O impacto industrial na composição química das águas subterrâneas com enfoque de consumo humano (Rio Grande, RS)

The alteration in the quality of groundwater in the industrial zone of Brazil's southernmost state was assessed by a hydrogeochemical study. In 70-85% of the studied area, fluoride, nitrate and phosphate in groundwater surpass the maximum limits for human consumption according to Brazilian environmental legislation. The chemical spectrum of contaminants and their spatial distribution show that fertilizer production processes are responsible for groundwater pollution. The natural conditions of the region are not favorable for minimal protection against infiltration of pollutants into the aquifer.

Avaliação de contaminantes inorgânicos e orgânicos em álcool combustível utilizando eletroforese capilar

This work reports the analysis of inorganic and organic contaminants in alcohol fuel samples using capillary electrophoresis. Chloride and sulfate were analyzed in nitrate/ monochloroacetic acid at 10 mmol L-1 concentration each under indirect UV detection (210 nm). The analysis of aldehydes is based on the 216 nm detection of 3-methyl-2-benzothiazoline hydrazone adducts. The running buffer consisted of 20 mmol L-1 tetraborate , 40 mmol L-1 sodium dodecyl sufate and 12 mmol L-1 beta-ciclodextrin. Both methodologies were applied to real samples indicating inorganic ion concentrations from 0.15 to 6.64 mg kg-1 and aldehydes from 32.0 to 91.3 mg L-1.

Active sulphide mine tailings impoundments as sources of contaminated drainage: controlling factors, methods of characterisation and geochemical constraints for mitigation

Low quality mine drainage from tailings facilities persists as one of the most significant global environmental concerns related to sulphide mining. Due to the large variation in geological and environmental conditions at mine sites, universal approaches to the management of mine drainage are not always applicable. Instead, site-specific knowledge of the geochemical behaviour of waste materials is required for the design and closure of the facilities. In this thesis, tailings-derived water contamination and factors causing the pollution were investigated in two coeval active sulphide mine sites in Finland: the Hitura Ni mine and the Luikonlahti Cu-Zn-Co-Ni mine and talc processing plant. A hydrogeochemical study was performed to characterise the tailingsderived water pollution at Hitura. Geochemical changes in the Hitura tailings were evaluated with a detailed mineralogical and geochemical investigation (solid-phase speciation, acid mine drainage potential, pore water chemistry) and using a spatial assessment to identify the mechanisms of water contamination. A similar spatial investigation, applying selective extractions, was carried out in the Luikonlahti tailings area for comparative purposes (Hitura low-sulphide tailings vs. Luikonlahti sulphide-rich tailings). At both sites, hydrogeochemistry of tailings seepage waters was further characterised to examine the net results of the processes observed within the impoundments and to identify constraints for water treatment. At Luikonlahti, annual and seasonal variation in effluent quality was evaluated based on a four-year monitoring period. Observations pertinent to future assessment and mine drainage prevention from existing and future tailings facilities were presented based on the results. A combination of hydrogeochemical approaches provided a means to delineate the tailings-derived neutral mine drainage at Hitura. Tailings effluents with elevated Ni, SO₄ ^2- and Fe content had dispersed to the surrounding aquifer through a levelled-out esker and underneath the seepage collection ditches. In future mines, this could be avoided with additional basal liners in tailings impoundments where the permeability of the underlying Quaternary deposits is inadequate, and with sufficiently deep ditches. Based on the studies, extensive sulphide oxidation with subsequent metal release may already initiate during active tailings disposal. The intensity and onset of oxidation depended on e.g. the Fe sulphide content of the tailings, water saturation level, and time of exposure of fresh sulphide grains. Continuous disposal decreased sulphide weathering in the surface of low-sulphide tailings, but oxidation initiated if they were left uncovered after disposal ceased. In the sulphide-rich tailings, delayed burial of the unsaturated tailings had resulted in thick oxidized layers, despite the continuous operation. Sulphide weathering and contaminant release occurred also in the border zones. Based on the results, the prevention of sulphide oxidation should already be considered in the planning of tailings disposal, taking into account the border zones. Moreover, even lowsulphide tailings should be covered without delay after active disposal ceases. The quality of tailings effluents showed wide variation within a single impoundment and between the two different types of tailings facilities assessed. The affecting factors included source materials, the intensity of weathering of tailings and embankment materials along the seepage flow path, inputs from the process waters, the water retention time in tailings, and climatic seasonality. In addition, modifications to the tailings impoundment may markedly change the effluent quality. The wide variation in the tailings effluent quality poses challenges for treatment design. The final decision on water management requires quantification of the spatial and seasonal fluctuation at the site, taking into account changes resulting from the eventual closure of the impoundment. Overall, comprehensive hydrogeochemical mapping was deemed essential in the identification of critical contaminants and their sources at mine sites. Mineralogical analysis, selective extractions, and pore water analysis were a good combination of methods for studying the weathering of tailings and in evaluating metal mobility from the facilities. Selective extractions with visual observations and pH measurements of tailings solids were, nevertheless, adequate in describing the spatial distribution of sulphide oxidation in tailings impoundments. Seepage water chemistry provided additional data on geochemical processes in tailings and was necessary for defining constraints for water treatment.

Influence of EfOM on the oxidation of micropollutants by Ozone and UV/H2O2 in secondary effluents

The aim of this work was to study the influence of effluent organic matter (EfOM) on micropollutants removal by ozone and UV/H2O2. To perform the experiments, deionized water and municipal secondary effluents (SE) were artificially contaminated with atrazine (ATZ) and treated by the two proposed methods. ATZ concentration, COD and TOC were recorded along the reaction time and used to evaluate EfOM effect on the system efficiency. Results demonstrate that the presence of EfOM can significantly reduce the micropollutant removal rate due to competition of EfOM components to react with radicals and/or molecular ozone. The hydroxyl radical scavenging caused by EfOM was quantified as well as the contribution of molecular ozone and �OH radicals during the ozonation of SE. EfOM components promoted higher inhibition of ATZ oxidation by hydroxyl radicals than by molecular ozone.

The effect of lignin as a natural adhesive on the physico-mechanical properties of Vitis vinifera fiberboards

Lignin was used as a natural adhesive to manufacture Vitis vinifera fiberboards. The fiberboards were produced at laboratory scale by adding powdered lignin to material that had previously been steam-exploded under optimized pretreatment and pressing conditions. The kraft lignin used was washed several times with an acidic solution to eliminate any contaminants and low molecular weight compounds. This research studied the effects of amounts of lignin ranging from 5% to 20% on the properties of Vitis vinifera fiberboards. The fiberboard properties evaluated were density, water resistance in terms of thickness swelling, water absorption, and the mechanical properties in terms of modulus of rupture, modulus of elasticity, and internal bond. Results showed that fiberboards made from Vitis vinifera without lignin addition had weaker mechanical properties. However, the fiberboards obtained using acid-washed kraft lignin as a natural adhesive had good mechanical and water resistance properties that fully satisfied the relevant standard specifications

Uso do Blue Rayon para extração/concentração de compostos policíclicos em amostras ambientais

This is a review about the use of Blue rayon in the extraction and concentration of environmental contaminants in the aquatic environment. Blue rayon is an adsorbent composed of fibers covalently linked with copper phthalocyanine trisulphonate that has the ability to selectively adsorb polycyclic compounds. Blue rayon can be used in situ, in columns or in flasks. This method showed to be efficient in the extraction of important classes of environmental contaminants like the polycyclic aromatic hydrocarbons (PAHs), aromatic amines and phenylbenzotriazoles (PBTAs) and can be an important tool in monitoring studies for the evaluation of water quality.

Pharmaceuticals occurrence in a WWTP with significant industrial contribution and its input into the river system

Occurrence and removal of 81 representative Pharmaceutical Active Compounds (PhACs) were assessed in a municipal WWTP located in a highly industrialized area, with partial water reuse after UV tertiary treatment and discharge to a Mediterranean river. Water monitoring was performed in an integrated way at different points in the WWTP and river along three seasons. Consistent differences between therapeutic classes were observed in terms of influent concentration, removal efficiencies and seasonal variation. Conventional (primary and secondary) treatment was unable to completely remove numerous compounds and UV-based tertiary treatment played a complementary role for some of them. Industrial activity influence was highlighted in terms of PhACs presence and seasonal distribution. Even if global WWTP effluent impact on the studied river appeared to be minor, PhACs resulted widespread pollutants in river waters. Contamination can be particularly critical in summer in water scarcity areas, when water flow decreases considerably

Fundamentos e aplicações ambientais dos processos fenton e foto-fenton

Wastewater and soil treatment processes based on Fenton's reagent have gained great attention in recent years due to its high oxidation power. This review describes the fundaments of the Fenton and photo-Fenton processes and discusses the main aspects related to the degradation of organic contaminants in water such as the complexation of iron, the use of solar light as the source of irradiation and the most important reactor types used. An overview of the main applications of the process to a variety of industrial wastewater and soil remediations is presented.

Frontal gòtic de Sant Llorenç de Morunys. Estudi del suport de fusta: tècnica de construcció i estat de conservació

Estudi preliminar realitzat a partir de la inspecció visual d’un frontal d’altar a les sales de reserva del Museu Diocesà i Comarcal de Solsona, lloc on es custodien les restes del que fou aquesta magnífica obra policromada de tombants del segle XIII executada en l’àmbit del bisbat d’Urgell. Avui en dia, la capa pictòrica ofereix un precari estat de conservació, però encara es conserven els estats preparatoris i una gran part del suport ligni. Les dades per a l’elaboració d’aquest estudi han estat recollides en diferents visites al museu durant els anys 2008-09. El suport del frontal de Sant Llorenç, de fusta de conífera, està constituït per quatre llargues posts disposades en sentit horitzontal que formen un plafó perfectament encaixat dins un marc que, en origen, tancava el conjunt. Actualment, les parts superior i inferior d’aquest marc no existeixen, degut a les nombroses vicissituds sofertes per l’obra al llarg del temps.L’encadellat de totes les peces es resolgué mitjançant espigues o clavilles de fusta, no detectant-se cap unió amb elements metàl·lics. Observant el revers del frontal amb llum rasant, s’aprecien les marques de l’eina que va desgruixar la superfície del suport, l’aixa. Pel sentit dels senyals deixats en la fusta, sembla que cada post va ser desbastada per separat. Després s’uniformaren els gruixos de cadascuna, tot passant un ribot per la zona que toca els cantells i es rebaixà la fusta tocant al perímetre del plafó per a facilitar l’encadellat del marc. Les labors de rebaix i allisat es durien a terme un cop el panell ja estava muntat. L’estat de conservació del suport ligni no és bo. La mancança de les peces superior i inferior del marc afecten l’estabilitat del conjunt que, al no quedar ben travat, acusa certs moviments de les peces amb les manipulacions i els trasllats, moviments que es transmeten també als estrats superiors, portadors de l’escassa policromia. Pel revers de l’obra es poden observar diverses pèrdues, de més o menys entitat, ocasionades per un antic i agressiu atac de xilòfags, de greus conseqüències per l’estructura lígnia, ja que ha debilitat molt les zones perimetrals del frontal, fent-les esdevenir poroses i fràgils.

Interferentes endócrinos no ambiente

Although the hypothesis that environmental chemicals may exhibit endocrine disrupting effects is not new, the issue has been a growing level of concern due to reports of increased incidences of endocrine-related disease in humans, including declining male fertility, and more significantly, to adverse physiological effects observed in wildlife where cause and effect relationships are more evident. The list of endocrine disrupting chemicals (EDCs) includes a range of anthropogenic compounds, phytoestrogens, naturally occurring sex steroids and synthetic estrogens. Within the aquatic environment, the presence of EDCs has concerned many scientists and water quality regulators. Discharge of effluents from treatment facilities is likely to be a significant source of input of contaminants to many systems, and the potential for concentration of hydrophilic compounds and transformation products within sludges has implications for their disposal. Then, understanding the processes and the fate of EDCs on the environment, as well as the mechanisms of endocrine disruption, may facilitate controlling or limiting exposure of both humans and the environment to these compounds.

Compósitos magnéticos baseados em hidrotalcitas para a remoção de contaminantes aniônicos em água

In this work the adsorption features of hydrotalcites (Al, Mg- CO3) and the magnetic properties of iron oxides have been combined in a composite to produce a magnetic adsorbent. These magnetic composites can be used as adsorbents for anionic contaminants in water and subsequently removed from the medium by a simple magnetic process. The magnetic hydrotalcites were characterized by XRD, magnetization measurements, N2 adsorption isotherms and Mössbauer spectroscopy. These magnetic adsorbents show remarkable adsorption capacity for anionic contaminants in water.

Aplicação de radiação UV artificial e solar no tratamento fotocatalítico de efluentes de curtume

Tannery effluents are very dangerous for the environment since they contain large amounts of dangerous and biorecalcitrant contaminants (organic matter and Cr(VI)). This paper reports the efficiency of heterogeneous photocatalysis, based on the application of solar and artificial radiation, furnished by UV lamps, using TiO2 fixed on a flat plate, in the treatment of synthetic effluents. The results of COD and Cr(VI) demonstrate that the use of solar radiation is the most efficient way to perform the photocatalytic treatment of these effluents since a minimum removal of 62 and 61% was observed for Cr(VI) and organic matter, respectively.

El vehicle elèctric: té problemes de comunicació?

Something on the level of pure electric vehicle communication is failing. If the benefits are so obvious: reducing emissions, existing technology, etc., why not EV, start to lead the global sales? Whose interests may be behind it?

Les captacions d'aigua destinada al consum humà al Principat d'Andorra: Anàlisi del marc jurídic actual, definició del procediment d'autorització i sistema d'informació geogràfic sobre les captacions i els perímetres de protecció associats

RESUM L’aigua és un recurs limitat necessari per a l’establiment de qualsevol forma de vida sobre la Terra. Aquest recurs, es veu regit pel cicle hidrològic i durant les diferents fases del seu cicle, l’aigua pot ser captada per ser aprofitada per l’ésser humà. En els darrers anys, la necessitat d’aigua per a la població ha estat incrementada provocant un impacte negatiu sobre aquest recurs. Per aquest motiu sorgeix la necessitat de crear polítiques globals per protegir l’aigua que vagin encaminades a minimitzar l’efecte negatiu provocat per l’home. Tota captació d’aigua destinada al consum humà ha de garantir uns paràmetres de qualitat i per tal de poder aconseguir aquest objectiu amb eficàcia és imprescindible l’aplicació d’una eina legal molt important: els perímetres de protecció. A l’article 6 de la Llei de policia i protecció de les aigües del 31 de juliol del 1985, s’estableix que tota captació d’aigua potable haurà de quedar aïllada mitjançant un perímetre de protecció, a l’interior del qual no podrà dur-se a terme cap activitat sense prèvia autorització de Govern. Els objectius principals d’aquest estudi son recopilar la informació existent en referència a les captacions d’aigua i els seus respectius perímetres de protecció, elaborar una base de dades que pugui contenir tota la informació existent i elaborar cartografia especifica amb la finalitat de realitzar una diagnosi de la situació actual de les captacions i perímetres associats i identificar els principals riscos potencials existents en aquestes àrees. Entre les conclusions mes rellevants obtingudes amb aquest treball, cal destacar que s’ha constatat que algunes activitats antròpiques potencialment contaminants es troben situades en zones properes a les captacions destinades a consum humà, inclòs dins dels seus perímetres de protecció, amb el conseqüent risc que aquesta situació comporta.

Automatització d'un procés de fabricació de peces plàstiques

RESUM L'automatització s'utilitza des de fa molts anys, tot i que va començar a agafar la definició que coneixem actualment al voltant dels anys seixanta i setanta, moment en què es comencen a comercialitzar els primers PLC. A partir d'aquí, el seu creixement ha estat exponencial. En aquest sentit, la tecnologia ha anat avançant i ha augmentat els components que la forma, per això a hores d'ara encara no sabem fins on podrà arribar i què aconseguirà. Per a la indústria tot això ha significat l'automatització de processos que fins ara utilitzaven molt mà d'obra, reduint-la dràsticament. Una de les indústries que més s'ha beneficiat de tots aquests avenços ha estat la de l'automoció, concretament les seves grans línies de producció, automatitzades a uns nivells que fins fa poc temps eren impensables. Aquest projecte forma part d'aquesta indústria, no directament per a la construcció de l'automòbil, sinó indirectament, ja que l'empresa per a la qual s'ha fet l'automatització fabrica peces plàstiques per a automòbils. Concretament, unes peces amb uns injerts metàl•lics conductors que es munten a tots els vehicles i s'utilitzen per accionar els neteja vidres dels cotxes. Aquest fet implica que la fabricació i el disseny de la peça sigui curosament vigilat i controlat per al client final, amb uns controls de qualitat extremadament exigents. El funcionament del procés de fabricació es fa a partir d'unes peces de plàstic produïdes per una injectora que es fan passar per unes estacions automatitzades, cada una de les quals fa una acció concreta per aconseguir el muntatge final.