were measured at fin deflection angles of up to 30 degrees for a sweepback angle of 67.6 degrees. Surface oil flow patterns and liquid crystal thermograms as well as schlieren pictures of fin shock shape were taken. The study shows that the flow was separated at deflection of 10 degrees and secondary separation were detected at deflection of theta greater than or equal to 20 degrees. The heat transfer and pressure distributions on flat plate showed an extensive plateau region followed by a distinct dip and local peak close to the fin foot. Measurements of the plateau pressure and heat transfer were in good agreement with existing prediction methods, but pressure and heating peak measurements at M greater than or equal to 6 were significantly lower than predicted by the simple prediction techniques at lower Mach numbers.

El Apocalipsis de Angers (Siglo XIV) : la gestualidad en una obra maestra

Integran este número de la revista ponencias presentadas en Studia Hispanica Medievalia VIII: Actas de las IX Jornadas Internacionales de Literatura Española Medieval, 2008, y de Homenaje al Quinto Centenario de Amadis de Gaula.

Prueba de emparejamiento de unidades fonológicas a partir de dibujos : diferencias de rendimiento entre niños prelectores de distinto estrato socioeconómico

Resumen: Este trabajo se enmarca en las investigaciones sobre lectura que consideran a la conciencia fonológica como un factor esencial en el aprendizaje lector. Con el objetivo de detectar dificultades en la manipulación de unidades subléxicas de manera temprana un total de 127 niños prelectores de Sala de 4 y Sala de 5 de dos escuelas de distinto nivel socioeconómico realizaron una prueba de emparejamiento de sílabas y fonemas a partir de dibujos. Los resultados muestran diferencias significativas de rendimiento según la unidad evaluada así como entre las escuelas de distinto nivel socioeconómico.

¿Cómo usan las redes sociales los jóvenes de Latinoamérica?

Resumen: La difusión de las redes sociales en Internet ha pasado a formar parte de la vida cotidiana de los jóvenes. Las motivaciones que guían la elección de algunas de ellas, la frecuencia de uso y su impacto en el consumo de medios de comunicación tradicionales conforman el núcleo de este trabajo. Los jóvenes mostraron estar familiarizados con los fines y aplicaciones de las diferentes redes sociales, aunque en su gran mayoría eligen Facebook como su favorita. Manifiestan que, en términos generales, las redes sociales ofrecen una forma de comunicación completa, ya que permiten compartir texto, fotos, videos y enlaces, y estar en contacto permanente con familiares, amigos y conocidos

El Matadero de Esteban Echeverría, o la inauguración de los mataderos

Resumen: En el presente texto retomamos y reconocemos el carácter de ‘texto fundante’ que El Matadero de Esteban Echeverría tiene en nuestra cultura argentina. Analizamos lo enraizado del texto conectándolo hacia atrás, con los orígenes de la gauchesca, y hacia adelante, con su culminación y con sus proyecciones, incluso en diversas disciplinas. Luego podemos centrarnos en el tema de la violencia como recurrente no solo literario, y precisar el sentido en que la tomamos. Sostenemos que la violencia de El Matadero ya estaba presente, de manera velada, en otras obras de Echeverría; no tanto por su tematización, sino porque figurativiza, de manera muy acorde con la ideología románticas, razón y corazón, considerado éste no como exclusiva sede de sentimientos, sino como víscera, y de allí sus equivalentes, como el estómago y el matambre. Esta parte visceral no accede a mayor formulación, porque no entra en el programa de la estética en boga. Desde este punto de vista, releo las quejas debidas al sufrimiento del corazón, y entiendo el llanto y el descontento de otro modo. Hay lamento porque nada, al menos en el terreno literario, brinda salida a ese fondo vivo, no esquemático y que le resulta abyecto, porque encierra un modo y un contenido que no puede reconocer como propios. Asociado con esta cara puesta en sombra, inopinadamente, El matadero vuelve a ser texto fundante, pero de otra parte de la literatura argentina: de lo marginal, que no puede sumarse a proyectos, y que muy pocos dicen.

MILU-CG method and the numerical study on the flow around a rotating circular cylinder

A hybrid finite difference method and vortex method (HDV), which is based on domain decomposition and proposed by the authors (1992), is improved by using a modified incomplete LU decomposition conjugate gradient method (MILU-CG), and a high order implicit difference algorithm. The flow around a rotating circular cylinder at Reynolds number R-e = 1000, 200 and the angular to rectilinear speed ratio alpha is an element of (0.5, 3.25) is studied numerically. The long-time full developed features about the variations of the vortex patterns in the wake, and drag, lift forces on the cylinder are given. The calculated streamline contours agreed well with the experimental visualized flow pictures. The existence of critical states and the vortex patterns at the states are given for the first time. The maximum lift to drag force ratio can be obtained nearby the critical states.

Methodological keys for the acquisition and long-term use of photographic collections representing elements of Heritage

Contributed to: Fusion of Cultures. XXXVIII Annual Conference on Computer Applications and Quantitative Methods in Archaeology – CAA2010 (Granada, Spain, Apr 6-9, 2010)

O acesso aos documentos sigilosos : um estudo das comissões permanentes de avaliação e de acesso nos arquivos brasileiros

Estudo sobre o acesso legal aos documentos de arquivo de caráter sigiloso, mediante mapeamento dos arquivos públicos que, no âmbito federal e estadual, instalaram comissões permanentes de acesso/avaliação de documentos sigilosos e/ou outros instrumentos normativos ou informais, que permitem ou dificultam o acesso aos documentos classificados. A legislação arquivística nacional referente aos documentos sigilosos foi sistematizada em quadros, a partir dos assuntos selecionados previamente. Dois modelos de questionário foram elaborados e aplicados nos arquivos públicos ou instituições afins que recolheram documentos de caráter sigiloso. A literatura, no que se refere ao direito à informação, é abundante, mas a abordagem específica sobre acesso aos documentos de caráter sigiloso ainda é incipiente. Na legislação há uma ênfase na normalização de classificação aos documentos de caráter sigiloso em detrimento aos dispositivos de acesso. Os principais autores referenciados nesta pesquisa concordam que o direito à informação situa-se no âmbito dos direitos civis, políticos e sociais, ou seja, o Estado deve comunicar suas atividades e o impacto que estas produzem na sociedade civil, à qual, por sua vez, deve ser assegurado o livre acesso a tais informações. Os limites a este acesso são a segurança do Estado e da sociedade e a proteção à vida privada - temas sempre polêmicos e centrais no debate democrático. A ausência de resposta de algumas instituições deixou lacunas na dissertação e evidencia que a questão do acesso aos documentos sigilosos ainda é uma questão delicada.

Detección de límites arquitectónicos en edificios históricos combinando imágenes digitales con nubes de puntos

[ES] El proyecto estudia algoritmos de detección de bordes aplicados a imágenes fotográficas y procedentes de nubes de puntos, posteriormente combina los resultados y analiza las posibilidades de mejora de la solución conjunta.