长效碳铵特性与应用效益研究

<正>我国现有可耕地面积104.5×10~5km~2,人均耕地面积仅8.67hm~2,化肥在粮食增产中的作用约占33.7%.所产氮肥量约16×10~6t(折纯),其中碳铵约占51%.这是我国特有的氮肥品种,含有氮素和二氧化碳,肥效快,不板结土壤,但存在易挥发损失、不易贮存、肥效期短、氮素利用率低和易结成硬块等缺点.研究长效碳铵的目的是减少碳铵的氨挥发,降低转化为硝态氮的淋溶损失,提高氮素利用率与延长肥效期,在减少施肥量条件下能促进作物生长发育.经多年研究证明,该肥料具有明显的氨稳定作用及增加铵态氮在土壤中的贮存量.该项研究查明了使长效碳铵产生较大经济效益的DCD添加量;创建了系统生产法新工艺,从而实现了生产出新型碳铵的目的.

黑土区春小麦群体物质和能量积累研究

利用大田和实验室测定的方法,测定黑土区春小麦群体根、茎、叶、穗等物质和能量在整个生育期的积累过程,旨在为黑土区农业生态系统研究提供实测依据。结果表明,在整个生育期中,春小麦不同器官鲜物质积累的最大值出现的时期各异;除叶和20 cm以下根外,其它器官干物质累积均随生长发育而增加;各器官含水量差异较大,但都随生长而降低;每个器官能量的累积总量并不都是随生长发育而持续增长,且器官间单位干物质所含能量差异较大,变化范围为0.9×10~4 J·g~(-1)(根,孕穗期)至1.5×10~4 J·g~(-1)(叶,三叶期),根、秸秆、籽粒积累的能量分别为6.8×10~5、78.9×10~5和87.9×10~5 J·m~(-2),分别占总积累能量的3.9％、45.4％、50.7％。同实测法相比,计算法获得的秸秆能值高出31％。因此,测定法较计算法能更精确地反映能量在生态系统中的流动。

the estimation of thyroxine in human plasma by an electrophoretic technique

A new method for the determination of thyroxine in blood is described. It relies upon the quantitative dependence of the distribution of thyroxine between albumin and thyroxine-binding protein when exogenous 131I-labelled thyroxine is added to serum in vitro. Preliminary results suggest an accuracy in the estimate of the hormone of about 5–10%. Results in a group of patients whose plasma P.B.I, levels were also determined are given and shown to be similar.

水肥耦合条件下春小麦叶片的光合作用

采用312-D最优饱和设计,在辽宁西部半干旱区进行了田间春小麦光合作用试验研究．结果表明:叶片光合速率与籽粒产量正相关．水肥单因子对叶片光合速率影响的大小顺序是,氮>水>磷．交互耦合作用对叶片光合速率影响的大小顺序为:氮与水耦合>氮与磷耦合>磷与水耦合．水肥耦合促进叶片光合速率提高的主要原因是:扩大了叶面积、提高了叶片蒸腾速率、增大了叶片气孔导度、提高了胞内水浓度、降低了胞内二氧化碳浓度．单叶光合速率高于7．5×10-3μmol／s的水肥优化管理方案是:施氮量为323．4-399．9 kg／hm2、施磷量为65．8-105．7 kg／hm2、灌水量为276．1-353．2 mm．

远紫外辐射对紫杉幼苗针叶膜脂过氧化及内源保护系统的影响

实验室条件下用远紫外线 (UV BC)光源照射紫杉幼苗 ,随照射时间延长 ,针叶的离子渗出率、膜脂过氧化水平、组织自动氧化速率及H2 O2 含量显著增加 ,可溶性蛋白、抗坏血酸、类胡萝卜素和叶绿素含量下降 ,叶绿体光系统II电子传递活性显著下降 ,外源活性氧清除剂苯甲酸钠和抗坏血酸对针叶膜脂过氧化有抑制作用 ;甲基紫精和DDC对针叶膜脂过氧化有促进效果 ,远紫外线引起的紫杉伤害可能和针叶树的越冬光氧化伤害有类似之处 .紫杉苗对紫外辐射的抗性远高于一般农作物 .

农业产业化对农民收入和农户行为的影响:以山东省龙口市为例

农业产业化是当今中国农业发展的热点,但产业化经营究竟能在多大程度上促进"三农"问题的根本转变,目前仍很少有人进行定量研究。文章以农业产业化起步较早的山东省龙口市为案例,通过生产调查和统计资料分析,对该问题做了初步研究。结果表明:尽管龙口市的乡村工业发展迅速且占据了农村经济的绝大部分,但与农民人均纯收入增长关系最为紧密的仍然是农业产业,其次才是农村第二、第三产业,这一结果应归功于农业产业化的发展。农户在家庭劳动力分配时,年老人趋向于从事农业生产,年轻人趋向于从事非农生产,许多农户将自家的劳动力投入到非农产业

Synthesis and properties of soluble poly[bis(benzimidazobenzisoquinolinones)] based on novel aromatic tetraamine monomers

Four aromatic tetraamine monomers possessing flexible ether linkages were successfully synthesized by nucleophilic aromatic substitution of hydroquinone, 4,4'-dihydroxybiphenyl, 2,2'-bis(4-hydroxyphenyl)propane, and 2,7-dihydroxynaphthalene with 5-chloro-2-nitroaniline, followed by reduction, respectively. With these monomers, a new class of soluble poly[ bis(benzimidazobenzisoquinolinones)] was prepared by a one-step, high-temperature solution polycondensation. The resulting polymers were completely soluble in phenolic solvents and had high inherent viscosities ranging from 1.2 to 1.5 g dL(-1). These polymers had glass transition temperatures in the range of 427-449 degrees C. Thermogravimetric analysis showed that all polymers were thermally stable, with 5% weight loss recorded above 510 degrees C in nitrogen.

有序介孔材料SBA-15吸附Ru(bpy)_3~(2+)修饰电极的电化学发光研究

制备了具有高比表面积且二维六方高度有序的介孔分子筛SBA-15,并采用TEM和氮气吸附实验对其结构性质进行了表征.利用静电作用将三联吡啶钌[Ru(bpy)32+]固定到表面带负电荷的SBA-15上,并将吸附有Ru(bpy)32+的SBA-15修饰到玻碳电极表面,研究了该固定化的Ru(bpy)32+的电化学发光行为.结果表明,随着三丙胺(TPA)的加入,氧化电流增加而还原电流减小,表明TPA对三价吡啶钌有催化作用,同时TPA的加入显著增强了发光强度.随着扫描速率的增加,发光强度逐渐降低.SBA-15较大的孔径和开放交联的孔结构体系促进了电极表面膜内的物质扩散和电子运动扩散.该修饰电极在5.0×10-5~1.0×10-2mol/LTPA浓度范围内,发光强度与浓度具有良好的线性关系,线性方程为y=71.7+41.2x,检出限为9.5×10-6mol/L.该电极在连续扫描下具有较好的稳定性.

Phenolphthalein immobilized membrane for an optical pH sensor

A phenolphthalein immobilized cellulose membrane for an optical pH sensor was described. The phenolphthalein was first reacted with the formaldehyde to produce a series of prepolymers with many hydroxymethyl groups. In this paper, the prepolymers was abbreviated to phenolphthalein-formaldehyde (PPF). Then the PPF was covalently immobilized to the diacetylcellulose membrane via hydroxymethyl groups. Finally the membrane was hydrolyzed in the 0.1 M NaOH solution for 24 h to reduce the response time. Advantageous features of the pH-sensitive membrane include (a) a large dynamic range from pH 8.0 to 12.50, or even broader, (b) rapid response time (2-30 s), (c) easy of fabrication, and (d) a promising material for determination of high pH values. The immobilized PPF has a broader dynamic range from 8.0 to 12.50 than the free phenolphthalein from pH 8.0 to 11.0, and this was due to the newly produced methylenes in our investigation.

Syntheses and crystal structures of [Mn(H2O)(4)(bpy)]L center dot 4H(2)O, [Mn(H2O)(4)(bpy)]L ' center dot 4H(2)O (H2L = SUCCINIC ACID, H2L ' = FUMARIC ACID)

Reactions of freshly prepared M(OH)(2-2x)(CO3)(x) (.) yH(2)O (M = Mn, Zn) and 4,4'-bipyridine (bpy) with succinic acid (H2L) or famaric acid (H2L') in CH3OH-H2O afforded [Mn(H2O)(4)(bpy)]L (.) 4H(2)O, 1, [Mn(H2O)(4)(bpy)]L' (.) 4H(2)O, 2 and [Zn(H2O)(4)(bpy)]L (.) 4H(2)O, 3. The three coordination polymers are isostructural and consist of (1)(infinity)[M(H2O)(4)(bpy)(2/2)](2+) cationic chains, crystal H2O molecules and dicarboxylate anions (succinate or fumarate anions). Within the chains, the metal atoms are each octahedrally coordinated by four aqua oxygen atoms and two pyridyl nitrogen atoms from two 4,4'-bipyridine ligands. The crystal H2O molecules are hydrogen bonded to dicarboxylate anions to form ribbon-like anionic chains. The cationic and anionic chains are interconnected via hyqrogen bonds to generate a 3D network. Crystal data: 1 triclinic, P (1) over bar, a = 7.235(1), b = 7.749(2), c = 10.020(2) Angstrom, alpha = 79.95(3), beta = 88.79(3), gamma = 71.39(3)degrees, V = 523.9(2) Angstrom(3) and D-cal = 1.494 g cm(-3) for Z = 1; 2 triclinic, P (1) over bar, a = 7.127(1), b = 7.800(2), c = 9.945(2) Angstrom, alpha = 80.26(3), beta = 87.86(3), gamma = 72.69(3)degrees, V = 520.2(2) Angstrom(3) and D-cal = 1.498 g cm(-3) for Z = 1; 3 triclinic, P (1) over bar, a = 7.189(1), b = 7.764(2), c = 9.843(2) Angstrom, alpha = 79.16(3), beta = 87.80(3), gamma = 71.29(3)degrees, V = 510.9(2) Angstrom(3) and D-cal = 1.559 g cm(-3) for Z = 1.

Synthesis and properties of soluble polyimides based on isomeric ditrifluoromethyl substituted 1,4-bis(4-aminophenoxy)benzene

A new fluorinated diamine monomer, [1,4-bis(4-amino-3-trifluoromethylphenoxy)benzene (2)], and a known isomeric analog 1,4-bis(4-amino-2-trifluoromethylphenoxy)benzene (3) were synthesized. A series of organosoluble polyimides Ia-d and IIa were prepared from the diamines (2, 3) and dianhydrides (a-d) by a high-temperature one-step method. The effects of the trifluoromethyl substituents on the properties of polyimides were evaluated through the study of their soluble, thermal, optical, and gas permeability properties. Polyimides (Ia-d) had glass transition temperatures between 229 and 279 degrees C, and the temperatures at 5% weight loss ranged from 510 to 533 degrees C under nitrogen. These polyimides could be cast into flexible and tough membranes from DMAc solutions. The membranes had tensile strengths in the range of 137-169 MPa, tensile modulus in the range of 1.6-2.2 GPa and elongations at break from 11% to 14%. The polyimide la with trifluoromethyl groups ortho to the imide nitrogen exhibited enhanced gas permeability, solubility, transparency, and thermal stability compared with the isomeric polyimide IIa with the CF3 group meta to the imide nitrogen.