Geochemical compositions of minerals from chilled dike margins of ODP Hole 140-504B

Mineral and whole-rock geochemical data are presented for chilled dike margins from the lower sheeted dike complex of Deep Sea Drilling Project/Ocean Drilling Program (DSDP/ODP) Hole 504B. Compositions of phenocrystic plagioclase (An80-89); olivine (Fo82-86); clinopyroxene (Wo52En40Fs8, with Cr2O3 up to 1.2%); and rare chromian spinel (Cr# 43) are consistent with those from the lavas and the upper dike complex recovered previously (DSDP Legs 69, 70, 83, and ODP Leg 111). Major and trace element compositions fall in group D of Autio and Rhodes (1983) and have high CaO/Na2O, and low TiO2, K2O, and (La/Sm)N values consistent with previous analyses from this site.

Mineralogy and textures of gabbros from ODP Hole 118-735B

Abundant iron-titanium (Fe-Ti) oxide gabbro, olivine gabbro, and troctolite were drilled at Hole 735B adjacent to the Atlantis II Fracture Zone of the Southwest Indian Ridge during Leg 118. The Fe-Ti oxide gabbro occurs as intrusive bodies into olivine gabbro with very sharp intrusive contacts. The size of the intrusive bodies varies from a millimeter to a few tens of meters. Mineralogical parameters, such as anorthite content of plagioclase and Mg/(Mg+Fe) ratios of mafic minerals exhibit bimodal distributions corresponding to olivine and Fe-Ti oxide gabbros, respectively. When the two major gabbro types are looked at separately, several downhole mineralogical cycles are recognized. The Fe-Ti oxide gabbros exhibit two such cycles with plagioclase becoming more sodic and mafic minerals becoming more iron-rich downward in the drill core. The olivine gabbros and troctolites, however, exhibit two cycles showing an upward increase in sodium in plagioclase and iron in mafic minerals. The mineralogical variations of these gabbros and the intrusive contact relationships probably resulted from downward intrusion of evolved magma into underlying solid or almost solidified olivine gabbros and troctolite. The dense evolved melt at the top of the cumulus pile probably formed from the crystallization of olivine gabbro cumulates followed by extreme fractional crystallization of residual melt in an isolated, ephemeral magma chamber. The interlayered occurrence of evolved and primitive gabbros from Hole 735B represents a typical section of lower ocean crust formed at a very slow spreading ridge.

Strontium, oxygen and hydrogen isotope ratios of basalts from DSDP Hole 504B

DSDP Hole 504B was drilled into 6 Ma crust, about 200 km south of the Costa Rica Rift, Galapagos Spreading Center, penetrating 1.35 km into a section that can be divided into four zones-Zone I: oxic submarine weathering; Zone II: anoxic alteration; Zones III and IV: hydrothermal alteration to greenschist facies. In Zone III there is intense veining of pillow basalts. Zone IV consists of altered sheeted dikes. Isotopic geochemical signatures in relation to the alteration zones are recorded in Hole 504B, as follows: Zone Depth(m) Average87Sr/86Sr Average delta18O (?) Average deltaD (?) I 275-550 0.7032 7.3 -63 II 550-890 0.7029 6.5 -45 III 890-1050 0.7035 5.6 -31 IV 1050-1350 0.7032 5.5 -36 Alteration temperatures are as low as 10°C in Zones I and II based on oxygen isotope fractionation. Strontium isotopic data indicate that a circulation of seawater is much more restricted in Zone II than in Zone I. Fluid inclusion measurements of vein quartz indicate the alteration temperature was mainly 300 +/- 20°C in Zones III and IV, which is consistent with secondary mineral assemblages. The strontium, oxygen, and hydrogen isotopic compositions of hydrothermal fluids which were responsible for the greenschist facies alteration in Zones III and IV are estimated to be 0.7037, 2?, and 3?, respectively. Strontium and oxygen isotope data indicate that completely altered portions of greenstones and vein minerals were in equilibrium with modified seawater under low water/rock ratios (in weight) of about 1.6. This value is close to that of the end-member hydrothermal fluids issuing at 21°N EPR. Basement rocks are not completely hydrothermally altered. About 32% of the greenstones in Zones III and IV have escaped alteration. Thus 1 g of fresh basalt including the 32% unaltered portion are required in order to make 1 g of end-member solution from fresh seawater in water-rock reactions.

Geochemical composition of olivine, spinel and amphibole in ODP Hole 209-1271B

Dunite and gabbroic materials recovered from Hole 1271B, Ocean Drilling Program (ODP) Leg 209, were examined for mineral chemistry to understand melt flow and melt-mantle reactions in the shallowest upper mantle of the Mid-Atlantic Ridge near the 15°20' Fracture Zone. Hole 1271B was drilled to 103.8 meters below seafloor on the inner corner high along the south wall of the 15°20' Fracture Zone. The total length of core collected was 15.9 m (recovery = ~15%). The dominant rock type in Hole 1271B is dunite, followed by brown amphibole gabbro, olivine gabbro, and troctolite, along with minor amounts of harzburgite and olivine gabbronorite. A large proportion of the dunite is associated with gabbroic rocks in Hole 1271B, similar to those observed in the Mohorovicic (Moho) transition zone of the Oman ophiolite, indicating significant magmatic activity in this region near the 15°20' Fracture Zone. Olivine Fo content varies from 89.2 to 91.2 in impregnated dunite and from 85.6 to 88.6 in troctolite, olivine gabbro, and olivine gabbronorite. Spinel Cr# (= 100 x Cr/[Cr + Al] molar ratio) ranges from 38.9 to 62.7 in dunite and from 46.3 to 57.6 in troctolites, olivine gabbro, and olivine gabbronorite. Compositional trends for spinel from dunite through troctolite toward olivine gabbro/gabbronorite are characterized by increases in TiO2, Cr#, and Fe3+#, very similar to those reported from Hess Deep Site 895. Olivine gabbro, olivine gabbronorite, and troctolite in Hole 1271B are considered to have formed as hybrid rocks between dunite and an evolved melt in the walls of a melt channel in the shallowest upper mantle that is tens of meters wide. The melt trapped in the wall rock crystallized plagioclase and clinopyroxene. On the other hand, dunite in the center of the melt channel became more refractory by melt-mantle reactions, increasing spinel Cr# to 62.5.

Petrographic and chemical characteristics of diabases at DSDP Holes 63-469 and 63-471

Diabasic rocks were recovered at Sites 469 and 471 on IPOD/DSDP Leg 63. The diabasic rocks are composed mainly of Plagioclase, clinopyroxene, and low-temperature alteration products. In addition to these phases, a considerable amount of primary biotite and lesser colorless amphibole are observed in some of the Site 471 diabases. Major and trace element data suggest that these rocks are tholeiitic; however, their highly altered nature obscures their petrologic affinity with the DSDP Leg 63 tholeiitic basalts and others from the nearby Pacific ocean floor. It is likely that the Site 469 and 471 diabasic rocks represent products of off-ridge intrusive activity.

Composition and structural formulas of ODP Site 200-1224 Eocene ferrobasalt minerals

The ~46-m.y.-old igneous basement cored during Leg 200 in the North Pacific represents one of the few cross sections of Pacific oceanic crust with a total penetration into basalt of >100 m. The rocks, emplaced during the Eocene at a fast-spreading rate (~14 cm/yr; full rate) are strongly differentiated tholeiitic basalts (ferrobasalts) with 7-4.5 wt% MgO, relatively high TiO2 (2-3.5 wt%), and total iron as Fe2O3 (9.1-16.8 wt%). The differentiated character of these lavas is related to unusually large amounts of crystallization differentiation of plagioclase, clinopyroxene, and olivine. The lithostratigraphy of the basement (cored to ~170 meters below seafloor) is divided into three units. The deepest unit (lithologic Unit 3), is a succession of lava flows of no more that a few meters thickness each. The intermediate unit (lithologic Unit 2) is represented by intermixed thin flows and pillows, whereas the shallowest unit (lithologic Unit 1), comprises two massive flows. The rocks range from aphyric to sparsely clinopyroxene-plagioclase-phyric (phenocryst content = <3 vol%) and from holocrystalline to hypohyaline. Chilled margins of pillow fragments show holohyaline to sparsely vitrophyric textures. Site 1224 oxide minerals present a type of alteration not previously seen, where titanomagnetite is only partially destroyed and the pure magnetite component is partially removed from the mineral, leaving, in the most extreme case, a nearly pure ulvöspinel residuum. As a result of this dissolution, iron, mainly in the oxidized state, is added to the circulating solvent fluids. This means that a considerable metal source can result from low-temperature reactions throughout the upper ocean crust. The coarsest-grained lithologic Unit 1 rocks have interstitial myrmekitic intergrowths of quartz and sodic plagioclase (~An12), roughly similar in mineralogy and bulk composition to tonalite/trondhjemite veinlets in abyssal gabbros from the southwest Indian Ocean and Hess Deep, eastern equatorial Pacific. Based on idiomorphic relationships and projections into the simplified Q-Ab-Or-H2O granite ternary system, the myrmekitic intergrowths formed at the same time as, or just after, the oxide minerals coprecipitated and at low water vapor pressure (~0.5 kbar). Their compositions correspond to SiO2-oligoclase intergrowths that are considerably less potassic than dacitic glasses that erupt, although rarely, along the East Pacific Rise or that have been produced experimentally by partial melting of gabbro. Based on the crystallization history and comparison to experimental data, the original interstitial siliceous liquids resulted from late-stage immiscible separation of siliceous and iron-rich liquids. The rare andesitic lavas found along the East Pacific Rise may be hybrid rocks formed by mixing of these immiscible siliceous melts with basaltic magma.

Geochemistry, mineralogy, and 40K-40Ar radiometric dating of DSDP Leg 84 basalts - Guatemala Trench

Geochemical (atomic absorption, neutron activation analyses), mineralogical (microprobe), and radiometric (40K - 40Ar) data are presented for five basalts from the Guatemala Trench area (Deep Sea Drilling Project, Leg 84). Strong geochemical and mineralogical differences distinguish two types among these basalts: (1) One basalt (Sample 567A-19,CC), recovered below Upper Cretaceous limestone has the following characteristics: it is quartz normative and has low TiO2, content, as well as low amounts of Cr, Ni and other transition metals, an LREE depleted pattern, and affinities of clinopyroxene phenocryst plotted into the field of tholeiitic and calc-alkalic pyroxenes. (2) Four alkaline basalts, recovered from the mafic and ultramafic acoustic basement, are nepheline normative and show high TiO2 content, high amounts of Cr, Ni and so on, an LREE enriched pattern and compositions of clinopyroxene phenocryst plotted close to or within the field of alkali basalt pyroxenes. These basalts are comparable to those recognized in the lower part of the Santa Elena complex and are clearly different from the oceanic basalts of the Cocos Plate. The radiometric age of the orogenic basalt seems to be close to 80 Ma. The alkaline basalts are clearly older, even if a discrepancy appears between the results of different analyses because of the secondary effects of alteration.

Chemical composition of soils and rocks from King George Island

Both the olivine-hearing tholeiite basalts of the island and the brown soils which have developed on the basalts contain 2-20% of a swelling clay mineral. It emerges from chemical, optical, X-ray diffraction and differential thermal analytical studies that this clay mineral is a Mg-rich, Fe2+ and AI-bearing tri-octahedral smectite, e. g. Mg-saponite. Due to petrographic and crystal chemical properties the saponite should have been formed by hydrothermal alteration of the primary Mg-Fe-minerals olivine and clinopyroxene. The soils consist of plagioclase, saponite and goethite which has been formed by chemical weathering within the soils. In the uppermost layer some of the soils contain humic substances and phosphatic material, the latter may be related to the recent production of guano.

Mineralogy of silts from the Bengal Fan

Early Miocene to Quaternary sediments drilled from the Bengal Fan are divided into six zones by modal proportions of heavy minerals. The sediments were mostly derived from the Himalayas. Detritus from the Indian subcontinent is found sporadically in clay-rich sediments that were deposited during periods of slow sedimentation, when the deep-sea channel migrated away from the drilled sites. The oldest sediments, ranging from 17 to about 15 Ma, were derived mostly from the Precambrian and Paleozoic sedimentary rocks of the lower Himalayas. At about 15 Ma, metamorphic terrains were eroded in the source area. Further large-scale unroofing of metamorphic rocks occurred around 11 Ma. After 10 Ma, the major constituents in the drainage basin or the drainage pattern changed a few times. Between 3.5 and 0.5 Ma, a large peridotite body was unroofed by uplift and successive erosion of the central Himalayas. At this time, the single large river that had supplied detritus to the early Bengal Fan was divided into the Indus and Ganges rivers.

Geochemistry and petrology of the volcanic rocks from the Sulu Sea

Major-, trace-, and rare-earth element analyses of the basaltic rocks recovered from the basement of the Sulu Sea and of lithic clasts from the pyroclastic unit representing the acoustic basement of the Cagayan Ridge, are presented. The major and trace elements were measured by X-ray fluorescence techniques, and rare-earth elements by instrumental neutron activation analysis. These data show that the Sulu Sea basalts are back-arc tholeiites and the lithic clasts are basalts, basaltic andesites, and andesites typical of volcanic arc suites erupted on continental crust. Petrogenetic modeling is used to show that the Sulu Sea basalts were derived from a heterogeneous mantle, probably representing subcontinental lithosphere, with contributions from a subduction component. The Sulu Sea is interpreted as a back-arc basin formed by rifting of an Oligocene to early Miocene volcanic arc leaving the Cagayan Ridge as a remnant arc. This event occurred during northward subduction of the Celebes Sea basement beneath the Oligocene to early Miocene arc.

Geochemistry and petrogenesis of basalts from DSDP Leg 92 holes

Basalts recovered on DSDP Leg 92 include all the major basalt types so far recovered from the ocean crust of the eastern Pacific. Basalts from Holes 597, 597A, 597B, 597C, and 599B are tholeiites exhibiting all the mineralogical and geochemical characteristics of N-type mid-ocean ridge basalts (MORB). Fragments of ferrobasalts and alkali basalts were also obtained, however, from Holes 60IB and 602B, respectively. Hole 597C, which penetrated 91 m into basement and is the deepest hole so far drilled in fast-spreading crust, yielded basalts that can be divided into three major lithologic units. The lowest unit, Unit III, contains modal olivine and comprises basalts which, at about 8 to 10% MgO, are as basic as any sampled from fast-spreading crust. The middle unit, Unit II, is the most evolved; its basalts are olivine free and contain between 6 and 7.5% MgO. The upper unit, Unit I, is intermediate in composition between Units II and III; it is characterized by both modal olivine and glomerocrysts made up of plagioclase and rare olivine. Unit I is probably a massive flow, whereas Units II and III may be massive flows or sills. The basalts appear to have undergone three stages of alteration ("deuteric," "relatively reducing," and "oxidizing"), the intensity of alteration decreasing markedly downcore. Hole 597B, at 26.4 m of basement penetration the only other "deep" hole, contains just one lithologic unit, which closely resembles Unit I of Hole 597C. Petrogenetic modeling reveals that the three lithologic units in Hole 597C are cogenetic and that they were derived from a depleted mantle source similar to the source of the tholeiites and ferrobasalts sampled in other holes; the alkali basalts are the only rocks derived from enriched mantle. Lavas of Unit III probably lay on the olivine-plagioclase cotectic, whereas the other lavas lay on an olivine-plagioclase-clinopyroxene peritectic. Some 60% of closed-system crystallization is needed to generate the most-evolved from the last-fractionated tholeiite, and a further 50% crystallization (80% overall) is needed to generate the ferrobasalts. Xenocrysts of calcic plagioclase and pseudomorphosed olivine in tholeiites from Hole 597B and Unit I of Hole 597C, and in the ferrobasalts from Hole 601B, provide evidence, however, that some magma mixing may have taken place.