Numerical ages of magnetostratigraphically calibrated biostratigraphic zones at DSDP Leg 73 Holes

Most Cenozoic nannofossil and many foraminiferal zonal boundaries have been accurately determined and magnetostratigraphically calibrated at five Leg 73 boreholes. The numerical ages of the boundaries were computed by assuming a linear seafloor spreading rate and a radiometric age of 66.5 m.y. for the Cretaceous/Tertiary boundary. Alternative magnetostratigraphic ages (given below in parentheses) were obtained by adopting a 63.5 m.y. age for the Cenozoic. Our data confirm previous determinations of the Pleistocene/Pliocene boundary at 1.8 (1.7) m.y. and of the Pliocene/ Miocene boundary at 5.1 (5.0) m.y. The Miocene/Oligocene boundary is placed within Chron C-6C and has a magnetostratigraphic age of 23.8 to 24.0 (22.7 to 22.9) m.y. The Oligocene/Eocene boundary is also very precisely located within Chron C-13-R, with a magnetostratigraphic age of 37.1 to 37.2 (35.5 to 35.6) m.y. The Eocene/Paleocene boundary should be located within an uncored interval of Chron C-24 and have a magnetostratigraphic age of 59.0 (55.4) +/- 0.2 m.y. The general accord of the magnetostratigraphic and radiometric ages supports the hypothesis that the seafloor spreading rate was linear during the Cenozoic. Two possible exceptions are noted: the middle Miocene radiometric ages are a few million years older, and the early Eocene radiometric ages are several million years younger, than the corresponding magnetostratigraphic ages.

Bolboforma of Eocene and lower Oligocene sediments of Maud Rise, Weddell Sea

Five species of Bolboforma have been found in middle Eocene to lower Oligocene sediments from Maud Rise, Weddel Sea, Antarctica (Leg 113, Holes 689B and 690B), the first reported Bolboforma from the Antarctic Paleogene. The previous oldest known occurrences of Bolboforma in the world's oceans were of late Eocene age and this study extends the known range to the middle middle Eocene (~ 44 Ma). Highest species diversity of Bolboforma in the Weddell Sea region of Antarctica occurred during the late Eocene, after which all but one important species disappeared before the Eocene/Oligocene boundary (36.5 Ma). The remaining species, B. irregularis, disappeared soon after, during the earliest Oligocene. The disappearance of Bolboforma in this region of Antarctica coincided with significant climatic cooling that occurred at the end of the Eocene and during the earliest Oligocene, when subpolar replaced temperate conditions. Bolboforma is not known from younger sediments in the Antarctic except for a brief interval during the late early Miocene, an interval of Neogene climatic warmth. The presence of Bolboforma in Eocene to lower Oligocene sequences in the Weddell Sea region of Antarctica is therefore consistent with this taxon's previously recognized association with temperate water masses. Bolboforma is of limited biostratigraphic value at present, because of relatively long stratigraphic ranges and diachronous extinctions. Previous suggestions that Bolboforma represents an encystment stage of phytoplankton require further critical study because the deposition, in large numbers, at paleodepths up to 2250 m in the open ocean, is an unlikely strategy for an encystment phase of a phytoplanktonic organism. A new species, Bolboforma antarctica, is described, exhibiting a stratigraphic range from middle middle Eocene to the upper Eocene (~ 44 to 39 Ma).

Stable isotope record of Globorotalia inflata

We sampled the upper water column for living planktic foraminifera along the SW-African continental margin. The species Globorotalia inflata strongly dominates the foraminiferal assemblages with an overall relative abundance of 70-90%. The shell delta18O and delta13C values of G. inflata were measured and compared to the predicted oxygen isotope equilibrium values (delta18O(eq)) and to the carbon isotope composition of the total dissolved inorganic carbon (delta13C(DIC)) of seawater. The delta18O of G. inflata reflects the general gradient observed in the predicted delta18O(eq) profile, while the delta13C of G. inflata shows almost no variation with depth and the reflection of the delta13C(DIC) in the foraminiferal shell seems to be covered by other effects. We found that offsets between delta18O(shell) and predicted delta18O(eq) in the surface mixed layer do not correlate to changes in seawater [CO3[2-]]. To calculate an isotopic mass balance of depth integrated growth, we used the oxygen isotope composition of G. inflata to estimate the fraction of the total shell mass that is grown within each plankton tow depth interval of the upper 500 m of the water column. This approach allows us to calculate the DELTA delta13C(interval added-DIC); i.e. the isotopic composition of calcite that was grown within a given depth interval. Our results consistently show that the DELTA delta13C(IA-DIC) correlates negatively with in situ measured [CO3[2-]] of the ambient water. Using this approach, we found DELTA delta13C(IA-DIC)/[CO3[2-]] slopes for G. inflata in the large size fraction (250-355 µm) of -0.013 per mil to 0.015 per mil (µmol/kg)**-1 and of -0.013 per mil to 0.017 per mil (µmol/kg)**-1 for the smaller specimens (150-250 µm). These slopes are in the range of those found for other non-symbiotic species, such as Globigerina bulloides, from laboratory culture experiments. Since the DELTA delta13C(IA-DIC)/[CO3[2-]] slopes from our field data are nearly identical to the slopes established from laboratory culture experiments we assume that the influence of other effects, such as temperature, are negligibly small. If we correct the delta13C values of G. inflata for a carbonate ion effect, the delta13C(shell) and delta13C(DIC) are correlated with an average offset of 2.11.

Accumulation rates, carbon composition and Eocene carbonate compensation depths of ODP Sites 199-1218 and 199-1219

CaCO3, Corg, and biogenic SiO2 were measured in Eocene equatorial Pacific sediments from Sites 1218 and 1219, and bulk oxygen and carbon isotopes were measured on selected intervals from Site 1219. These data delineate a series of CaCO3 events that first appeared at ~48 Ma and continued to the Eocene/Oligocene boundary. Each event lasted 1-2 m.y. and is separated from the next by a low CaCO3 interval of a similar time span. The largest of these carbonate accumulation events (CAE-3) is in Magnetochron 18. It began at ~42.2 Ma, lasted until ~40.3 Ma, and was marked by higher than average productivity. The end of CAE-3 was abrupt and was associated with a large-scale carbon transfer to the oceans prior to warming of high-latitude regions. Changes in carbonate compensation depth associated with CAE excursions were small in the early part of the middle Eocene but increased to as much as 800 m by the late middle Eocene before decreasing into the late Eocene. Oxygen isotope data indicate that the carbonate events are associated with cooling conditions and may mark small glaciations in the Eocene.

(Table 2) Geochemistry of K-feldspars and associated plagioclase phenocrysts and rims at DSDP Legs 69, 52, 51 and 19

Basalts from some holes of the Deep Sea Drilling Project contain secondary K-feldspar which forms pseudomorphs after calcic (>76% An) Plagioclase cores, whereas Plagioclase of rims and microlites (68-74% An) remains unaltered. In basalts of Hole 504B two such grains with relics of Plagioclase in the central parts of phenocysts were recovered. The composition of the Plagioclase rims and of non-replaced phenocrysts is An79-81; the composition of relics is An83. The An and Ab contents of the K-feldspar is higher than in K-feldspar from altered basalt in Hole 418A in the Atlantic Ocean near the Bermuda Rise. Replacement of plagioclases by K-feldspar evidently is caused by oxygen-rich nearbottom sea water penetrating into basalts. The temperature interval of K-feldspathization is probably in the range 30 to 80°C, more-calcic Plagioclase being replaced by K-feldspar at higher temperatures.

Pollen analyses of sediment core GeoB9508-5

Millennial-scale dry events in the Northern Hemisphere monsoon regions during the last Glacial period are commonly attributed to southward shifts of the Intertropical Convergence Zone (ITCZ) associated with an intensification of the northeasterly (NE) trade wind system during intervals of reduced Atlantic meridional overturning circulation (AMOC). Through the use of high-resolution last deglaciation pollen records from the continental slope off Senegal, our data show that one of the longest and most extreme droughts in the western Sahel history, which occurred during the North Atlantic Heinrich Stadial 1 (HS1), displayed a succession of three major phases. These phases progressed from an interval of maximum pollen representation of Saharan elements between ~19 and 17.4 kyr BP indicating the onset of aridity and intensified NE trade winds, followed by a millennial interlude of reduced input of Saharan pollen and increased input of Sahelian pollen, to a final phase between ~16.2 and 15 kyr BP that was characterized by a second maximum of Saharan pollen abundances. This change in the pollen assemblage indicates a mid-HS1 interlude of NE trade wind relaxation, occurring between two distinct trade wind maxima, along with an intensified mid-tropospheric African Easterly Jet (AEJ) indicating a substantial change in West African atmospheric processes. The pollen data thus suggest that although the NE trades have weakened, the Sahel drought remained severe during this time interval. Therefore, a simple strengthening of trade winds and a southward shift of the West African monsoon trough alone cannot fully explain millennial-scale Sahel droughts during periods of AMOC weakening. Instead, we suggest that an intensification of the AEJ is needed to explain the persistence of the drought during HS1. Simulations with the Community Climate System Model indicate that an intensified AEJ during periods of reduced AMOC affected the North African climate by enhancing moisture divergence over the West African realm, thereby extending the Sahel drought for about 4000 years.

Age models, ostracods and trace elements of five gravity cores from the NW Black Sea

New Mg/Ca, Sr/Ca, and published stable oxygen isotope and 87Sr/86Sr data obtained on ostracods from gravity cores located on the northwestern Black Sea slope were used to infer changes in the Black Sea hydrology and water chemistry for the period between 30 to 8 ka B.P. (calibrated radiocarbon years). The period prior to 16.5 ka B.P. was characterized by stable conditions in all records until a distinct drop in d18O values combined with a sharp increase in 87Sr/86Sr occurred between 16.5 and 14.8 ka B.P. This event is attributed to an increased runoff from the northern drainage area of the Black Sea between Heinrich Event 1 and the onset of the Bølling warm period. While the Mg/Ca and Sr/Ca records remained rather unaffected by this inflow; they show an abrupt rise with the onset of the Bølling/Allerød warm period. This rise was caused by calcite precipitation in the surface water, which led to a sudden increase of the Sr/Ca and Mg/Ca ratios of the Black Sea water. The stable oxygen isotopes also start to increase around 15 ka B.P., although in a more gradual manner, due to isotopically enriched meteoric precipitation. While Sr/Ca remains constant during the following interval of the Younger Dryas cold period, a decrease in the Mg/Ca ratio implies that the intermediate water masses of the Black Sea temporarily cooled by 1-2°C during the Younger Dryas. The 87Sr/86Sr values drop after the cessation of the water inflow at 15 ka B.P. to a lower level until the Younger Dryas, where they reach values similar to those observed during the Last Glacial Maximum. This might point to a potential outflow to the Mediterranean Sea via the Sea of Marmara during this period. The inflow of Mediterranean water started around 9.3 ka B.P., which is clearly detectable in the abruptly increasing Mg/Ca, Sr/Ca, and 87Sr/86Sr values. The accompanying increase in the d18O record is less pronounced and would fit to an inflow lasting ~100 a.

Compilation of 231Protactinium/230 Thorium excess ratios in various surface sediment samples from the South Atlantic

In large areas of the world's oceans, there is a relationship between the mass flux of particulate matter and the unsupported 231Pa/230Th (xs231Pa/xs230Th) activity ratio of recent sediments. This observation forms the basis for using the xs231Pa/xs230Th ratio as a proxy for past changes in export productivity. However, a simple relationship between xs231Pa/xs 230Th ratio and particle flux requires that the water residence time in an ocean basin is far in excess of the scavenging residence time of 231Pa, and that the composition of sinking particles maintains a strong preference for the adsorption of 230Th over 231Pa with a constant 230Th/231Pa fractionation factor (F). The best correlation between xs231Pa/xs230Th ratio and mass flux is found in the Pacific Ocean. In the Atlantic, the contrast in the xs231Pa/xs230Th ratios between open ocean (low flux regions) and ocean margins (high flux regions) is much less pronounced due to the shorter residence time of deep water, resulting in less effective boundary scavenging of 231Pa. In the Southern Ocean, south of the Polar Front, there is no more a simple relationship between xs231Pa/xs230Th and particle flux. This is a result of a southward decrease in F, probably reflecting the increased opal content of sinking particles. Opal does not fractionate 231Pa and 230Th significantly. This lack of fractionation results in high xs231Pa/xs230Th ratios in opal-dominated regions, even in areas of very low particle fluxes such as the Weddell Sea. The xs231Pa/xs230Th ratio can therefore only be used as a paleoproductivity proxy if, in the time interval of interest, changes in the basin ventilation rate and differential scavenging of both radionuclides due to changes in the chemical composition of particulate matter can be excluded.

Magnetostratigraphy of ODP Leg 138 sites

The aims of this study are twofold. First, the study tries to provide the most reliable chronology possible for two critical sections by correlating the magnetic polarity stratigraphy measured in these sediments with a newly revised geomagnetic polarity time scale. Second, this study attempts to examine in detail the nature of seven short events not included in the shipboard standard time scale, but for which abundant magnetostratigraphic evidence was obtained during the Leg. Data presented here force some modifications of the shipboard interpretations of the magnetostratigraphy of Sites 845 and 844 on the basis of new data generated using discrete samples and from a greater appreciation of the magnetostratigraphic signature of Miocene-age short events. Those short events can be classified into two groups: those that probably reflect short, full-polarity intervals and those that more likely represent an interval of diminished geomagnetic intensity. Three of the seven events documented here correspond well with three subtle features, as seen in marine magnetic profiles, that have been newly included in the geomagnetic polarity time scale as short, full-polarity chrons. One of the seven events corresponds to a poorly defined feature of the marine magnetic record that has also been newly included in the geomagnetic polarity time scale, but which was considered of enigmatic origin. The three remaining events investigated here, although they have not been identified with features in the seafloor magnetic record, are suggested to be events of a similar nature, most likely times of anomalously low geomagnetic intensity. In addition to the Miocene magnetostratigraphic results given, several sets of averaged paleomagnetic inclinations are presented. Although these results clearly show the effects of a residual coring overprint, they demonstrate that paleomagnetic estimates of paleolatitudes can be made which are in good general agreement with ancient site positions calculated using hot spot-based plate reconstructions.

Calcareous dinoflagellates in Maastrichtian to early Miocene sediments of DSDP Hole 39-357

The evolution of calcareous dinoflagellate communities has been investigated for the latest Cretaceous to earliest Neogene interval of the mid-latitude South Atlantic. In doing so, the response of calcareous dinoflagellates to Cenozoic climatic change has been addressed for the first time. Trends in species composition and distribution patterns of wall types indicate significant changes which correlate with major palaeoenvironmental modifications. A first major shift concerning the relative abundance of species and wall types occurred across the Cretaceous-Tertiary boundary. The associations remained stable during the entire Paleocene and Eocene. Only in the late Eocene did a dramatic decrease in temperature cause a slight diversification. A second major shift in the abundance patterns occurred across the Eocene-Oligocene boundary. The early Miocene warming is possibly reflected in the distinct increase in relative abundance of one species. The assemblages of calcareous dinoflagellates evidently react to major climatic changes during the Cenozoic. These poorly investigated organisms may thus provide an important contribution to the understanding of earth's palaeoclimatic evolution.

(Table 3) Stable isotope record of Cretaceous foraminifera from DSDP Hole 44-392A

Mid-Cretaceous (Barremian-Turonian) plankton preserved in deep-sea marl, organic-rich shale, and pelagic carbonate hold an important record of how the marine biosphere responded to short- and long-term changes in the ocean-climate system. Oceanic anoxic events (OAEs) were short-lived episodes of organic carbon burial that are distinguished by their widespread distribution as discrete beds of black shale and/or pronounced carbon isotopic excursions. OAE1a in the early Aptian (~120.5 Ma) and OAE2 at the Cenomanian/Turonian boundary (~93.5 Ma) were global in their distribution and associated with heightened marine productivity. OAE1b spans the Aptian/Albian boundary (~113-109 Ma) and represents a protracted interval of dysoxia with multiple discrete black shales across parts of Tethys (including Mexico), while OAE1d developed across eastern and western Tethys and in other locales during the latest Albian (~99.5 Ma). Mineralized plankton experienced accelerated rates of speciation and extinction at or near the major Cretaceous OAEs, and strontium isotopic evidence suggests a possible link to times of rapid oceanic plateau formation and/or increased rates of ridge crest volcanism. Elevated levels of trace metals in OAE1a and OAE2 strata suggest that marine productivity may have been facilitated by increased availability of dissolved iron. The association of plankton turnover and carbon isotopic excursions with each of the major OAEs, despite the variable geographic distribution of black shale accumulation, points to widespread changes in the ocean-climate system. Ocean crust production and hydrothermal activity increased in the late Aptian. Faster spreading rates [and/or increased ridge length] drove a long-term (Albian-early Turonian) rise in sea level and CO2-induced global warming. Changes in ocean circulation, water column stratification, and nutrient partitioning lead to a reorganization of plankton community structure and widespread carbonate (chalk) deposition during the Late Cretaceous. We conclude that there were important linkages between submarine volcanism, plankton evolution, and the cycling of carbon through the marine biosphere.

Strontium isotope ratios of middle Eocene to Oligocene sediments from Maud Rise, Antarctica

A 87Sr/86Sr isotope curve of the middle Eocene to Oligocene was produced from analysis of foraminifera in Ocean Drilling Program Hole 689B, Maud Rise, near the coast of Antarctica. Sediments from the hole are well preserved with no evidence of diagenetic alteration. The sequence is nearly complete from 46.3 to 24.8 Ma, with an average sampling interval of 166 kyr. Excellent magnetostratigraphy in Hole 689B allows calibration to the geomagnetic polarity time scale of Cande and Kent (1992). Marine strontium isotopic ratios were nearly stable from 46.3 to 35.5 Ma, averaging near 0.70773, after which they began to increase. A slow increase began after 40.4 Ma, rising at a rate of only about 8*10**-6/m.y. from base values of 0.707707. From 35.5 Ma to 24.8 Ma the average slope increased to 40*10**-6/m.y. The slope remained constant at least until 24.8 Ma, when the record becomes discontinuous owing to unconformities. We evaluate several possible controls on the marine strontium isotope curve that could have led to the observed growth in 87Sr/86Sr ratios near the Eocene/Oligocene boundary. Three mechanisms are considered, including the onset of Antarctic glaciation, increased mountain building in the Himalayan-Tibetan region, and decreased hydrothermal activity. None of the mechanisms alone seems to adequately explain the increased 87Sr/86Sr ratios during the Oligocene. Glaciation as a weathering agent was too episodic and probably began too late to explain the upturn in marine 87Sr/86Sr ratios. There is evidence that uplift in the Himalayan-Tibetan region began in the Miocene, much too late to control Oligocene strontium isotope ratios. Lastly, hydrothermal flux changes since the Eocene were apparently not great enough alone to account for the rise in marine 87Sr/86Sr ratios. We suggest that a combination of causes, such as decreased hydrothermal activity perhaps followed by increased glaciation and mountain building, might best explain the growth of the marine 87Sr/86Sr curve during the Oligocene.

Planktonic foraminifera stratigraphy and datums of ODP Site 184-1143 and Hole 184-1146A, South China Sea

The biostratigraphy of Miocene-age sediment samples recovered from Ocean Drilling Program Sites 1143 and 1146, South China Sea, is presented. The preservation of the planktonic foraminifers recovered from both sites varies widely, from poor to very good. The volume of biogenic sediment in the >63-µm size fraction also varies considerably, with many samples being dominated by mud. In comparison to shipboard biostratigraphy, based on core catcher analyses with a depth resolution of ~10 m, we analyzed samples from the two stratigraphic columns every 2-3 m (~45- to 93-k.y. resolution). The placement of planktonic foraminifer zonal boundaries was made at a resolution of ~1.5 m at Site 1146 and ~3.0 m at Site 1143. The higher resolution has resulted in significant changes in biostratigraphic zonal boundary locations compared to shipboard results. For the time interval of 5.54-10.49 Ma, the changes in zonation reveal similar age-depth models at both sites, with three segments of changing sedimentation rate through the upper Miocene, though the differences in sedimentation rates at Site 1146 are subtler than those at Site 1143. The boundary between lithologic Units II and III at Site 1146 corresponds to a sharp change in sedimentation rate (58 to 21 m/m.y.) at 15.1 Ma (the first occurrence of Orbulina suturalis). At this site, the interval from 16.4 to 15.1 Ma is characterized by very high mass accumulation rates in the noncarbonate fraction. Above this interval the carbonate fraction becomes increasingly important in the sediment flux to the South China Sea. At Site 1143, sedimentation rates increase from 8 to 99 m/m.y. at 8.6 Ma. This corresponds to a dramatic increase in both carbonate and noncarbonate mass accumulation rates at the site, but no change in lithology.

Late Cenozoic carbonate accumulation rates of ODP Leg 115 samples

The principal paleoceanographic objective of Ocean Drilling Program Leg 115 was to collect a suite of materials that would allow reconstruction of the dynamic features of the late Cenozoic carbonate system in the equatorial Indian Ocean. This goal was achieved with the recovery of sediments from a closely spaced depth transect (1541-4428 m) of five sites (Sites 707 through 711) from on and around the Mascarene Plateau that record the last 50 m.y. of pelagic deposition. More than 2200 measurements of carbonate content are combined here with a highly resolved bio- and magnetostratigraphy to produce the first detailed compilation of bulk, carbonate, and noncarbonate mass accumulation rates (MARs) from the Indian Ocean. These results allow us to recognize three major depositional intervals, each characterized by a distinct depth-dependent pattern of carbonate accumulation: (1) the Paleogene, a time of moderate accumulation rates (0.4-0.7 g/cm**2/1000 yr) and reduced between-site accumulation differences; (2) the early and middle Miocene, a period characterized by greatly reduced carbonate MARs (typically <0.2 g/cm**2/1000 yr) at all sites and a shallow carbonate compensation depth; and (3) the late Miocene to Holocene, a time span marked by the highest bulk and carbonate accumulation rates of the last 50 Ma (1.6-1.8 g/cm**2/1000 yr), and the first appearance of substantial contrasts in carbonate accumulation as a function of the water depth of the drill site. The fundamentally different character of the carbonate system during each of these intervals must represent a regional response to the complex evolution of late Cenozoic oceans and climate.

Stable foraminifer isotope composition of ODP Site 184-1143, South China Sea

Site 1143 is located at 9°21.72'N, 113°17.11'E, at a water depth of 2772 m within a basin on the southern continental margin of the South China Sea. Three holes were cored at the site and combined into a composite (spliced) stratigraphic section that documents complete recovery for the upper 190.85 meters composite depth, the interval of advanced piston coring (Wang, Prell, Blum, et al., 2000, doi:10.2973/odp.proc.ir.184.2000; Wang et al., 2001, doi:10.1007/BF02907085). The early Pliocene to Holocene sediment sequence provided abundant and well-preserved calcareous microfossils and offered an excellent opportunity to establish foraminiferal stable isotope records. Here, we present benthic and planktonic d18O and d13C records that cover the last 5 m.y. These data sets will provide an important basis for upcoming studies to generate an orbitally tuned oxygen isotope stratigraphy and examine long- and short-term changes in deep and surface water mass signatures (temperature, salinity, and nutrients) with an average sample spacing of ~2.9 k.y. for the benthic and ~2.6 k.y. for the planktonic records.