J-P fundamentals ...

Reproduced from type-written copy.

Car builders' cyclopedia of American practice.

The 2d ed., 1884, was reprinted in 1888; the 3d ed., 1895, reprinted in 1898.

Cyclopædia of the practice of medicine.

Each volume contains "Biographical sketches of the authors."

The pictorial sketch-book of Pennsylvania. Or, its scenery, internal improvements, resources, and agriculture,

The fourth part has separate t.-p.: Locomotive sketches, with pen and pencil. From Philadelphia to Pittsburg. (13-192 p.)

The happy prince, and other tales ;

Illustrated lining-papers.

Planetary Penetrators for Sample Return Missions

Thesis (Master's)--University of Washington, 2016-06

Parametric Optimization of Inductively Driven Liner Compression Driver System

Thesis (Master's)--University of Washington, 2016-06

Stabilisation of isocyanate cross linked polybutadiene binder

Isocyanate cross-linked hydroxy terminated polybutadiene is used as a binder for solid rocket propellant. Rocket motors containing this propellant require a storage life of at least 20 years. During storage it has been found that the important rubbery properties of the binder can be lost due to oxidative cross-linking of the polybutadiene chains. This could cause catastrophic failure when the rocket motor is required. At present the bis-hindered phenol Calco 2246 is used as a thermal oxidative stabiliser, but it's performance is only adequate. This has led to the search for a more efficient stabiliser system. To hasten the evaluation of new antioxidant systems the use of dynamic thermal analysis was investigated. Results showed that a tentative relationship existed between predictions by thermal analysis and the long term oven ageing for simple single antioxidant systems. But for more complex systems containing either autosynergistic or mixed antioxidants no relationship was observed suggesting that results for such an "accelerated" technique cannot be used for the purpose of extrapolation for long term performance. This was attributed to the short time and more aggressive condition used (hjgher temperature and oxygen rich atmosphere in thermal analysis) altering the mechanism of action of the antioxidants and not allowing time for co-operative effect of the combined antioxidant system to form. One potential problem for the binder system is the use of an diisocyanate as a cross-linking agent. This reacts with the hydroxyl hydrogen on the polymer as well as other active hydrogens such as those contained in a number of antioxidants, affecting both cross-linking and antioxidant effectiveness. Studies in this work showed that only antioxidants containing amine moieties have a significant affect on binder preparation, with the phenolic antioxidants not reacting. This is due to the greater nucleophilicity of the amines. Investigation of a range of antioxidant systems, including potentially homo, hetero and autosynergistic systems, has highlighted a number of systems which show considerably greater effectiveness than the currently used antioxidant Calco 2246. The only single antioxidant which showed improvement was the partially unhindered phenol y-Tocopherol. Of the mixed systems combinations of the sulphur containing antioxidants e.g. DLTP with higher levels of chain-breaking antioxidants, especially Calco 2246, were the most promising. Also the homosynergistic mix of an aromatic amine and a phenol was seen to be very effective but the results were inconsistent. This inconsistency could be explained by the method of sample preparation used. It was shown that the efficiency of a number of antioxidant.s could be dramatically improved by the use of ultrasound during the mixing stage of preparation. The reason for this increase in performance is unclear but in the case of the homosynergistic amine/phenol mix both more efficient mixing and/or the production of a novel mechanism of action are suggested

Degradation and stabilisation of diisocyanate cured polybutadiene

Hydroxyl terminated polybutadiene (HTPB) has been used as a rocket propellant binder which is required to be stored for at least twenty years. It is found that the excellent stress-strain characteristics of this propellant can be totally lost, during this long storage, due to the deterioration of the polybutadiene chains. As a result, the propellant can not stand the service loads, which may lead to a catastrophe. The study of the HTPB binder degradation, below 80°C, has been carried out by investigating the environmental factors and the changes which occur along the macromolecular chains. Results have shown that oxygen is the main factor which causes the crosslinking and chain scission reactions. The former is the predominant reaction and proceeds rapidly under oxygen sufficient environment. The unsaturation of polymer chain, which provides the desired physical properties to the binder, was lost with the increase in crosslink density. At the same time hydroperoxides were found to form and decompose along the polymer chains. Therefore, the deterioration of the binder results from the oxidation of polymer chains. Since the oxidation reaction occurred at higher rate than oxygen diffusion rate and oxygen diffusion rate is inversely proportional to the crosslink density, the binder, below the surface layer in a thick section container, could be naturally protected under an oxygen deficient condition for a long time. Investigation of the effectiveness of antioxidants in HTPB binder has shown that the efficiency of an antioxidant depends on its ability to scavenge radicals. Generally, aromatic amines are the most effective binder antioxidants. But when a peroxide decomposer is combined with an aromatic amine at the appropriate ratio, a synergistic effect is obtained, which gives the lowest binder gel increase rate.

Improvements to the arc-spraying process

After a brief review of the various forms of thermal spraying equipment and processes, descriptions of the basic principles involved and the general functions for which thermally sprayed coatings are used are given. The background of the collaborating company, Metallisation, is described and their position in the overall market discussed, providing a backdrop against which the appropriateness of various project options might be judged. Current arc-spraying equipment is then examined, firstly in terms of the workings of their constituent parts and subsequently by examining the effects of changes in design and in operating parameters both upon equipment operation and the coatings produced. Published literature relating to these matters is reviewed. Literature relating to the production, comminution and propulsion of the particles which form the spray is discussed as are the mechanisms involved at impact with the substrate. Literature on the use of rockets for thermal spraying and induction heating as a process for feedstock melting are also reviewed. Three distinct options for further study are derived and preliminary tests and costings made to allow one option alone, the use of rocket acceleration, to go forward to the experimental phase. A suitable rocket burner was developed, tested and incorporated into an arc-spray system so that the sprayability of the whole could be assessed. Coatings were made using various parameters and these are compared with coatings produced by a standard system. Coatings were examined for macro and micro hardness, cohesive strength, porosity and by microstructural examination. The results indicate a high degree of similarity between the coatings produced by the standard system and the high velocity system. This was surprising in view of the very different atomising media and velocities. Possible causes for this similarity and the general behaviour of this new system and the standard system are discussed before the study reaches its conclusions in not proving the hypothesis that an increase in particle velocity would improve the mechanical properties of arc-sprayed steel coatings. KEY WORDS: Sprayed metal coatings, Electric arc spraying, High velocity flame spraying, Sprayed coating properties

As estações ferroviárias do Triângulo Mineiro e Alto Paranaíba e suas interfaces: história e conservação

The implementation of the railway in Triângulo Mineiro and Alto Paranaíba helped to develop the area and connexion with other states: São Paulo, Goiás and Mato Grosso. The railway used to transport people and goods throughout many train stations in urban and rural areas and some major railroad complexes. There were many factors that led to the decline and abandonment of these properties: governmental policies which were in favour of road transportation and automotive industry, the replacement of the steam locomotive for electric and electric-diesel locomotives, changing part of the railway plan, removal of railways and loss of function of the buildings, extinction of passenger trains, which led the stations to lose its main purpose: people transport. 53% of the stations built inside the study area were demolished and most of them are in rural areas. There are several situations: stations on a precarious conservation state, most of them in the city s rural area, stations being used in urban and rural areas with new uses, stations working with cargo and goods transportation. The stations in Triângulo Mineiro and Alto Paranaíba area in Minas Gerais are the object of this dissertation, wherein the main interest lies on the stations that are in operation, 21 buildings, seeking to verify their conservation state, their agents and role in preserving the train memory. Maps, charts and tables were made for this collection s understanding, having visited the stations that are listed by the cultural heritage and the ones that are in operation with new functions. Field records were made allowing the understanding of these properties in operation. It is observed that only the buildings listing, despite ensuring the non-demolition, does not help on the use and preservation of these stations, because there are some buildings that have this protection level, but are abandoned and in disrepair. The use of these stations by a train company, operating with cargo and goods transportation do not also guarantee the buildings preservation, as they are not treated with any preservation interest, their maintenance are precarious. The using by these companies are various, however, only a few stations have internal spaces dedicated to the railroad memory. Most of the stations did not have preservation projects with architects and specialists participation and the major concern, during maintenance process, is on the building s external part. The stations conservation begins on the local government interest, that preserve these properties, most of them are in urban areas, the major challenge is on their using definition and occupancy, especially in the countryside, wherein the buildings uses must be sustainable, as regards the appreciation and management of this heritage.

Studio dell'effetto di Hump in un motore a solido in piccola scala con metodi di produzione di punzonatura e colaggio

L’oggetto di questo elaborato riguarda lo studio prestazionale di un Solid Rocket Motor mediante l’introduzione del fattore di “Hump”, che va a compensare il discostamento tra il profilo delle pressioni sperimentali e teoriche, cercando di legare tali variazioni a spiegazioni fisiche. In particolare andremo ad investigare, all’interno di due differenti tipologie di colata, quale sia l’effetto predominante all’interno del propellente che genera proprio tali discostamenti della pressione, e quindi della spinta, rispetto alla condizione ideale. Nell’elaborato verranno anzitutto presentate le diverse tipologie di propulsori, i loro singoli componenti, i parametri fondamentali che regolano la meccanica di questa tipologia di motori, le tipologie di grain esistenti e le loro caratteristiche. Successivamente descriveremo le BARIA (Bomb ARIAne), usate per i test del grain nella ditta AVIO s.p.a., e le tipologie di riempimento di questo motore, investigando i fenomeni fisici a cui sarà legato l’effetto di “Hump”. In seguito si descriverà il fattore di “Hump”, evidenziando, per le differenti tipologie di riempimento, i fenomeni fisici a cui sarà legato il discostamento tra le pressioni sperimentali e teoriche. Verranno poi descritti i programmi utilizzati, gli script in Matlab prodotti, al fine di ottenere le mappe relative all’orientazione ed alla concentrazione delle particelle, da introdurre nel simulatore. Infine verranno esposti i risultati ottenuti e confrontati con i dati sperimentali forniti dalla ditta AVIO s.p.a., le conclusioni e gli sviluppi futuri.

A cidade sem barreiras é para todos?: avaliação das condições de deslocamento no bairro da Cidade Alta, Natal/RN

In this present work, the conditions of displacements and the behaviors of the users are evaluated, face to the physical adequacies in accessibility in the inserted area in the central quadrilateral of the Quarter of Cidade Alta, in the City of Natal/RN, space clipping established by its great meaning historical and cultural. For this reason such area was a target of an integrated actions plan during the years of 1993 and 1998, with the implantation of part of the Project CIDADE SEM BARREIRAS (City without Barriers) and, later, the implementation of the Project CIDADE PARA TODOS's proposals (City for All), having as supports the constant Brazilian norms inserted into the NB9050/1994 and in the Municipal law number 4.090/92, effective ones in the period of the interventions. Considering that the carried through actions at the time were directed to the elimination of the architectural barriers to guarantee the right to go and to come, the research received a human universe formed by all the people in situation of displacement in the central area of the interventions in the quarter of the Cidade Alta, independently of their locomotive or sensorial conditions, emphasizing the aspects most excellent how much to the accessibility of the sidewalk, as promotional of mobility, integration and urban organization, as well as of the public squares of that one quadrilateral, conceived, originally, as spaces of aggregation and social inclusion. The work appealed to the direct comment and the gotten results had been collated with the ex port facto law and technique norms, of the year of 2004, and with the legal devices contained in the Federal Decree number 5.296/2004, as way to certify the levels of efficiency of these adaptations in that it says respect to the current conditions of demanded accessibility and urban mobility

Key factors affecting purchase intention in Russian online context

Russian e-commerce has drawn a lot of attention in academic publications as well as in public media lately. The market is growing with a speed of rocket offering companies enormous business opportunities. However, combination of Russian culture, consumer online purchasing and decision-making process forms a subject yet completely unknown. From international online business perspective it is vital for companies to know how a culture affects consumer’s purchase decision and what are the key elements that need to be modified in order to successfully expand online operations to Russian market. Here, the main purpose is to define the key factors affecting Russian consumer’s online purchase intention. In order to answer the main research question, firstly the role of culture in purchase intention context is researched. Secondly, focus is drawn to the factors that affect online purchase intention. Lastly, it is researched how Russian culture is affecting e-commerce attributes modification. The objective is not only to expand the theoretical understanding of the subject but also to provide companies with a clear vision on how the online operations should be conducted in Russian online market. Ranganathan’s and Jha’s conceptual framework was chosen as a ground theory in this study. Here, three main categories Computer Self-Efficacy and Past Online Experience, Website Quality and Costumer Concerns form basis for the study. Various articles and academic literature supplemented this theoretical approach. Qualitative research method was adapted and the study was conducted through five expert interviews. As a conclusion it can be stated that culture forms a ground for entire purchase decision-making process in online context. Results from the interviews were grouped according to main three theoretic categories and placed with Ranganathan’s and Jha’s original framework. This formed a new theoretical framework that defines diverse factors affecting specifically Russian consumer’s online purchase intention. This study suggests that following factors need to be taking into serious consideration in Russian online context: photography style, detailed product and company information, colors, language, product variety, reviews, recommendations, strong social media presence, fast check out and minimalistic order information, counterfeit fear, cash on delivery payment, training and guidance, extensive customer service, consumers’ insecurity, inexperience, high interest for technology and their individualistic personality.

Bitcoin mining is about to become a lot less profitable.

Imagine being told that your wage was going to be cut in half. Well, that’s what’s soon going to happen to those who make money from Bitcoin mining, the process of earning the online currency Bitcoin. The current expected date for this change is 11 July 2016. Many see this as the day when Bitcoin prices will rocket and when Bitcoin owners could make a great deal of money. Others see it as the start of a Bitcoin crash. At present no one quite knows which way it will go. Bitcoin was created in 2009 by someone known as Satoshi Nakamoto, borrowing from a whole lot of research methods. It is a cryptocurrency, meaning it uses digital encryption techniques to create bitcoins and secure financial transactions. It doesn’t need a central government or organisation to regulate it, nor a broker to manage payments. Conventional currencies usually have a central bank that creates money and controls its supply. Bitcoin is instead created when individuals “mine” for it by using their computers to perform complex calculations through special software. The algorithm behind Bitcoin is designed to limit the number of bitcoins that can ever be created. All Bitcoin transactions are recorded on a public database known as a blockchain. Every time someone mines for Bitcoin, it is recorded with a new block that is transmitted to every Bitcoin app across the network, like a bank updating its online records.