Optimització de la tècnica del miralls màgics a partir de mesures de teoria de la informació

La visualització científica estudia i defineix algorismes i estructures de dades que permeten fer comprensibles conjunts de dades a través d’imatges. En el cas de les aplicacions mèdiques les dades que cal interpretar provenen de diferents dispositius de captació i es representen en un model de vòxels. La utilitat d’aquest model de vòxels depèn de poder-lo veure des del punt de vista ideal, és a dir el que aporti més informació. D’altra banda, existeix la tècnica dels Miralls Màgics que permet veure el model de vòxels des de diferents punts de vista alhora i mostrant diferents valors de propietat a cada mirall. En aquest projecte implementarem un algorisme que permetrà determinar el punt de vista ideal per visualitzar un model de vòxels així com també els punts de vista ideals per als miralls per tal d’aconseguir el màxim d’informació possible del model de vòxels. Aquest algorisme es basa en la teoria de la informació per saber quina és la millor visualització. L’algorisme també permetrà determinar l’assignació de colors òptima per al model de vòxels

Abordagem teórico-experimental da teoria do campo cristalino na disciplina de síntese inorgânica

We describe herein the synthesis and characterization of the complexes KNiF3, [Ni(en)3]I2, [Ni(en)3]Cl2, [Ni(acac)2(H2O)2], [Ni(en)2(H2O)2]Cl2 and [Ni(NH3)6](BF4)2 (en = ethylenediamine, acac- = acetylacetonate) performed in the inorganic synthesis major course at the Chemistry Institute of UFRGS (Universidade Federal do Rio Grande do Sul). The compounds were characterized by infrared and electronic spectroscopy and the electrolytic conductivity was measured. The parameters 10Dq and B were obtained from the electronic spectra and the nefelauxetic and spectrochemical series were determined. The obtained spectrochemical series was F- < acac- < NH3 < en and the nefeulaxetic series was en < NH3 < acac- < F-.

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O centenário da Teoria de Bohr

The year 2013 marks the centennial of that wondrous year in which Niels Bohr proposed a novel theory about the constitution of atoms and small molecules after which the way we regard atoms and their behaviour began to be drastically altered. Bohr drew on several sources for his original description of the atoms, most importantly on spectroscopy and Balmer's equation thereof, the new quantum hypothesis advanced a few years earlier by Planck, and the planetary atom proposed by Rutherford. Although Bohr's ideas were to be eventually overtaken by the advent of quantum mechanics, his theory was the basis of a new thinking about atoms and molecules which constitutes an invaluable asset in the development of science ever since.

Contextualizando reações ácido-base de acordo com a teoria protônica de Brönsted-Lowry usando comprimidos de propranolol e nimesulida

This paper reports the use of alternative materials for teaching experimental chemistry. In this context, nimesulide and propranolol tablets were used to teach chemical concepts about acid-base reactions according to Brönsted-Lowry protonic Theory. Important topics of Organic, Analytical and Pharmaceutical Chemistry were discussed, such as purification by acid-base extraction, solubility of organic compounds in aqueous solutions, buffers, the dissociation constant (pKa), potentiometric titration and ionization of drugs in biological fluids. The purification of propranolol and nimesulide from tablets produced yields of 75% and 90%, respectively. The experimental values of pKa for both drugs were in agreement with those from the literature.

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