Comparison of EN & ASME welding and its allied processes standards

This thesis is made in cooperation with Wärtsilä and Sandvik. The main purpose of the thesis is to clarify the best suitable American standards for European standards used in Wärtsilä’s investigation checklist and to make wide and easily readable tables for Wärtsilä and their subcontractors. One of the most important issues is to make clear if the compared American standards are demanding enough for Wärtsilä’s needs. The research is done by comparing EN standards mentioned in Wärtsilä’s investigation checklist to corresponding ASME, AWS, ASNT and ASTM standards. The research shows that there is visible lack of requirements in American standards compared to European ones. Some areas of American standards are more demanding than European standards but in larger scale EN standards are much wider and more demanding than American standards. Because of these reasons, usage of European standards should be recommended for Wärtsilä’s subcontractors to ensure the quality and reliability of production.

Imagen tomada de noche, con luz de flash, donde se puede apreciar la textura de una reja de color blanco, que permite ver a través de ella algunas bicicletas colgadas

Imagen tomada de noche, con luz de flash, donde se puede apreciar la textura de una reja de color blanco, que permite ver a través de ella algunas bicicletas colgadas.

Clemson Sandhill Farmers Market : market flash

This periodical tells about all the activities going on at the Sandhill Farmers Market and other markets in the Columbia area. Many things are hot linked to the market flash including recipes, planting tips, Clemson University and the South Carolina Farmer's Market.

Clemson Sandhill Farmers Market : market flash

This periodical tells about all the activities going on at the Sandhill Farmers Market and other markets in the Columbia area. Many things are hot linked to the market flash including recipes, planting tips, Clemson University and the South Carolina Farmer's Market.

Clemson Sandhill Farmers Market : market flash

This periodical tells about all the activities going on at the Sandhill Farmers Market and other markets in the Columbia area. Many things are hot linked to the market flash including recipes, planting tips, Clemson University and the South Carolina Farmer's Market.

A produção de vinhos finos: um flash do desafio brasileiro.

No Brasil, a viticultura ocupa uma área de aproximadamente 71 mil hectares, com vinhedos estabelecidos desde o extremo sul do País, em latitude de 31 o Sul, até regiões situadas muito próximas ao equador, em latitude de 5 o Sul. Em função da diversidade ambiental, existem no País pólos vitícolas típicos de regiões temperadas, caracterizadas por um período de repouso hibernal; pólos em áreas subtropicais, onde a videira é cultivada com dois ciclos anuais, definidos em função de um período de temperaturas mais baixas, nos quais há risco de geadas; e pólos de viticultura tropical, onde é possível a realização de podas sucessivas, com a realização de dois e meio a três ciclos vegetativos por ano. Nos últimos anos, as estatísticas oficiais registram uma produção de uvas que varia em torno de 1,2 milhão de toneladas por ano. Deste volume, cerca de 45% é destinado ao processamento para a elaboração de vinhos, sucos e outros derivados, e 55% comercializado para o consumo in natura no mercado interno e exportação.

Study and experimental characterization of the laser welding process for the manufacturing of electric powertrain components in the automotive industry

The PhD project that will be presented in this thesis is focused on the study and optimization of the production process for the manufacturing of electrical powertrain components in the automotive field using the laser beam welding process (LBW). The objective is to define, through experimental activities, an optimized process condition for applications in the electrical field that can be generalized, that is, which guarantees its reproducibility as the types of connections vary and which represents the basis for extending the method to future applications in e-mobility sector. The work developed along two lines of research, the convergence of which made it possible to create prototypes of battery modules based on different types of lithium-ion cells and stator windings for electric motors. On the one hand, the different welding configurations involving the production of batteries based on pouch cells and therefore the welding of aluminum and copper in dissimilar configuration were studied, while for the prismatic cells only one configuration was analyzed. On the other hand, the welding of pure copper hairpins with rectangular shape in edge joint configuration was studied for the production of stator windings. The experimental tests carried out have demonstrated the feasibility of using the LBW process for the production of electric powertrain components entirely designed and developed internally as the types of materials and welding configurations vary; the methodologies required for the characterization methods, necessary for the end-of-line tests, for the evaluation of the properties of the different joint configurations and components (battery and electric motor) were also defined with the aim of obtaining the best performance. The entire doctorate program was conducted in collaboration with Ferrari Auto S.p.A. and the direct industrial application of the issues addressed has been faced.

Caratterizzazione in camera climatica dei rivelatori a scintillazione in corso di installazione a M.te Cimone per l’esperimento Gamma-Flash

Questa Tesi di Laurea è legata agli aspetti tecnologici dell'esperimento Gamma-Flash, progetto coordinato dall'Istituto Nazionale di Astrofisica finanziato dall'Agenzia Spaziale Italiana che ha lo scopo di studiare eventi altamente energetici che avvengono in atmosfera denominati Terrestial Gamma-ray Flashes (TGFs). Questi eventi hanno uno stretto legame con i fulmini che avvengono durante episodi temporaleschi. I fulmini producono particelle ionizzate ed elettroni che per effetto bremmstrahlung emettono radiazione in un ampio intervallo di energie da centinaia di keV a decine di MeV. Questo tipo di eventi è stato rivelato da numerose missioni da satellite fin dagli anni '90 (BATSE/CGRO) e successivamente con i satelliti RHESSI, AGILE, BeppoSAX e Fermi. Molto più rare sono le osservazioni di questi eventi da terra o da rivelatori posti su velivoli. Gamma-Flash ha lo scopo di realizzare strumentazione per la rivelazione di questi eventi da un osservatorio posto su M.te Cimone (2165m s.l.m) e su un aereo in grado di raggiungere quote di 8-10000m. L'esperimento viene effettuato attraverso rivelatori a scintillazione e con elettronica dedicata la cui risposta in energia dipende dalla temperatura di funzionamento. È quindi importante conoscere come il detector si comporta al variare della temperatura, che, soprattutto nell'esperimento terrestre, può variare di decine di gradi anche su tempi scala brevi. Scopo di questa tesi è stato quindi di caratterizzare uno dei rivelatori che saranno posti all'Osservatorio O. Vittori di M.te Cimone utilizzando una camera climatica che simula le condizioni di temperatura variabili e riscontrabili durante l'esperimento.

Comparison of full-field electroretinogram in diabetic and non diabetic dogs with cataracts

Being the commonest ocular disorder, dense cataracts disable fundoscopic examination and the diagnosis of retinal disorders, which dogs may be predisposed. The aim of this study was to compare the electroretinographic responses recorded according to the International Society for Clinical Electrophysiology of Vision human protocol to evaluate retinal function of diabetic and non diabetic dogs, both presenting mature or hypermature cataracts. Full-field electroretinogram was recorded from 66 dogs, with ages varying from 6 to 15 years old allocated into two groups: (1) CG, non diabetic cataractous dogs, and (2) DG, diabetic cataractous dogs. Mean peak-to-peak amplitude (microvolts) and b-wave implicit time (milliseconds) were determined for each of the five standard full-field ERG responses (rod response, maximal response, oscillatory potentials, single-flash cone response and 30 Hz flicker). Comparing CG to DG, ERGs recorded from diabetic dogs presented lower amplitude and prolonged b-wave implicit time in all ERG responses. Prolonged b-wave implicit time was statistically significant (p< 0.05) at 30 Hz flicker (24.0 ms versus 22.4 ms). These data suggests full-field ERG is capable to record sensible alterations, such as flicker's implicit time, being useful to investigate retinal dysfunction in diabetic dogs.

Damage assessment of the equine sperm membranes by fluorimetric technique

To validate a practical technique of simultaneous evaluation of the plasma, acrosomal and mitochondrial membranes in equine spermatozoa three fluorescent probes (PI, FITC-PSA and MITO) were associated. Four ejaculates from three stallions (n=12) were diluted in TALP medium and split into 2 aliquots, 1 aliquot was flash frozen in liquid nitrogen to induce damage in cellular membranes. Three treatments were prepared with the following fixed ratios of fresh semen: flash frozen semen: 100:0 (T100), 50:50 (T50), and 0:100 (T0). A 150-µL aliquot of diluted semen of each treatment was added of 2 µL of PI, 2 µL of MITO and 80 µL of FITC-PSA; incubated at 38.5ºC/8 min, and sperm cells were evaluated by epifluorescent microscopy. Based in regression analysis, this could be an efficient and practical technique to assess damage in equine spermatozoa, as it was able to determine the sperm percentage more representative of the potential to fertilize the oocyte.

Sliding wear of weld layers with application to cane mill shaft rebuilding

Three welding procedures used to rebuild worn shafts in sugar cane mills were analysed: two submerged arc welding processes and one flux cored arc welding (FCAW) process. Sliding wear tests were in accordance with ASTM G 77 standard, using rings of welding material, blocks of bronze SAE 67, and oil as lubricant. The worn surfaces of rings and blocks were analysed by scanning electron microscopy to determine the wear mechanisms. High contact pressure, high operating temperature, and low relative speed were applied in sliding wear tests to match the conditions in sugar cane mills. Transferred material and evidence of adhesive junctions were detected. Additionally, hardened fragments produced abrasive grooves on the worn surfaces. The welding deposits that presented strong adhesion on the worn surface showed higher mass loss than the materials that presented more abrasive characteristics. Plastic mechanical properties were measured and related to the mass loss. The tested materials presented similar hardness but different yield stress and hardening coefficient. A relationship between wear, strain hardening coefficient, and yield stress was found. The welding deposit that presented the highest hardening coefficient showed the highest mass loss, with evidence of severe adhesion on the worn surface.

Photophysical properties of a photocytotoxic fluorinated chlorin conjugated to four beta-cyclodextrins

A meso-tetrakis(pentafluorophenyl)-chlorin with the reduced pyrrole ring linked to an isoxazolidine ring (FC) has been conjugated to four beta-cyclodextrins (CDFC). The CDFC exhibits excellent water solubility and is a potent photosensitizer towards proliferating NCTC 2544 human keratinocytes. The study by conventional steady state absorption and fluorescence spectroscopies and by time-resolved femto- and nanosecond laser flash spectroscopies suggests that in ethanol and pH 7 buffer the beta-cyclodextrins embed the highly hydrophobic tetrakis(pentafluorophenyl)-chlorin macrocycle and strongly interact with the chlorin rings in the singlet and triplet manifolds. In these solvents, femtosecond spectroscopy suggests that the conjugate undergoes a rapid relaxation in the upper excited singlet states induced by photochemical and/or conformation change(s) at a rate of about 5 ps(-1) to fluorescent states whose lifetime is similar to 8 ns. This interaction is destroyed upon addition of Triton X100 to buffer. Both FC and CDFC strongly fluoresce (Phi(F) similar to 0.5) in micelles. Similar behavior is observed at the triplet level. In ethanol and water, the initial transient triplet state absorbance decays within 1-3 mu s yielding a longer lived triplet with spectral properties indistinguishable from that of original difference absorbance spectra. The determination of the molar absorbance in the 440-460 nm region (similar to 35 000 M(-1) cm(-1)) leads to an estimate of similar to 0.2 for the triplet formation quantum yield of FC in toluene and of FC and CDFC in Triton X100 micelles. Quenching of the CDFC triplets by dioxygen in buffer produces (1)O(2) in a good yield consistent with the effective photocytotoxicity of the chlorin-cyclodextrins conjugate towards cultured NCTC 2544 human keratinocytes. By contrast, FC which aggregates in buffer produces little if any (1)O(2).

Effect of terbium(III) on the binding of aromatic guests with sodium taurocholate aggregates

The effect of binding Tb(3+) to sodium taurocholate aggregates containing polyaromatic hydrocarbon guests was examined using pyrene and 1-ethylnaphthalene as guests that bind to the primary aggregate, and 1-naphthyl-1-ethanol as a secondary aggregate guest. Time-resolved fluorescence quenching studies were used to study the binding site properties, while laser flash photolysis quenching studies provided information on the dynamics of the guest-aggregate system. Both the primary and secondary aggregate binding sites became more compact in the presence of bound Tb(3+), while only the primary aggregate became more accessible to anionic molecules. The binding dynamics for the guest-primary aggregate system became faster when Tb(3+) was bound to the aggregate. In contrast, for the guest-secondary aggregate the presence of Tb(3+) resulted in a small decrease in the dissociation rate constant. The influence of bound Tb(3+) on the primary and secondary bile salt aggregates is significantly different, which affects how these aggregates can be used as supramolecular host systems to modify guest reactivity.

Thermal diffusivity of polymers by modified angstrom method

The nature of the molecular structure of plastics makes the properties of such materials markedly temperature dependent. In addition, the continuous increase in the utilization of polymeric materials in many specific applications has demanded knowledge of their physical properties, both during their processing as raw material, as well as over the working temperature range of the final polymer product. Thermal conductivity, thermal diffusivity and specific heat, namely the thermal properties, are the three most important physical properties of a material that are needed for heat transfer calculations. Recently, among several different methods for the determination of the thermal diffusivity and thermal conductivity, transient techniques have become the preferable way for measuring thermal properties of materials. In this work, a very simple and low cost variation of the well known Angstrom method is employed in the experimental determination of the thermal diffusivity of some selected polymers. Cylindrical shaped samples 3 cm diameter and 7 cm high were prepared by cutting from long cylindrical commercial bars. The reproducibility is very good, and the results obtained were checked against results obtained by the hot wire technique, laser flash technique, and when possible, they were also compared with data found in the literature. Thermal conductivity may be then derived from the thermal diffusivity with the knowledge of the bulk density and the specific heat, easily obtained by differential scanning calorimetry. (C) 2009 Elsevier Ltd. All rights reserved.