911 resultados para short-range ordering
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The gravitational properties of a straight cosmic string are studied in the linear approximation of higher-derivative gravity. These properties are shown to be very different from those found using linearized Einstein gravity: there exists a short range gravitational (anti-gravitational) force in the nonrelativistic limit; in addition, the deflection angle of a light ray moving in a plane orthogonal to the string depends on the impact parameter. © 2008 World Scientific Publishing Company.
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The short-range diffusion phenomenon (Snoek Effect) was investigated by mechanical spectroscopy measurements between 300 K and 650 K, in a polycrystalline niobium sample, containing oxygen and nitrogen, using a torsion pendulum. Experimental spectra of anelastic relaxation were obtained under three conditions: as-received sample; annealed sample and subsequently annealed in an oxygen atmosphere for three hours at 1170 K in partial pressure of 5°10 -5mbar. The experimental spectra obtained were decomposed in elementary Debye peaks and the anelastic relaxation processes were identified. With anelastic relaxation parameters and the lattice parameters, the interstitial diffusion coefficients of the oxygen and nitrogen in niobium were calculated for each kind of preferential occupation (octahedral and tetrahedral). The results were compared with the literature data, and confirmed that the best adjustment is for the preferential occupation octahedral model for low concentrations of interstitial solutes, but at higher concentration of oxygen were observed deviations of experimental data for the interstitial diffusion coefficients of oxygen in niobium when compared with the literature data, this could be related to the possible occurrence of a double occupation of interstitial sites in the niobium lattice by oxygen interstitials. © (2010) Trans Tech Publications.
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We have investigated some diamondoids encapsulation into single walled carbon nanotubes (with diameters ranging from1.0 up to 2.2 nm) using fully atomistic molecular dynamics simulations. Diamondoids are the smallest hydrogen-terminated nanosized diamond-like molecules. Diamondois have been investigated for a large class of applications, ranging from oil industry to pharmaceuticals. Molecular ordered phases were observed for the encapsulation of adamantane, diamantane, and dihydroxy diamantanes. Chiral ordered phases, such as; double, triple, 4- and 5-stranded helices were also observed for those diamondoids. Our results also indicate that the modification of diamondoids through chemical functionalization with hydroxyl groups can lead to an enhancement of the molecular packing inside the carbon nanotubes in comparison to non-functionalized molecules. For larger diamondoids (such as, adamantane tetramers), we have not observed long-range ordering, but only a tendency of incomplete helical structural formation. © 2012 Materials Research Society.
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CaSnO3 and SrSnO3 alkaline earth stannate thin films were prepared by chemical solution deposition using the polymeric precursor method on various single crystal substrates (R- and C-sapphire and 100-SrTiO3) at different temperatures. The films were characterized by X-ray diffraction (θ-2θ, ω- and φ-scans), field emission scanning electron microscopy, atomic force microscopy, micro-Raman spectroscopy and photoluminescence. Epitaxial SrSnO3 and CaSnO 3 thin films were obtained on SrTiO3 with a high crystalline quality. The long-range symmetry promoted a short-range disorder which led to photoluminescence in the epitaxial films. In contrast, the films deposited on sapphire exhibited a random polycrystalline growth with no meaningful emission regardless of the substrate orientation. The network modifier (Ca or Sr) and the substrate (sapphire or SrTiO3) influenced the crystallization process and/or the microstructure. Higher is the tilts of the SnO6 octahedra, as in CaSnO3, higher is the crystallization temperature, which changed also the nucleation/grain growth process. © 2012 Elsevier Inc. All rights reserved.
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The present paper is a comprehensive study concerning Fe K-edge X-ray absorption spectroscopy (XAS) measurements, which were performed to characterize the local structure of (1 - x)Pb(Fe2/3W1/3)O 3-xPbTiO3 samples as a function of temperature and PbTiO3 content. Results obtained by the fits of extended X-ray absorption fine structure consist with rhombohedral symmetry for Pb(Fe 2/3W1/3)O3 composition at temperatures lower than room temperature. This result is in apparent disagreement with X-ray and neutron diffraction characterization which have been reported. This apparent disagreement is related to the fact that XAS probes the short-range order, whereas X-ray diffraction provides structural information about the average structure. Moreover, as the PbTiO3 content increases, a disorder has been detected at local structure of the FeO6 octahedron. Analysis of X-ray absorption near edge structure spectra did not show modifications in intensity nor energy of transitions. © 2013 American Institute of Physics.
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SrSnO3, a perovskite-type complex oxide, was synthesized by the modified Pechini method using two different precursors, tin chloride and metallic tin. The first one is already traditional in the literature and it claims about 30 days, only for the cleaning of tin citrate aiming at the elimination of the chloride. The second route was developed by our research group and saves time, taking 6 h to complete the synthesis of the resin. The results show that SrSnO3 obtained from the metallic tin show a higher short range order, leading to a band gap value higher than those reported in the literature, besides a meaningful reduction in the formation of SrCO 3, as compared to the one obtained from tin chloride.
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In this work La1-xCaxCoO3 (x = 0-0.4) pigments were synthesized by the polymeric precursor method with heat treatments at 700, 800 and 900 C for 4 h. The powders were characterized by colorimetry, UV-vis spectroscopy and powder X-ray diffraction (XRD). The X-ray diffraction patterns showed the presence of a single phase perovskite, changing its structure from rhombohedral to cubic, when calcium was added to the lattice. All of the pigments had a black colour with a strong absorption over the whole of the visible spectrum as a consequence of the different oxidation states of cobalt and the high short-range disorder. The substitution of Ca2+ for La3+ did not influence the pigment colour but decreased its final cost. © 2013 Elsevier Ltd. All rights reserved.
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Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)
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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
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Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)
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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
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As Redes de Sensores Sem Fio possuem capacidades limitadas de processamento, armazenamento, comunicação (largura de banda) e fonte de energia, além de possuírem características e requisitos básicos de uma RSSF como: necessidade de se auto-organizar, comunicação com difusão de curto alcance e roteamento com múltiplos saltos. Neste trabalho é proposto uma ferramenta que otimize o posicionamento e os pacotes entregues através do uso de Algoritmo Genético (AG). Para solucionar o problema de roteamento que melhore o consumo de energia e maximize a agregação de dados é proposto a utilização de lógica fuzzy no protocolo de roteamento Ad hoc Ondemand Distance Vector (AODV). Esta customização é intitulada AODV – Fuzzy for Wireless Sensor Networks (AODV-FWSN). Os resultados mostram que a solução proposta é eficiente e consegue prolongar a vida útil da RSSF e melhorar a taxa de entrega de dados quando comparado com soluções similares.
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O Pula-pula-assobiador Basileuterus leucoblepharus, um pássaro comum da Mata Atlântica, emite um único e distintivo tipo de canto para defesa territorial. O reconhecimento individual ou entre vizinho e estranho pode ser mais difícil quando as aves compartilham cantos semelhantes. De fato, a análise dos cantos de diferentes indivíduos revelou ligeiras diferenças nos domínios temporal e das freqüências. Efetivamente, um exame cuidadoso dos sinais de 21 indivíduos diferentes por 5 métodos complementares de análise revelou que, primeiro, um ou dois espaços na série tonal ocorrem entre duas notas sucessivas em determinados momentos do canto e, segundo, ocupam posições em tempo e freqüência estereotipadas para cada indivíduo. Experiências de "play-back" confirmam esses dados. Através de experiências de propagação, mostramos que esta informação individual pode ser transmitida somente a curta distância ( < 100 m) na mata. Considerando o tamanho e a repartição dos territórios, este processo de comunicação mostra-se eficiente e bem adaptado.