997 resultados para DEI-MS


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Se efectuó un muestreo sistemático paralelo en sentido perpendicular a la cota hasta las 100 y 120 mn. Las área de distribución se realizaron con el programa SURFER. La anchoveta peruana mantuvo predominio en aguas costeras y se registró hasta las 88 mn. Con amplia distribución entre Punta Falsa y el Callao.

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Para efectuar el siguiente estudio se utilizó la técnica hidroacústica, se estimaron las biomasas de onces especies.

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The new-generation nebulizers are commonly used for the administration of salbutamol in mechanically ventilated patients. The different modes of administration and new devices have not been compared. We developed a liquid chromatography-tandem mass spectrometry method for the determination of concentrations as low as 0.05 ng/mL of salbutamol, corresponding to the desired plasma concentration after inhalation. Salbutamol quantification was performed by reverse-phase HPLC. Analyte quantification was performed by electrospray ionization-triple quadrupole mass spectrometry using selected reaction monitoring detection ESI in the positive mode. The method was validated over concentrations ranging from 0.05 to 100 ng/mL in plasma and from 0.18 to 135 ng/mL in urine. The method is precise, with mean inter-day coefficient of variation (CV%) within 3.1-8.3% in plasma and 1.3-3.9% in urine, as well as accurate. The proposed method was found to reach the required sensitivity for the evaluation of different nebulizers as well as nebulization modes. The present assay was applied to examine whether salbutamol urine levels, normalized with the creatinine levels, correlated with the plasma concentrations. A suitable, convenient and noninvasive method of monitoring patients receiving salbutamol by mechanical ventilation could be implemented. Copyright © 2011 John Wiley & Sons, Ltd.

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For more than a decade scientists tried to develop methods capable of dating ink by monitoring the loss of phenoxyethanol (PE) over time. While many methods were proposed in the literature, few were really used to solve practical cases and they still raise much concern within the scientific community. In fact, due to the complexity of ink drying processes it is particularly difficult to find a reliable ageing parameter to reproducibly follow ink ageing. Moreover, systematic experiments are required in order to evaluate how different factors actually influence the results over time. Therefore, this work aimed at evaluating the capacity of four different ageing parameters to reliably follow ink ageing over time: (1) the quantity of solvent PE in an ink line, (2) the relative peak area (RPA) normalising the PE results using stable volatile compounds present in the ink formulation, (3) the solvent loss ratio (R%) calculated from PE results obtained by the analyses of naturally and artificially aged samples, (4) a modified solvent loss ratio version (R%*) calculated from RPA results. After the determination of the limits of reliable measurements of the analytical method, the repeatability of the different ageing parameters was evaluated over time, as well as the influence of ink composition, writing pressure and storage conditions on the results. Surprisingly, our results showed that R% was not the most reliable parameter, as it showed the highest standard deviation. Discussion of the results in an ink dating perspective suggests that other proposed parameters, such as RPA values, may be more adequate to follow ink ageing over time.

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F. 2-183 Temporal (incompl. du début) : — Mystère des bergers (11v) et des rois mages (28v). — Litanies de Rouen (128). F. 183 Dédicace. F. 185v « De s. Audoeno sequentia. » F. 187-237v Sanctoral : — s. Ouen (225) ; — « Festum Romani » (232). F. 237v Commun des saints. F. 263v « Pro defunctis ». F. 264 Kyrie, Gloria, Sanctus, Agnus Dei (XIVe-XVe s.). (Loriquet, Pothier et Collette, Le Graduel de l'église cathédrale de Rouen au XIII e s., 1907, 2 vol., fac-sim. du ms. entier). Cf. De Coussemaker, Drames liturgiques, 235 et 334.

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F. 1 Messes votives et diverses (incompl. du début). F. 2 Messes des ss. Silvestre, Adrien [III], Senèse et Théopompe (dont les reliques étaient à Nonantola). — Addit. XIIIe s. F. 5v Incipit, Préface, Sanctus et Canon jusqu'à l'Agnus Dei. F. 10 Bénédictions épiscopales et ordinations. F. 15v Messes du Temporal et du Sanctoral mêlés : s. Denis (79v). F. 88v Oraisons diverses. F. 101v Messes de la Pentecôte à l'Avent. F. 105 Commun des saints (incompl.). — Addit. XIIIe s. F. 106 Consécration d'église. F. 108 Ordinations. F. 111v Messe pour la dédicace. — Addit. XIe s.

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F. Iv Notice de l'abandon d'un four par « Armannus de Mora » à Saint-Pierre de Moissac, début XIIe s. (Delisle, Anc. sacram., 226). F. 2 Antiphonale missarum. F. 12v-16 et 22-22v Ordo missae, avec préface simple note???e, addit. XIIe s. (Martène, De ant. eccl. rit., I, 537). F. 16v Incipit, Préface et Sanctus notés, Canon jusqu'à l'Agnus Dei, avec Oremus et Pater notés. F. 23 Temporal et Sanctoral mêlés : translat. et fête de s. Vivien (115 et 121v). F. 145 « Ordo ad consecrandum ecclesiam » (Martène, op. cit., II, 728) et « Missa in dedicatione basilicae ». F. 156v Ordinations. F. 167 « Ordo ad ordinandum abbatem vel abbatissam » (ibid., 425-427). F. 169 Oraisons diverses. F. 178 Messes votives : « pro invasione paganorum [Normannorum] » (211v). F. 231v Prières et bénédictions. F. 239v « Ordo ad visitandum infirmum » (Martène, op. cit., I, 870-880), etc. F. 269 Bénédictions épiscopales, avec addit. du XIIe s. (280). F. 282 Oraisons de la messe du Saint-Sépulcre (XIIe s.). F. 283v « Benedictio lectoris » (XIIe s.).