辽西油松纯林可持续经营途径探讨

Under the direction of Sustainable Development, some key issues of forestry in Western Liaoning Province were analyzed in this paper. "Planting Broad-leaved Trees and Accelerating Conifers" (PBTAC) was put forward as the effective approach to sustainable management on the Pure Plantation of Pinus tabulaeformis and the unique path of forestry sustainable development in Western Liaoning Province. The concept, aim, and notices of "PBTAC" were also analyzed and discussed.

燕儿沟流域水保治理措施优化配置示范研究

作为综合治理试验示范区 ,燕儿沟流域在水土保持技术措施配置中 ,坚持以土地利用结构调整为中心的综合治理方略 ,贯彻强化基本农田建设、退耕还林 (草 )的指导思想 ,强调降雨就近拦蓄 ,合理利用土地 ,减少水土流失 ,取得最大效益。同时 ,在配置实施过程中兼顾退耕与基本农田建设同步 ,发展粮食与水土保持同步的主导思想 ,探索生态环境建设的合理模式 ,并取得了可喜成效

Sol-gel synthesis and characterization of SiO2@NaGd(WO4)(2): Eu3+ core-shell-structured spherical phosphor particles

Monodisperse, core-shell-structured SiO2@NaGd(WO4)(2):Eu3+ particles were prepared by the sol-gel method. The samples were characterized by X-ray diffraction, field emission scanning electron microscopy, transmission electron microscopy, photoluminescence (PL), and low-voltage cathodoluminescence (CL) as well as time-resolved PL spectra and lifetimes. PL and CL study revealed that the core-shell-structured SiO2@NaGd (WO4)(2):Eu3+ particles show strong red emission dominated by the D-5(0) - F-7(2) transition of Eu3+ at 614 nm with a lifetime of 0.74 ms. The PL and CL emission intensity can be tuned by the coating number of NaGd(WO4)(2):Eu3+ phosphor layers on SiO2 and by accelerating voltage and the filament current, respectively.

Luminescence properties of sol-gel derived spherical SiO2@Gd-2(WO4)(3): Eu3+ particles with core-shell structure

Monodisperse, core-shell structured SiO2@Gd-2(WO4)(3):Eu3+ particles were prepared by the sol-gel method. The samples were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy, transmission electron microscopy, photoluminescence (PL) and low-voltage cathodoluntinescence (CL). PL and CL study revealed that the core-shell structured SiO2@Gd-2(WO4)(3):Eu3+ particles show strong red emission dominated by the D-5(0)-F-7(2) transition of Eu3+ at 615 nm with a lifetime of 0.89 ins. The PL and CL emission intensity can be tuned by the coating number of Gd-2(WO4)(3):Eu3+ phosphor layers on SiO2 particles, the size of the SiO2 core particles, and by accelerating voltage and the filament current, respectively.

Miscibility and crystallization behavior of PBT/epoxy blends

The miscibility and the isothermal crystallization kinetics for PBT/Epoxy blends have been studied by using differential scanning calorimetry, and several kinetic analyses have been used to describe the crystallization process. The Avrami exponents n were obtained for PBT/Epoxy blends. An addition of small amount of epoxy resin (3%) leads to an increase in the number of effective nuclei, thus resulting in an increase in crystallization rate and a stronger trend of instantaneous three-dimensional growth. For isothermal crystallization, crystallization parameter analysis showed that epoxy particles could act as effective nucleating agents, accelerating the crystallization of PBT component in the PBT/Epoxy blends. The Lauritzen-Hoffman equation for DSC isothermal crystallization data revealed that PBT/Epoxy 97/3 had lower nucleation constant K, than 100/0, 93/7, and 90/10 PBT/Epoxy blends. Analysis of the crystallization data of PBT/Epoxy blends showed that crystallization occurs in regime II. The fold surface free energy, sigma(e) = 101.7-58.0 x 10(-3) J/m(2), and work of chain folding, q = 5.79-3.30 kcal/mol, were determined. The equilibrium melting point depressions of PBT/Epoxy blends were observed and the Flory-Huggins interaction parameters were obtained.

Mesoscopic simulation of the impregnating process of unidirectional fibrous preform in resin transfer molding

The resin transfer molding has gained popularity in the preparation of fiber-reinforced polymer-matrix composites because of its high efficiency and low pollution. The non-uniform inter-tow and intra-tow flows are regarded as the reason of void formation in RTM. According to the process characteristics, the axisymmetric model was developed to study the interaction between the flow in the inter-tow space and that in the intra-tow space. The flow behavior inside the fiber tows was formulated using Brinkman's equation, while that in the open space around the fiber tows was formulated by Stokes' equation. The volume of fluid (VOF) method was applied to track the flow front, and the effects of filling velocity, resin viscosity, inter-tow dimension and intra-tow permeability on fluid pressure and flow front were analyzed. The results show that the flow front difference between the inter-tow and intra-tow becomes larger with the decrease of intra-tow permeability, as well as the increase of filling velocity and inter-tow dimension.

Partial oxidation of methane to syngas over Pt/A(2)O(3) and Pt/CeO2/Al2O3

The catalytic oxidation of methane to syngas has been carried out over Pt/Al2O3 and Pt/CeO2/Al2O3. It was found that the catalysts with ceria exhibit a higher activity and selectivity than those without ceria. The catalysts were characterized by means of TPR, TPD, SEM-EDX and XRD. There is a strong interaction between ceria and platinum under the reaction condition, which increase the dispersion of platinum over catalysts, preventing the sinter of the Pt particles. As a result of the synergistic;effect between Pt and ceria, the activity of Pt/Al2O3 for combustion reaction was suppressed, the activity and selectivity :For partial oxidation were improved greatly. Another role of ceria in the catalyst is the enhancing of the WGSR, which leads to the increase of the selectivity of catalyst for hydrogen and accelerating the equilibrium of the reaction.

PROMOTER EFFECT OF POLY(4-VINYLPYRIDINE) ON THE DIRECT ELECTRON-TRANSFER BETWEEN CYTOCHROME-C AND GOLD ELECTRODE

The electrochemistry of cytochrome c was studied at the PVP-modified gold electrode. It was found that the promoter effect is related to the amount of PVP at the gold electrode. From our results, it can be seen that the nitrogen element in the polymer is important for accelerating the electron transfer of cytochrome c.

REEVALUATION OF 2,2-BIPYRIDINE AND PYRAZINE AS PROMOTERS FOR DIRECT ELECTRON-TRANSFER BETWEEN CYTOCHROME-C AND METAL-ELECTRODES

Results from previous electrochemical studies have indicated that 2,2'-bipyridine and pyrazine do not function as promoters for heterogeneous electron transfer between cytochrome c and metal electrodes. Their lack of activity was attributed to the improper positioning of the two functional groups in 2,2'-bipyridine and the inefficient length of pyrazine. In the present study it was determined that both 2,2'-bipyridine and pyrazine act as promoters when self-absorbed over a sufficiently long dipping time or at roughened electrodes. The promoter characteristics of these two molecules were studied and compared with those of 4,4'-bipyridine. The difference in their promoter behavior appears to result primarily from their different strengths of adsorption and not because electrodes modified with 2,2'-bipyridine or pyrazine are unsuitable for accelerating direct electron transfer reactions in cytochrome c. These results have implications regarding the mechanism(s) of promoter effects in electrochemical reactions of cytochrome c.

Tidally induced upwelling off Yangtze River estuary and in Zhejiang coastal waters in summer

MASNUM wave-tide-circulation coupled numerical model (MASNUM coupled model, hereinafter) is developed based on the Princeton Ocean Model (POM). Both POM and MASNUM coupled model are applied in the numerical simulation of the upwelling off Yangtze River estuary and in Zhejiang coastal waters in summer. The upwelling mechanisms are analyzed from the viewpoint of tide, and a new mechanism is proposed. The study suggests that the tidally inducing mechanism of the upwelling includes two dynamic aspects: the barotropic and the baroclinic process. On the one hand, the residual currents induced by barotropic tides converge near the seabed, and upwelling is generated to maintain mass conservation. The climbing of the residual currents along the sea bottom slope also contributes to the upwelling. On the other hand, tidal mixing plays a very important role in inducing the upwelling in the baroclinic sea circumstances. Strong tidal mixing leads to conspicuous front in the coastal waters. The considerable horizontal density gradient across the front elicits a secondary circulation clinging to the tidal front, and the upwelling branch appears near the frontal zone. Numerical experiments are designed to determine the importance of tide in inducing the upwelling. The results indicate that tide is a key and dominant inducement of the upwelling. Experiments also show that coupling calculation of the four main tidal constituents(M-2, S-2, K-1, and O-1), rather than dealing with the single M-2 constituent, improves the modeling precision of the barotropic tide-induced upwelling.

中国东部近海温度锋面的分布特征和变化规律

海洋锋面既是各种物理过程，如环流、上升流、混合等的结果，也是这些物理过程的指标，还是影响流场结构、海洋热量和动量交换、海气相互作用以及生物化学过程的重要因素。同时，海洋锋面研究还与海洋产业活动，如海洋渔业、环境保护、海洋倾废等密切相关，也是军事海洋学必须考虑的问题。所以，海洋锋面的研究也成为物理海洋学和海洋交叉学科研究中的一个重要内容。 本研究以中国东部近海（渤海、黄海、东海及南海北部）锋面的分布特征、变化规律、动力机制及对相应过程的影响为研究对象，以1985~2002年AVHRR Pathfinder的卫星海表面温度数据为基础，辅以POM模式，通过数据分析、模式验证和动力机制分析相结合的方法，既全面描述了中国东部近海锋面分布和变化的总体特征，又深入研究了三个典型锋面，即南黄海西部沿岸锋面、黄海暖流源区陆架锋面和东海黑潮陆坡锋面的具体特点，结果如下： 1，中国东部近海温度锋面分布状况的季节变化明显。冬季，锋面丰富，形状规则，位置稳定，可以明确区分出14条沿岸流锋面和暖流锋面。春季及夏初，锋区分布范围广，没有规则的锋面形态，也没有固定的发生区域，不能明确分辨出具体锋面，锋区大体按黑潮流域—长江河口沿岸区域—南黄海区域的方向和渤海—北黄海—南黄海的方向转移。夏季在沿岸区域产生潮汐锋，秋季则很少有锋面出现。对于冬季锋面的位置来讲，沿岸锋面的年际变化小，暖流锋面的年际变化大；受地形限制的锋面年际变化小，脱离地形控制的锋面年际变化大。 2，冬季山东半岛南部（即南黄海西部）温度锋面的完整形态为“N”形，东、西两部分平行岸线和等深线，中间部分跨越等深线。表层以下的黄海沿岸流和黄海暖流及分支是此锋面生成和维持的直接原因：南下沿岸流与北上的黄海暖流形成了锋面的东部部分，反气旋性回流的沿岸流与被沿岸流挟入南黄海西部的黄海暖流暖水及进入南黄海西部的黄海暖流分支形成了锋面的中部和西部部分。通过强烈的垂直混合，此锋面形态特征从表层以下传播到表层。沿岸流和暖流的强弱会影响此锋面的位置，锋面的形成会反过来影响上述流态。冬季风是维持相关环流和锋面结构的间接原因。 3，暖舌西移和双暖舌温度结构是冬季南黄海温度分布的主要特征，黄海暖流源区暖舌南北两侧形成的双锋面是南黄海锋面结构的主要特征，这两条锋面有时也可在西端连为一体，形成环绕黄海暖水舌前锋区的弧形锋面。南侧锋面大致沿长江浅滩边缘，北侧锋面大致呈东西走向，横跨黄海海槽入口，在此锋面的阻挡下，黄海暖舌无法沿海槽中央北上，在两锋面之间沿着黄海海槽西侧进入黄海。统计结果表明，北侧锋面的位置、强度变化，是驱使暖舌沿海槽西侧进入黄海、并控制其西移程度的主要因素。当北侧锋面偏南或强度大时，暖舌西移程度大，当两条锋面间隔距离大时，暖舌的西移程度弱，暖舌主体北侵的程度就越大，双暖舌结构越不明显。源区黄海暖流的东西向质量和热量输运，黄海内部的风应力等通过影响锋面的位置和强度而间接影响暖舌西移程度。黄海暖舌甚至黄海暖流的起源值得进一步探讨。 4，东海黑潮锋在台湾岛东北部和九州岛西南部的平均经向位置之间存在着反位相的年际变化规律。长期观测资料和数值试验结果都表明，进入东海的黑潮流量的改变能够导致黑潮锋面位置在两地反位相的变化：当黑潮流量增大时，黑潮在台湾岛东北部的向陆架入侵减小，锋面向南偏移，而同时黑潮在九州岛西南部的向陆架入侵增大，锋面向北偏移；冬季风应力在台湾岛东北部以东北风为主，在九州岛西南部以西北风为主。当风应力增大时，黑潮锋面在台湾岛东北部向西北偏移，在九州岛西南部向西南方向偏移。黑潮流轴位置的改变也可能是导致反位相变化的原因。位涡输运方程中的地形和斜压联合效应项以及风应力项（主要是Ekman输运）在两地的不同表现可能是控制这种变化的机制。

铜管不锈钢管腐蚀性能及铁牺牲阳极保护研究

铜管一直是电厂凝汽器的主要应用管材，但由于其抗冲刷和抵御污染物腐蚀的能力差，特别不耐氨蚀，美国和欧洲大量使用不锈钢管替代铜管作为冷凝管，然而不锈钢管在我国的运用仅处于初步阶段。 常使用锌、铝阳极对铜管进行牺牲阳极保护，然而存在着电位差过大、阳极溶解过快的问题。铁基牺牲阳极与铜电位差适当、来源广泛、价格便宜，在一些工程上有所应用，但是目前针对铁基牺牲阳极的理论研究报道很少。 本文选用紫铜管、304不锈钢管作为实验用管材，首先运用实验室全浸实验、极化曲线和电化学阻抗研究了二者在海水和淡水中的腐蚀性能以及CO2、溶解氧对其腐蚀的影响。结果表明：CO2会加速二者的腐蚀，溶解氧却对它们的腐蚀影响不同，促进铜管的腐蚀却抑制不锈钢管的腐蚀；随浸泡时间的延长，紫铜管由于表面产物膜的生成耐蚀性提高，304不锈钢管的耐蚀性却降低；淡水中，304不锈钢管和紫铜管都具有很好的耐蚀性能。随后，运用失重法和极化曲线对比研究了紫铜管、304不锈钢管的氨蚀性能，运用SEM分析和电化学阻抗研究了紫铜在不同浓度氨溶液中的腐蚀机理。发现，304不锈钢管的耐氨蚀能力远远好于铜管；溶解氧是影响氨蚀的关键因素，其对二者氨蚀的影响也不同；紫铜管在低氨浓度和高氨浓度溶液中腐蚀机理和产物不同，低氨浓度时形成保护性的产物膜（CuO 和Cu(OH)2），高氨浓度时由活化溶解控制，生成可溶的[Cu (NH3)4]2+。 选用工业纯铁、35钢为牺牲阳极材料。恒电流实验结果表明它们具有良好的牺牲阳极性能；通过极化曲线和自腐蚀电位测试分析，认为将二者用于铜管牺牲阳极保护是可行的；实验室阴极保护效果测试表明，工业纯铁和35钢对紫铜管具有良好的保护效果，保护度达90%以上。

Abundance of Calanus sinicus across the tidal front in the Yellow Sea, China

The abundance of Calanus sinicus eggs, nauplii, copepodites and adults and chlorophyll a (Chl-a) concentration were studied across tidal fronts in October 2000, and May and June 2001 in the Yellow Sea, China. The aim of the study was to evaluate the role of tidal fronts in the ecology of C. sinicus. The hydrographic tidal fronts were identified by the horizontal temperature gradient in the bottom layer and the temperature profiles across the fronts. The survey results showed that the concentration of Chl-a was high in the vicinity of the fronts, particularly in spring and early summer. The abundance of C. sinicus eggs and nauplii was usually higher in the tidal fronts than in the adjacent areas. In May and June 2001, the abundance of copepodites and adults of C. sinicus peaked in the tidal front. In June 2001 and October 2000, many copepodites and adults were found in stratified region.

Environmental changes reflected by sedimentary geochemistry in recent hundred years of Jiaozhou Bay, North China

Sediment geochemical technique was employed to assess how the sediment records reflect the environmental changes of Jiaozhou Bay, a semi-enclosed bay adjacent to Qingdao, China. In the past hundred years, Jiaozhou Bay has been greatly impacted by human interventions. A dated core sediment by Pb-210 chronology was analyzed for trace metals including Li, Cd, Cr, Pb, Cu, Ni, Co, Zn together with C, N, P and BSi. Based on the research, the development of Jiaozhou Bay environment in the past hundred years can be divided into three stages: (1) before the 1980s characterized by relatively low sedimentation rate, weak heavy metal pollution and scarce eutrophication; (2) from the 1980s to 2000, accelerating in the 1990s, during which high sedimentation rates, polluted by heavy metals and the frequent occurrence of red tide; (3) after 2000, the period of the improvement of environment, the whole system has been meliorated including the heavy metal pollution and hypernutrification. (c) 2006 Elsevier Ltd. All rights reserved.

Impact of tidal front on the distribution of bacterioplankton in the southern Yellow Sea, China

Three surveys were carried out in anchovy spawning periods in southern Yellow Sea in May and June 2001, and June 2002. Chlorophyll a (Chl-a) concentration, bacterioplankton abundance, biomass and their variations along the zone of tidal fronts were investigated. The results showed that (1) high Synechococcus abundance distributed more often in frontal area and middle-surface layer of a stratified zone; and (2) the maximal abundance of bacteria occurred in stratified and mixed zone. 2006 Elsevier B.V. All rights reserved.