Radical formation on gamma-radiolysis of poly [(methacrylic acid)-co-acrylonitri

The radicals formed on gamma-radiolysis of a series of copolymers of methacrylic acid and acrylonitrile have been investigated by ESR spectroscopy. This series of copolymers spanned the full composition range and the study was carried out at 77 K and ambient temperature. The radicals formed in the copolymers at 77 and 303 K were found to be similar to those found in the two homopolymers, but in the intermediate composition range the presence of acrylonitrile propagation radicals was also detected. These radicals were not observed to be formed in significant quantities on the radiolysis of polyacrylonitrile. They are believed to result from a scission of the main chain at methacrylic acid/acrylonitrile diad sequences following loss of the methacrylic acid carboxyl group. At 77 K, the copolymers with high methacrylic acid contents were found to be more sensitive to radical formation than the methacrylic acid homopolymer, but this enhanced sensitivity was not evident at ambient temperature, where the G-values for radical formation for the copolymers were slightly less than the values for the homopolymers. (C) 2003 Society of Chemical Industry.

O servidor p??blico brasileiro: uma tipologia da burocracia

As teorias sobre a burocracia governamental e seu comportamento fornecem diferentes abordagens te??ricas e diferentes interpreta????es. A partir da tipologia de agentes burocr??ticos criada por Anthony Downs (1967), esse trabalho analisa os servidores p??blicos federais brasileiros e sua postura face ao trabalho. Com a aplica????o de question??rios a um grupo de servidores, buscou-se verificar a exist??ncia e/ou pertin??ncia dos tipos descritos como alpinistas, conservadores, defensores, militantes e homens de Estado. Os dados obtidos foram tratados pela t??cnica de an??lise de aglomerados. Os resultados encontrados apontam que a tipologia possui limites fluidos entre um perfil de burocrata e outro, acenando para a necessidade de se repensar as concep????es sobre a burocracia governamental e aprofundar os estudos.

A alteridade em Clarice Lispector

Percebendo a presença do tema da alteridade na obra de Clarice Lispector, este estudo o analisa no romance A paixão segundo G. H. e no conto “A mensagem” com respaldo na filosofia existencialista, amparado em Jean-Paul Sartre, Simone de Beauvoir, Frantz Fanon e Søren Kierkegaard e no que hoje seria o desdobramento desse olhar da filosofia existencialista dedicado ao estudo do outro, desdobramento no qual privilegiaremos as reflexões de Pierre Bourdieu, Kwame Anthony Appiah e Jacques Derrida.

O estranhamente familiar na obra de Attilio Colnago

Esta dissertação investiga o unheimlich – em português, 'estranhamente familiar' -, conceito psicanalítico desenvolvido por Sigmund Freud, em obras que fazem parte de 4 (quatro) séries do trabalho do artista plástico Attilio Colnago: "Do Retorno às Meias Verdades", “10 + 1 Perigosas Maneiras de Amar", "Minas das Liberdades Gerais" e "Diálogos com a Paixão". Aproxima as obras do artista – já tão conhecidas por seus aspectos principais tais como a presença da figura humana, os espaços interiores, o sagrado em um contraponto com o profano, e as memórias – do estranhamente familiar. Para tanto, pesquisou-se a bibliografia ligada ao tema, que teve como ponto de partida o ensaio de Freud de 1919, "Das Unheimliche", – traduzido para o português como "O Estranho" – e prosseguiu-se através de escritos de outros autores que se interessam pelo conceito de estranhamente familiar, trazendo-o para a contemporaneidade e associando-o a outras áreas do conhecimento, entre eles Nicholas Royle, Anneleen Masschelein e Anthony Vidler. Com base na teoria estudada foram selecionadas, dentre as séries escolhidas, as obras mais significativas em relação ao tema para serem analisadas. Busca-se desvendar e analisar um lado ainda não investigado da obra do artista e ao mesmo tempo mostrar a importância de se estudar o conceito de estranhamente familiar no campo das artes plásticas.

South-South relations and the English School of International Relations: Chinese and Brazilian ideas and involvement in Sub-Saharan Africa

The rise of large developing countries has led to considerable discussions of re-balancing global relations and giving greater priority to understanding South-South relations. This paper, in exploring the central ideas of Chinese and Brazilian foreign policy and the behavior of these two rising Southern countries toward Sub-Saharan Africa, argues that the English School of International Relations is well suited to understanding the intentions and actions that characterize South-South relations.

Changes in the ways of life of farmers in the northwest of Portugal after 1980

ABSTRACT This study analyzes the changes from 1980s in the lifestyles of families of pluriactive and exclusively agricultural farmers in the northwest of Portugal caused by the income arising from the migration of at least one member of the family to another country in the European Union and the narrowing of the labor and consumer markets among the villages, towns and cities. The theoretical framework used to analyze the changes in the way of life of the pluriactive farmers was based on Giddens' theory of structuration, which denies both the absolute determinism of the structure on the subject and the freedom of unrestrained action of these same subjects. The study was carried out with the application of a survey to 78 farmers, divided into "pluriactive" and "exclusively agricultural" farmers. The findings pointed out to a greater aquisition of modes of urban life by pluriactive farmers compared with the exclusively agricultural farmers and showed a generational bias in this process of acculturation.

Estrutura e ação nas organizações: algumas perspectivas sociológicas

O presente trabalho apresenta uma reflexão teórica sobre a relação objetividade-subjetividade e sua presença no campo de estudos organizacionais, visando a analisar as perspectivas abertas a partir das sínteses teóricas de Giddens e Bourdieu. Expõe algumas contribuições clássicas da teoria organizacional, aprofunda a análise das correntes subjetivistas nos estudos e pesquisas empíricas do campo organizacional, destacando o individualismo metodológico, de forma a considerar a presença significativa dessa corrente nos estudos organizacionais. As contribuições sociológicas de Giddens e Bourdieu são analisadas, sendo que apresentam duas tentativas de síntese no debate objetividade-subjetividade. E, por fim, destaca algumas aplicações dessas perspectivas teóricas no campo de estudo e pesquisa organizacional a partir da visão crítica do pós-modernismo, visando a apontar possíveis perspectivas e limitações.

Vasco da Gama and the Later Portuguese Colonial Presence in India

A chegada de Vasco da Gama à Índia marcou o início de uma nova era na história da Índia e do mundo. Foi um encontro marcado por colaboração e resistências. Tanto os indianos como os portugueses faziam cedências por necessidade ou por conveniências. Não se pode ignorar neste processo o impacto dos renegados portugueses que se espalharam pela Asia toda. Era o resultado da "grande soltura" após a morte de Afonso de Albuquerque que acreditava numa economia comandada. O império da sombra, tão bem descrito por Fernão Mendes Pinto prevaleceu.

Notes on health care planning in Latin America and the Caribbean

Attention is called to the fact that the efforts to improve health of populations in Latin America have generally failed. The inequality in the distribution of ill-health is great. The authors accept the fact that the lack of resources available to the health sector may be a restriction towards the improvement of the situation, but they argue that a much more important issue is the misuse of such resources and their maldistribution within the health sector. The lack of integration and coordination between the health services, the conflict of public and private health systems, the under-utilization of existing services and the gap between planning and real implementation are discussed.

Assessment and prediction of asthma and its severity in the pediatric community

Seventy four asthmatic children aged 7 to 11 years were examined along with controls matched by age and sex. Clinical and laboratory investigations preceded a 28-day follow-up where data about morning and evening peak expiratory flow rate (PEF), symptoms and treatment were recorded. The coefficient of variation of PEF was found to be an objective measurement of asthma severity that has statistically significant correlation with both symptoms (r s= .36) and treatment (r s= .60). Moreover, it separates mild and severe asthmatics, as confirmed by statistically significant differences (p= .008 or less) in symptoms, treatment, skin allergy and airways response to exercise. Skin allergy and airways responsiveness to exercise were found to be predictors of both disease and severity. By means of logistic regression analysis it was possible to establish the probabilities for both asthma and severe asthma when children presenting and not presenting these characteristics are compared. One single positive skin test represent a probability of 88% for the development of asthma and a probability of 70% for severe disease. A PEF reduction of 10% after an exercise test implies a probability of 73% for disease and a probability of 64% for severe disease. Increases in these variables imply geometrically increased risks and their presence together have a multiplicative effect in the final risk.

The social adjustment of patients with schizophrenia: implications to the mental health policy in Brazil

A sample (n=124) of schizophrenic patients from a defined catchment area of the city os S.Paulo, Brazil, who had been consecutively admitted to hospital, was assessed for psychopathological status and social adjustment levels. Sociodemographic, socio-economic and occupational characteristics were recorded: almost 30% of the subjects had no occupation and received no social benefit, more than two-thirds had a monthly per capita income of US$ 100.00 or less. Sixty-five percent presented with Schneiderian firstrank symptoms. Nearly half the sample showed poor or very poor social adjustment in the month prior to admission. The most affected areas of social functioning were participation in the household activities, work and social withdrawal. The current mental health policy of promoting extra-mural care as an alternative to the previous hospital-based model will then mean the investment in a network of new community-based services, that give effective treatment and support to patients and their families. The need of further research into the current picture of mental disorders in the country is stressed.

Mortality among patients with non-affective functional psychoses in a metropolitan area of South-Eastern Brazil

High mortality rates among those suffering from schizophrenia and related psychoses have been consistently described in developed societies. However, to date there is a lack of data on this matter in Brazil. In order to examine this issue, a prospective 2-year follow-up study was carried out in S. Paulo. The sample consisted of 120 consecutive admissions to psychiatric hospitals in a defined catchment area, aged 18 to 44 years old, with clinical diagnoses of non-affective functional psychoses according to the ICD-9. After 2 years, 116 (96.7%) subjects were traced. During the study period there were 7 deaths (6.0% of those traced), 5 (4.3%) due to suicide. All but one of the suicides occurred in the first year after discharge from hospital. Age and sex Standardised Mortality Ratios (relative to rates for the population of the city of Sao Paulo) were 8.4 for overall mortality (95% confidence interval: 4.0-15.9) and 317.9 for deaths due to suicide (95% confidence interval: 125.2-668.3). These results are in agreement with previous studies, and show that in Brazil non-affective functional psychoses are life-threatening illnesses, which need adequate care, particularly when patients go back to live in the community after hospital discharge.

The development of a scale to measure concepts of schizophrenia: experience among Brazilian psychiatrists

INTRODUCTION: Among psychiatric disorders schizophrenia is often said to be the condition with the most disputed definition.The Bleulerian and Schneiderian approaches have given rise to diagnostic formulations that have varied with time and place. Controversies over the concept of schizophrenia were examined within European/North American settings in the early 1970s but little has since been reported on the views of psychiatrists in developing countries. In Brazil both concepts are referred to in the literature. A scale was developed to measure adherence to Bleulerian and Schneiderian concepts among psychiatrists working in S. Paulo. METHODOLOGY: A self-reported questionnaire comprising seventeen visual analogue-scale statements related to Bleulerian and Schneiderian definitions of Shizophrenia, plus sociodemographic and training characteristics, was distributed to a non-randomised sample of 150 psychiatrists. The two sub-scales were assessed by psychometric methods for internal consistency, sub-scale structure and test-retest reliability. Items selected according to internal consistency were examined by a two-factor model exploratory factor analysis. Intraclass correlation coefficients described the stability of the scale. RESULTS: Replies were received from 117 psychiatrists (mean age 36 (SD 7.9)), 74% of whom were made and 26% female. The Schneiderian scale showed better overall internal consistency than the Bleulerian scale. Intra-class correlation coefficients for test-retest comparisons were between 0.5 and 0.7 for Schneiderian items and 0.2 and 0.7 for Bleulerian items. There was no negative association between Bleulerian and Schneiderian scale scores, suggesting that respondents may hold both concepts. Place of training was significantly associated with the respondent's opinion; disagreement with a Bleulerian standpoint predominated for those trained at the University of S. Paulo. CONCLUSIONS: The less satisfactory reliability for the Bleulerian sub-scale limits confidence in the whole scale but on the other hand this questionnaire contributes to the understanding of the controversy over Bleulerian and Schneiderian models for conceptualisation of schizophrenia, the former requiring more inference and therefore being prone to unreliability.