(Table T1) Stable oxygen and carbon isotopic composition of benthic foraminifers in ODP Site 199-1218 sediments

The transition from the late Oligocene warm period into the early Miocene was marked by a series of rapid and brief episodes of cryospheric expansion and global cooling. We analyzed benthic foraminifers from nannofossil oozes recovered at Ocean Drilling Program Site 1218 to construct a stable isotope stratigraphy for the deep Pacific.

(Table T1) Clay-mineral composition of ODP Site 184-1146 sediments

The preliminary results of a comprehensive study of clay minerals (<2 µm) are presented for the upper 2 m.y. of sediments from Ocean Drilling Program Leg 184 Site 1146 from the northern margin of the South China Sea, close to the Pearl River mouth. More than 500 samples were analyzed, and four main mineral species are present: smectite, illite, chlorite, and kaolinite. On a general basis, illite + chlorite and smectite display anti-correlated behavior in relation to changes in the proportion of primary to secondary minerals in the sediment. Low-frequency and high-frequency changes are observed in the smectite/(illite + chlorite) ratio.

(Table T1) Ages of white mica clasts in core samples of ODP Hole 210-1276A

Fifty-seven white mica clasts were separated from five samples taken from near the bases of turbidites ranging in age from early Albian to middle Eocene. Twenty two (39%) of the micas have ages between 260 and 340 Ma and five (9%) have older ages (~400-600 Ma). The former age range is characteristic of the North American Alleghenian orogeny and the Iberian Variscan orogeny. The latter range is characteristic of the North American Acadian orogeny and older basement rocks in the Grand Banks and Newfoundland areas. Both age ranges are present in the middle Eocene sample, but only the younger range occurs in the middle Albian sample. This difference could be a sampling artifact. If this is not the case, then the most likely explanation is that the Acadian-aged micas within the Meguma Zone underlying the Grand Banks were totally reset by Alleghenian reactivation of the zone, a feature which occurs extensively in Nova Scotia. The addition of Acadian-aged micas in the middle Eocene sample may reflect a change in sediment provenance as drainage systems unrelated to rift topography developed. With the exception of one clast dated at 186 Ma, the 12 other micas obtained from the upper Paleocene sample yielded ages between 55 and 74 Ma, with 7 falling within ±2 m.y. of the 57-Ma age of the sample indicated by the biostratigraphic age-depth plot for Site 1276. This, together with the volcaniclastic content of the sample, indicates an input from near-contemporaneous volcanism. The nearest known occurrences of near-contemporaneous late Paleocene volcanism that could have produced white micas are in Greenland and Portugal, some 2000 and 1500 km distant, respectively, from Site 1276 during the Paleocene. However, ages of volcanism in these areas indicate that they could probably not be sources of micas younger than 60 m.y., which suggests some as-yet unknown volcanic source in the North Atlantic area. Accumulation in the Grand Banks area of airborne-transported volcaniclastic material from eruptions of slightly different ages, followed by a single resedimentation event, could account for the spread of dates obtained from the sample. White micas from the lowermost Albian sample show a spread of ages between 37 and 284 Ma that is completely different from the age distribution pattern of the middle Albian and middle Eocene samples. The sample location is between, and at least 25 m above and below, two igneous sills dated at 98 and 105 Ma. The sills have narrow thermal aureoles and ages older than the youngest detrital micas in the sample. It is unlikely, therefore, that the spread of mica ages in the sample is due to partial resetting of ages caused by thermal effects associated with the intrusion of the sills. The resetting may have been associated with a longer lived thermal event.

(Table T1) Age determination of seven ODP Leg 201 sites

As part of a wider paleoclimate and paleoceanographic study of Holocene-upper Pleistocene laminated sediments from the eastern equatorial Pacific and Peru continental margin, we completed 32 accelerator mass spectrometry (AMS) 14C dates from cores recovered during Ocean Drilling Program (ODP) Leg 201. Sample preparation and measurement were carried out at the ANTARES AMS facility, Australian Nuclear Science and Technology Organisation (ANSTO), in Sydney, Australia (Lawson et al., 2000, doi:10.1016/S0168-583X(00)00276-7; Fink et al., 2004, doi:10.1016/j.nimb.2004.04.025). Although the sediments are predominantly diatomaceous oozes (D'Hondt, Jørgensen, Miller, et al., 2003, doi:10.2973/odp.proc.ir.201.2003), they contain sufficient inorganic (e.g., foraminifer tests and nannofossil plates) and organic (Meister et al., 2005, doi:10.2973/odp.proc.sr.201.105.2005) carbon to allow 14C dating. These dates permitted us to reconstruct a history of sediment accumulation over the past 20 k.y., particularly on the Peru continental margin. In this report we present 14C AMS dates and other pertinent data from cores from Sites 1227, 1228, and 1229 collected during Leg 201 at the Peru continental margin.

(Table T1) Abundance of silicoflagellates in sediments of ODP Hole 199-1219A

Silicoflagellates ranging from middle Eocene to middle Miocene in age are present in Ocean Drilling Program Hole 1219A. The hole was drilled 250.8 meters below seafloor of which an ~120 m section primarily composed of nannofossil ooze with variable radiolarian and clay content is early Miocene and Oligocene in age, and a 95-m section is Eocene radiolarian and zeolithic clays, radiolarian and diatom oozes, and nannofossil oozes and chalks. A total of 150 samples were studied at a sample interval of one per section. Diversity of silicoflagellates is moderate, and the preservation is good. Abundance is generally low, with many samples barren of silicoflagellates, but 31 species and subspecies were identified. One new species, Naviculopsis trigeminus, is described.

(Table T1) Correlations between marker beds and drill holes for ODP Leg 171B sites

More than 50 discrete volcanic ash layers were recovered at the five drill sites of the Blake Nose depth transect (Leg 171B, western central Atlantic). The majority of these ash layers are intercalated with Eocene hemipelagic sediments with a pronounced frequency maximum in the upper Eocene. Several ash layers appear to be deposited from volcanic fallout with little or no indication of secondary remobilization. They provide excellent stratigraphic markers for a correlation of the Leg 171B drill sites. Other ash layers were probably redeposited from volcaniclastic-rich turbidity currents, but they still represent geologically instantaneous events that can be used in stratigraphic correlation between adjacent drill holes. Additional nonvolcanic marker beds, like the suspect late Eocene impact event layer, were included in our hole-to-hole correlations. Stratigraphic and downcore positions of marker beds were compiled and plotted against existing composite depth records that were constructed to guide high-resolution sampling. Comparison of our correlation with the spliced composite sections of each drill site reveals several minor and some major discrepancies. These may result from drilling distortion or missing sections, from the lack of unambiguous criteria for the synchronism of ash layers, or from the systematic exclusion of marker-bed data in the construction of the spliced record. Integration of both correlation approaches will help eliminate most of the observed discrepancies.

(Table T1) Paleomagnetic properties of ODP Hole 191-1179D basalts

During Ocean Drilling Program Leg 191, ~100 m of mid-Cretaceous igneous crust was cored at Site 1179 (41.08°N, 159.96°E), located within magnetic Anomaly M8 on the abyssal plain of the northwest Pacific Ocean near Shatsky Rise. Paleomagnetic data from this section are significant because they can constrain the mid-Cretaceous Pacific plate paleolatitude and paleomagnetic pole, both of which can be used to infer tectonic drift and other geodynamic processes. In this study, we analyzed the paleomagnetism of 122 samples from 40 flows in the Site 1179 basalt section. Comparison of inclination data among flows implies 13 independent measurements of the paleomagnetic field. Assuming a reversed magnetic polarity because of the site location within Anomaly M8, the data give a mean paleocolatitude of 88.1° ± 6.8° (corresponding to a paleolatitude of 1.9°N). The paleocolatitude is consistent with other mid-Cretaceous Pacific paleomagnetic data that indicate ~39° northward drift of the western Pacific plate since mid-Cretaceous time. Comparison of observed between-flow colatitude variance with that expected from secular variation data suggests that secular variation may not have been completely averaged with the 13 independent groups sampled at Site 1179. Colatitude scatter in the section is markedly less in the deepest 33 m of the hole, indicating a shift from rapidly erupted flows in the bottom ~33 m of the section to more slowly emplaced flows above.

(Table T1) Permeability, electrical resistivity and density of ODP Hole 193-1188A and Site 193-1189 minicores, PACMANUS field

Magmatic fluids, heat fluxes, and fluid/rock interactions associated with hydrothermal systems along spreading centers and convergent margins have a significant impact on the genesis of major sulfide deposits and biological communities. Circulation of hydrothermal fluids is one of the most fundamental processes associated with localized mineralization and is controlled by inherent porous and permeable properties of the ocean crust. Heat from magmatic intrusions drives circulation of seawater through permeable portions of the oceanic crust and upper mantle, discharging at the seafloor as both focused high-temperature (250°-400°C) fluids and diffuse lower-temperature (<250°C) fluids. This complex interaction between the circulating hydrothermal fluids and the oceanic basement greatly influences the physical properties and the composition of the crust (Thompson, 1983; Jacobson, 1992, doi:10.1029/91RG02811; Johnson and Semyan, 1994, doi:10.1029/93JB00717). During Ocean Drilling Program (ODP) Leg 193, 13 holes were drilled in the PACMANUS hydrothermal system (Binns, Barriga, Miller, et al., 2002, doi:10.2973/odp.proc.ir.193.2002). The hydrothermal system consists of isolated hydrothermal deposits lined along the main crest of the Pual Ridge, a 500- to 700-m-high felsic neovolcanic ridge in the eastern Manus Basin. The principal drilling targets were the Snowcap (Site 1188) and Roman Ruins (Site 1189) active hydrothermal fields. Samples from these two sites were used for a series of permeability, electrical resistivity, and X-ray computed tomography measurements.

(Table T1) In situ methane concentrations of ODP Site 201-1230

A method for quantifying in situ dissolved methane concentrations in sediment cores that have gas voids is described. The method relies on normalizing methane (CH4) in the gas voids to nitrogen (N2) and/or argon (Ar). The principles of the method are presented. The method was tested during Ocean Drilling Program Leg 201, and preliminary results indicate that it can be used to generate reproducible and accurate dissolved methane values if argon and nitrogen are both measured or if one is measured along with pressure of the gas void.

(Table T1) Bulk rock geochemistry of fresh lavas from ODP Leg 193 sites, PACMANUS field

Leg 193 was the fourth Ocean Drilling Program expedition focusing on understanding subseafloor hydrothermal systems. This program was the first to combine studies of the volcanology, structure, hydrology, mineralization, and microbiology of a subseafloor hydrothermal system hosted by felsic rocks by coring at the PACMANUS hydrothermal field in the Manus Basin, Papua New Guinea. The study examines only the petrology and bulk rock and mineral chemistry of the freshest and most morphologically youthful lava flows recovered from the shallowest drill cores at the four sites occupied during Leg 193. There are subtle but distinct petrographic and geochemical variations between the closely spaced sites.