微过氧化物酶-11修饰电极对O_2和H_2O_2的电催化还原

运用电化学循环伏安法和旋转圆盘电极技术研究了O2 和H2O2 在Nafion膜固定的微过氧化物酶 11修饰的玻碳 (MP 11 +Nafion/GC)电极上的电化学还原.结果表明,修饰电极对O2 和H2O2 的还原均具有电催化作用.测定和比较了O2 和H2O2 在MP 11 +Nafion/GC电极上电催化还原反应的一些动力学参数.发现O2 在修饰电极上经历了四电子还原 ,且还原过程与溶液的 pH值有关.

Electrochemistry and spectroscopy study on the interaction of microperoxidase-11 with lipid membrane

The interaction of microperoxidase-11 (MP11) with cationic lipid vesicles of didodecyldimethylammonium bromide (DDAB) induces an alpha -helical conformation from random coil conformations in solution and this change then makes heme macrocycle more distorted. DDAB-induced MP11 conformations were investigated by cyclic votammetry (CV), circular dichroism (CD) and UV-vis spectrometry. All results indicate that the binding of MP11 in solution to DDAB vesicles and the ordered structure formation are driven by mostly electrostatic interaction between negatively charged residues in the undecapeptide and positively charged lipid headgroups on the membrane surface. Upon binding to DDAB, its half-peak potential was also changed. The mechanism of the interaction between MP11 and DDAB was also discussed. (C) 2001 Elsevier Science B.V. All rights reserved.

Morphology of conductive blend fibers of polyaniline and polyamide-11

Polyaniline (PANI), a member of the intrinsically conducting polymer (ICPs) family, was blended with polyamide-11 (polyco-aminoundecanoyle) in concentrated sulfuric acid. The above solution was used to spin conductive PANI/polyamide-11 fibers by wet-spinning technology. Scanning electron microscope (SEM) and transmission electron microscope (TEM) were employed to study the two-phase morphology of the conductive PANI/polyamide-11 fibers. The micrographs of the cross-section, the axial section and the surface of the monofilament demonstrated that the two blend components were incompatible. The morphology of PANI in the fibers was of fibrillar form, which was valuable for producing conducting channels. The electrical conductivity of the fibers was from 10(-6) to 10(-1) S/cm with the different PANI fraction and the percolation threshold was about 5 wt.%. By comparing the two blend systems of PANI/Polyamide-11 fibers and carbon black filled poly(ethylene terephthalate) (PET) fibers, it was shown that the morphology of the conductive component had an influence on electrical conductivity, The former had higher conductivity and lower percolation threshold than the latter. (C) 2001 Elsevier Science B.V. All rights reserved.

Crystal transitions of Nylon 11 under drawing and annealing

The crystal transitions of Nylon 11 annealed and drawn at different temperatures (T-d) with different drawing ratios (n) were investigated by wide-angle X-ray diffraction (WAXD). The alpha -form of Nylon Il could be transformed from the delta'-form by annealing at high temperature, The results showed that the crystal transitions of Nylon 11 strongly depended on the thermal history and the conditions of drawing. The delta'-form Nylon Il could he gradually transformed into the alpha -form when it was drawn at high temperature and the alpha -form was only partly transformed into the delta'-form when it was drawn at low temperature. This should be due to the effect of the competition between thermal inducement and drawing inducement. The thermal inducement was favorable to producing the alpha -form, while the drawing inducement was favorable to producing the delta'-form. (C) 2001 Elsevier Science Ltd. All rights reserved.

LaMAl_(11)O_(19)(M=Mg,Fe)的化学键性质和穆斯堡尔谱研究

利用复杂晶体化学键的平均能带模型研究了LaMAl11O19(M =Mg ,Fe)晶体的化学键性质。结果表明 ,La O键只有 3%的共价性 ,4f1格位却具有很强的共价特征。晶体中各格位共价次序为 :La O

尼龙11结构与性能的研究进展

结合作者的研究工作 ,综述了尼龙 11的物理化学性质、晶体结构、晶型转变及压电性的研究进展

Photoreduction behaviors of microperoxidase-11 adsorbed on the roughened silver electrodes

It was found that microperoxidase-ll (MP-II) can undergo photoreduction at the bale roughened silver electrode. No photoreduction happens at the roughened silver electrode modified with mercaptoundecanoic carboxylic acid/poly-lysine. The photoreduction mechanism is discussed.

Phase transition temperature of HPT(2,3,6,7,10,11-hexa-n-pentyloxytriphenylene) from molecule dynamic simulation

Molecule dynamics simulation was used on HPT(2,3,6,7,10,11-hexa-n-pentyloxytriphenylene), which is a discotic Liquid crystal. From analyzing the energy and displacement varying with the temperature, the phase transition temperature of PM6MPP can be predicted. The deviations of T-g, T-m and T-i due to the MD time scale are small enough that it should be possibly used to predict the material properties especially when more powerful computers are available.

Structure and Conformation of 2,3,6, 7,10,11-hexakispentyloxytriphenylene by TEM and Computer Simulation

Experimental electron diffraction patterns and high resolution images were used to determine the space group and unit cell dimensions of 2,3,6,7,10,11-hexakispentyloxytriphenylene. Subsequently the molecular conformation was calculated by energy minimized package in Cerius2. Using this method, we got the HPT crystal structure: space group: P6/mmm; lattice type: hexogonal; the lattice parameters are a = b = 20.3 angstrom, c = 3.52 angstrom, = = 90 degrees, = 120 degrees. The core of HPT is not perpendicular to the column. The angle between a axis and HPT core plane is 9 degrees which cannot be seen in b-c projection. The simulated ED patterns and HREM images are good agreement with the experimental ED patterns and HREM images.

Isothermal and nonisothermal crystallization kinetics of nylon-11

Analysis of the isothermal, and nonisothermal crystallization kinetics of Nylon-11 is carried out using differential scanning calorimetry. The Avrami equation and that modified by Jeziorny can describe the primary stage of isothermal and nonisothermal crystallization of Nylon-11. In the isothermal crystallization process, the mechanism of spherulitic nucleation and growth are discussed; the lateral and folding surface free energies determined from the Lauritzen-Hoffman equation are sigma = 10.68 erg/cm(2) and sigma(e) = 110.62 erg/cm(2); and the work of chain folding q = 7.61 Kcal/mol. In the nonisothermal crystallization process, Ozawa analysis failed to describe the crystallization behavior of Nylon-ii. Combining the Avrami and Ozawa equations, we obtain a new and convenient method to analyze the nonisothermal crystallization kinetics of Nylon-11; in the meantime, the activation energies are determined to be -394.56 and 328.37 KJ/mol in isothermal and nonisothermal crystallization process from the Arrhonius form and the Kissinger method. (C) 1998 John Wiley & Sons, Inc.

Three dimensional solution structure of neurotoxin CM-11 from the Ophiophagus hannah

The Ophiophagus hannah (King Cobra) neurotoxin CM-11 is a small protein with 72 amino acid residues, Based on complete assignments of H-1-NMR resonances and determination of secondary structures of CM-11, 349 distance and 27 dihedral angle constraints including 19 phi's and 8 chi's were collected from NOESY and DQF-COSY , and the chemical stereospecific assignment of beta(1)H was partially achieved, Twelve structures with lower energy was obtained via metric matrix distance geometry and refinement with simulated annealing, These structures have a low RMSD of 0.14 nm for backbone atoms and 0.20 nm for heavy atoms, with no distance constraint violation more than 0.05 nm, and no dihedral angle violation more than 3 degrees.

甲烷与二氧化碳重整制取合成气反应的研究 (I)Sr_(1-x)La_xNiAl_(11)O_(19)催化剂的物理化学性质表征

合成了具有磁铅石结构的Ｓｒ１－ｘＬａｘＮｉＡｌ１１Ｏ１９系列催化剂，并用ＸＲＤ、ＵＶ－ＤＲＳ、Ｈ２－Ｏ２滴定及Ｐｙ－ＩＲ等方法对其体相及表面性质进行了表征．结果表明，Ｌａ３＋离子能够同晶取代Ｓｒ２＋离子进入催化剂晶格内部；随着Ｌａ３＋含量增加，催化剂的结晶度提高，从而降低了镍的还原性，并使金属镍在表面上的分散度略有提高；在ＳｒＮｉＡｌ１１Ｏ１９中掺入Ｌａ３＋离子，能够抑制晶体沿ｃ轴方向的生长，提高其比表面积；同时Ｌａ３＋离子对Ｓｒ２＋离子的调变，减少了表面的酸中心数目

甲烷与二氧化碳重整制取合成气反应的研究 (I)Sr_(1-x)La_xNiAl_(11)O_(19)催化活性表征

对具有磁铅石结构的Ｓｒ１－ｘＬａｘＮｉＡｌ１１Ｏ１９对甲烷与二氧化碳重整反应的催化活性、积炭量和稳定性进行了研究．不同还原温度下催化剂的ＸＲＤ和催化活性的实验结果表明，金属镍是ＣＨ４＋ＣＯ２重整反应的活性组分，金属镍含量越大，反应活性越高．反应后催化剂积炭量的分析结果说明，在相同镍含量和分散度的情况下，Ｌａ３＋离子对Ｓｒ２＋离子调变，可以降低催化剂的表面酸性，提高催化剂的抗积炭能力．ＬａＮｉＡｌ１１Ｏ１９是一种具有较好催化活性、稳定性和抗积炭性能的催化剂.

十一钼硅钴杂多蓝H_8[SiMo_(11)Co(H_2O)O_(39)]·20H_2O的合成与晶体结构

采用电解法制备了未见文献报道的杂多蓝H8[SiMo11Co（H2O）O39]·20H2O，通过X-射线衍射测定了其晶体结构，该晶体属单斜晶系，空间群P21；。晶胞参数全矩阵最小二乘法修正至中心原子Si与4个氧形成四面体结构，配原子M（M＝11／12Mo＋1／12Co）与O形成12个MO6八面体结构3个MO6共边形成4个M3O13三金属簇，4个三金属簇与SiO4四面体共角相连形成阴离子结构。