Oxygen-Nonstoichiometric YBaCo4O7+δ as a Catalyst in H2O2 Oxidation of Cyclohexene

Here we present oxygen-nonstoichiometric transition metal oxides as highly prominent candidates to catalyze the industrially important oxidation reactions of hydrocarbons when hydrogen peroxide is employed as an environmentally benign oxidant. The proof-of-concept data are revealed for the complex cobalt oxide, YBaCo4O7+δ (0 < δ < 1.5), in the oxidation process of cyclohexene. In the 2-h reaction experiments YBaCo4O7+δ was found to be significantly more active (>60 % conversion) than the commercial TiO2 catalyst (<20 %) even though its surface area was less than one tenth of that of TiO2. In the 7-h experiments with YBaCo4O7+δ, 100 % conversion of cyclohexene was achieved. Immersion calorimetry measurements showed that the high catalytic activity may be ascribed to the exceptional ability of YBaCo4O7+δ to dissociate H2O2 and release active oxygen to the oxidation reaction.

A Case-base Approach to Workforces’ Satisfaction Assessment

It is well known that human resources play a valuable role in a sustainable organizational development. Indeed, this work will focus on the development of a decision support system to assess workers’ satisfaction based on factors related to human resources management practices. The framework is built on top of a Logic Programming approach to Knowledge Representation and Reasoning, complemented with a Case Based approach to computing. The proposed solution is unique in itself, once it caters for the explicit treatment of incomplete, unknown, or even self-contradictory information, either in terms of a qualitative or quantitative setting. Furthermore, clustering methods based on similarity analysis among cases were used to distinguish and aggregate collections of historical data or knowledge in order to reduce the search space, therefore enhancing the cases retrieval and the overall computational process.