Proposta de metodologia para aplicação de eficiência energética em uma usina hidrelétrica

Pós-graduação em Engenharia Mecânica - FEG

Síntese de nanopartículas de sulfeto de cobre, preparação e estabilidade coloidal de fluidos trocadores de calor em meio aquoso

Pós-graduação em Química - IQ

Análise técnica, econômica e ecológica do uso de biogás em célula a combustível de óxido sólido (SOFC)

Pós-graduação em Engenharia Mecânica - FEG

Recuperação de biomassa bacteriana produzida no tratamento de efluente industrial

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Net power optimization of an irreversible Otto cycle using ECOP and ecological function

This paper presents an analysis of an irreversible Otto cycle aiming to optimize the net power through ECOP and ecological function. The studied cycle operates between two thermal reservoirs of infinite thermal capacity, with internal irreversibilities derived from non-isentropic behavior of compression and expansion processes, irreversibilities from thermal resistance in heat exchangers and heat leakage from the high temperature reservoir to the low temperature reservoir. Analytical expressions are applied for the power outputs optimized by the ECOP, by the ecological function and by the maximum power criteria, in conjunction with a graphic analysis, in which some cycle operation parameters are analyzed for an increased comprehension of the effects of the irreversibilities in the optimized power.

Ecological optimization of an irreversible Brayton cycle with regeneration, inter-cooling and reheating

A mathematical model is developed for an irreversible Brayton cycle with regeneration, inter-cooling and reheating. The irreversibility are from the thermal resistance in the heat exchangers, the pressure drops in pipes, the non-isentropic behavior in the adiabatic expansions and compressions and the heat leakage to the cold source. The cycle is optimized by maximizing the ecological function, which is achieved by the search for optimal values for the temperatures of the cycle and for the pressure ratios of the first stage compression and the first stage expansion. The advantages of using the regenerator, intercooler and reheater are presented by comparison with cycles that do not incorporate one or more of these processes. Optimization results are compared with those obtained by maximizing the power output and it is concluded that the point of maximum ecological function has major advantages with respect to the entropy generation rate and the thermal efficiency, at the cost of a small loss in power.

Aproveitamento energético de uma planta de sulfatação

Pós-graduação em Engenharia Mecânica - FEG

Utilização de trocadores de calor de placas em espiral em processos da indústria siderúrgica

Stricter environmental policies are shown necessary to ensure an effective pollutant emission control. It is expected for the present year of 2015, that Brazil will assume, at the 21th United Nation's Climate Change Conference (COP21), implementation of commitment to a low carbon economy. This positioning affects the industrial environment, so that is deemed necessary to search for new technologies, less aggressive to the environment, so the adequacies to the new emission policies do not cause a negative effect on production. Almost all of the processes performed in the steel industry demand burning fuel and, therefore, flue gases are sent to the atmosphere. In this present work is discussed the utilization of heat exchangers so, by recovering part of the available heat from the flue gases of certain industrial process, the combustion air is preheated. The combustion air preheat results in less energy requirement, i.e., less need of fuel consumption and, in addition, minor amount of pollutants to be emitted. Due to better fitting to the process, it is studied the utilization of spiral plate heat exchangers. The heat exchanger dimensioning is made by an iterative method implemented in the software Microsoft Excel. Subsequently are analyzed the gains in terms of process's thermal efficiency improvement and the percentage of fuel saving. The latter implies in reduction of the same percentage of greenhouse gases emission

Utilização de trocadores de calor de placas em espiral em processos da indústria siderúrgica

Stricter environmental policies are shown necessary to ensure an effective pollutant emission control. It is expected for the present year of 2015, that Brazil will assume, at the 21th United Nation's Climate Change Conference (COP21), implementation of commitment to a low carbon economy. This positioning affects the industrial environment, so that is deemed necessary to search for new technologies, less aggressive to the environment, so the adequacies to the new emission policies do not cause a negative effect on production. Almost all of the processes performed in the steel industry demand burning fuel and, therefore, flue gases are sent to the atmosphere. In this present work is discussed the utilization of heat exchangers so, by recovering part of the available heat from the flue gases of certain industrial process, the combustion air is preheated. The combustion air preheat results in less energy requirement, i.e., less need of fuel consumption and, in addition, minor amount of pollutants to be emitted. Due to better fitting to the process, it is studied the utilization of spiral plate heat exchangers. The heat exchanger dimensioning is made by an iterative method implemented in the software Microsoft Excel. Subsequently are analyzed the gains in terms of process's thermal efficiency improvement and the percentage of fuel saving. The latter implies in reduction of the same percentage of greenhouse gases emission

Anion dopant effects on the structure and performance of polyethersulfone membranes

In this work, the effect of various casting solution salt dopants with similar cations, but different anions: (NaPO3)(6), Na2SO4, Na2CO3, NaCl, and NaF, on the morphology and performance of polyethersulfone ultrafiltration membranes was evaluated. The phase inversion process was used to produce all membranes using an 18% polyethersulfone in n-methylpyrrolidone casting solution and water as the non-solvent. Scanning electron microscopy (SEM) images of the membrane cross-section and surface pores were used to determine the specific anion effects on membrane morphology. The SEM images depicted significant changes to the membrane internal structure and pore size with respect to the type and concentration of the casting solution anion dopant. Membrane permeability, molecular weight cut-off, alginate retention, and susceptibility to fouling were evaluated using ultrapure water dead-end and ultrapure water, aqueous polyethylene glycol, aqueous sodium alginate, and natural surface water cross-flow filtration tests. Among the anions evaluated, hexametaphosphate doped at 1% w/w to the polymer resulted in the membrane with highest dead-end permeability at 490 LMH-bar (2- to 3-fold greater than the control), greatest alginate retention at 96.5%, and lowest susceptibility to fouling. The significant increase in membrane performance indicates that the hexametaphosphate anion has great potential to be used as a membrane casting solution dopant. It was also clearly demonstrated that membrane pore morphological characteristics can be effectively used to predict drinking water treatment performance. (C) 2012 Elsevier B.V. All rights reserved.

Experimental study on vortex-induced motions of a semi-submersible platform with four square columns, Part I: Effects of current incidence angle and hull appendages

An experimental study on Vortex-Induced Motion (VIM) of the semi-submersible platform concept with four square columns is presented. Model tests were carried out to check the influence of different headings and hull appendages (riser supports located at the pontoons; fairleads and the mooring stretches located vertically at the external column faces; and hard pipes located vertically at the internal column faces). The results comprise in-line, transverse and yaw motions, as well as combined motions in the XY plane, drag and lift forces and spectral analysis. The main results showed that VIM in the transverse direction occurred in a range of reduced velocity 4.0 up to 14.0 with amplitude peaks around reduced velocities around 7.0 and 8.0. The largest transverse amplitudes obtained were around 40% of the column width for 30 degrees and 45 degrees incidences. Another important result observed was a considerable yaw motion oscillation, in which a synchronization region could be identified as a resonance phenomenon. The largest yaw motions were verified for the 0 degrees incidence and the maxima amplitudes around 4.5 degrees. The hull appendages located at columns had the greatest influence on the VIM response of the semi-submersible. (C) 2012 Elsevier Ltd. All rights reserved.

Development of enzymic time-temperature integrators with rapid detection for evaluation of continuous HTST pasteurization processes

The assessment of the thermal process impact in terms of food safety and quality is of great importance for process evaluation and design. This can be accomplished from the analysis of the residence time and temperature distributions coupled with the kinetics of thermal change, or from the use of a proper time-temperature integrator (TTI) as indicator of safety and quality. The objective of this work was to develop and test enzymic TTIs with rapid detection for the evaluation of continuous HTST pasteurization processes (70-85 degrees C, 10-60 s) of low-viscosity liquid foods, such as milk and juices. Enzymes peroxidase, lactoperoxidase and alkaline phosphatase in phosphate buffer were tested and activity was determined with commercial reflectometric strips. Discontinuous thermal treatments at various time-temperature combinations were performed in order to adjust a first order kinetic model of a two-component system. The measured time-temperature history was considered instead of assuming isothermal conditions. Experiments with slow heating and cooling were used to validate the adjusted model. Only the alkaline phosphatase TTI showed potential to be used for the evaluation of pasteurization processes. The choice was based on the obtained z-values of the thermostable and thermolabile fractions, on the cost and on the validation tests. (C) 2012 Elsevier Ltd. All rights reserved.

Speciation and fractionation of Ca and the REE in fresh and marine waters

This study is concerned with speciation and fractionation of the rare earth elements (REE) and calcium (Ca) in aqueous solutions. The aim is to investigate the chemical states and physical sizes in which these elements can be present. The REE (including neodymium) and Ca have contrasting geochemical behavior in aqueous solutions. Ca is a major dissolved element, while the REE are trace components and highly reactive with aquatic particles. The major interests of the five papers included in this thesis are the following: · Papers I and V deal with the behavior of neodymium (Nd) and its isotopes in the Kalix River and some marine waters. · The diffusive gradients in thin-films (DGT) method is developed for measuring Ca and Mg in Paper II. · Paper III presents a speciation and fractionation study of Ca in the Kalix and Amazonian rivers. · The rare earth elements and their carrier phases are investigated in the Kalix river in Paper IV. For most elements a detailed study of speciation and fractionation can not be performed using only one method. This is due to the overall heterogeneity of the material, considering both size and chemical composition, which is present in aquatic solutions. During this project the aquatic geochemistry of the REE and Ca has been studied using mainly three methods; cross-flow filtration (CFF), field-flow fractionation (FFF) and diffusive gradients in thin-films (DGT). Field work has to a large part been conducted in the Kalix River, in northern Sweden, which is one of the last pristine river systems in Europe. Some field work has also been conducted in the Baltic Sea and the Arctic Ocean. Results from Amazonian rivers are also presented. These are the main conclusions from this work: The DGT technique works equally well for measuring Ca and Mg in natural waters as previously reported for trace metal. A significant colloidal phase for Ca could be detected in the Kalix River and in different Amazonian rivers. This was concluded independently using both CFF and FFF. Variations in REE signatures in the Kalix River suggests two different pathways for the REE during weathering and release form soil profiles and transport in the river. No significant variation in Nd-isotopic composition could be detected in the Kalix River although concentrations varied by a factor of ~10. This suggests that there is one major source for Nd in the river although different pathways for the REE may exist. A study of Nd in the Kalix River, the Baltic Sea and the Arctic Ocean showed that the isotopic compositions in the diffusible fractions were similar to water samples. However, the relative amount of diffusible Nd increased with salinity, probably reflecting the lower concentration of colloidal and particulate material in marine waters.

Modelli di scambio termico in pozzo sulla base della caratterizzazione geotermica di un reservoir a bassa entalpia: studio di sensitività sulla efficienza dei sistemi di condizionamento a pompa di calore

Tra i temi di attualità, quello del risparmio energetico è tra i più dibattuti negli ultimi anni; tale tema è strettamente correlato al problema del riscaldamento globale, infatti, mentre sul prossimo esaurimento delle risorse energetiche tradizionali non vi sono ancora certezze assolute, per quanto riguarda l’azione nociva dei gas serra, la Comunità Scientifica Internazionale si ritrova d’accordo su una netta presa di posizione contro l’emissione di tali sostanze, provocata in larga parte dall’utilizzo dei combustibili fossili. In questo contesto, l’Unione Europea sta promuovendo la diffusione di tecnologie che non prevedano l’utilizzo di gas, petrolio o carbone, soprattutto per il settore dell’edilizia, ove una corretta progettazione e l’utilizzo di tecnologie non convenzionali può portare alla riduzione anche dell’80% dei consumi, con conseguente abbattimento delle emissioni. Tra questi interventi innovativi, il più comune e conosciuto è sicuramente quello del solare termico e fotovoltaico; ma ne esistono anche di altri, ancora non molto pubblicizzati in Italia, ma ampiamente conosciuti e utilizzati in altri paesi dell’Unione. Tra questi, vi è il sistema di riscaldamento analizzato in questa tesi: la pompa di calore geotermica. Tale sistema, come verrà spiegato nell’elaborato di laurea, ha indubbi vantaggi economici, energetici ed ambientali, a fronte di una non trascurabile spesa iniziale. Attualmente, nel Nord Italia, si incominciano a vedere impianti di questo tipo, sulla scia del successo riscontrato nei paesi confinanti (in particolare Austria e Svizzera). La progettazione si basa attualmente su modelli statici, sviluppati dall’Università Svizzera del Canton Ticino, per l’utilizzo della pompa di calore nel territorio alpino. Obiettivo della tesi, è la verifica di tali modelli, di cui si è venuto a conoscenza grazie alla collaborazione con l’Università SUPSI, sulle condizioni idrogeologiche della Pianura Padana, soffermandosi su alcuni parametri fondamentali della progettazione di una pompa di calore geotermica, quali la conduttività e la capacità termica volumetrica dei terreni incontrati, la presenza di falde, ed i parametri geometrici del pozzo, al fine di dare una valutazione tecnica ed economica dell’impianto. Tali analisi è stata infatti fino ad ora affrontata in maniera sommaria dai perforatori, che eseguono generalmente sempre lo stesso modello di pozzo geotermico, sulla base degli esempi consolidati di Svizzera e Germania. Alcune misure di temperatura in situ sono state rilevate in collaborazione con la società Geotermia SRL di Mantova, ditta specializzata nella perforazione di pozzi geotermici (tale esperienza è parte centrale dell’estratto “Laboratorio di Tesi Ls”), mentre la parte modellistica della tesi è stata sviluppata in collaborazione con lo studio di progettazione Studio Seta SRL di Faenza, il cui stabile è climatizzato in parte con una pompa di calore geotermica.

Sistemi per la climatizzazione mediante pompe di calore geotermiche e pali energetici

We need a large amount of energy to make our homes pleasantly warm in winter and cool in summer. If we also consider the energy losses that occur through roofs, perimeter walls and windows, it would be more appropriate to speak of waste than consumption. The solution would be to build passive houses, i.e. buildings more efficient and environmentally friendly, able to ensure a drastic reduction of electricity and heating bills. Recently, the increase of public awareness about global warming and environmental pollution problems have “finally” opened wide possibility in the field of sustainable construction by encouraging new renewable methods for heating and cooling space. Shallow geothermal allows to exploit the renewable heat reservoir, present in the soil at depths between 15 and 20 m, for air-conditioning of buildings, using a ground source heat pump. This thesis focuses on the design of an air-conditioning system with geothermal heat pump coupled to energy piles, i.e. piles with internal heat exchangers, for a typical Italian-family building, on the basis of a geological-technical report about a plot of Bologna’s plain provided by Geo-Net s.r.l. The study has involved a preliminary static sizing of the piles in order to calculate their length and number, then the project was completed making the energy sizing, where it has been verified if the building energy needs were met with the static solution obtained. Finally the attention was focused on the technical and economical validity compared to a traditional system (cost-benefit analysis) and on the problem of the uncertainty data design and their effects on the operating and initial costs of the system (sensitivity analysis). To evaluate the performance of the thermal system and the potential use of the piles was also used the PILESIM2 software, designed by Dr. Pahud of the SUPSI’s school.