Rare earth element contents and sources in phosphorites from Pacific seamounts

Distribution of rare earth elements (REE) was studied in phosphorites collected from seamounts at depths from about 400 to 3600 m. In general phosphorites are characterized by high REE con¬tent, by a strong negative Ce anomaly, by a slight positive Gd anomaly, and by slight enrichment in heavy REE, which is also characteristic of seawater, where, to certain extent, composition of REE depends on depth. Comparison of REE composition in phosphorites and in seawater from the Northwest Pacific by means of Q-mode factor analysis revealed that REE have been transported into the phosphorites from various water depths following submergence of the seamounts. This corresponds to paleotectonic reconstructions, but is only partially consistent with age determinations of phosphorites.

(Table 4) Contents of P2O5 and REE in phosphorites from Pacific seamounts

Changes in concentration levels and speciation of heavy metals during sedimentation on example of a typical semi-closed bay, where bottom sediments have formed due to river run-off, are under consideration. It is shown that due to desorption of mobile manganese, zinc and copper entered the bay with river suspended matter, their total contents in bottom sediments decrease and percentages of lithogenic forms increase. Contents and speciation of iron in bottom sediments are determined by its participation in coagulation of river colloids in the mixing zone and by mechanical differentiation of sedimentary material.

Swath sonar bathymetry during SONNE cruise SO202 (INOPEX) with links to multibeam raw data files

Multibeam data were measured during R/V SONNE cruise SO202 (INOPEX) along track lines of 6938 NM total length in the North Pacific and Bering Sea during transits and stationary work. Starting from Hokkaido (Japan) data were achieved east of the Kuril-Kamchatka Trench and south of the Aleutian Trench. The track crosses the Bowers Ridge, the continental margin of Alaska and the Umnak Plateau in the Bering Sea. Further data were gained in the North Pacific in the area of the Patton Seamounts, Gibson Seamount, Hess Rise and Shatsky Rise. The multibeam sonar system Simrad EM 120 from Kongsberg was operated using 191 beams and an aperture angle of 90° to 140° due to particular conditions. The refraction correction was achieved utilizing 6 CTD profiles measured during the cruise and one from cruise SO201. The quality of data might be reduced during bad weather periods. The dataset contains raw data that are not processed and thus may contain errors and blunders in depth and position.

Age of samples from the sedimentary cover of the Primorye continental slope and from the submarine Bogorov Rise

Results of a complex study of the sedimentary cover (continuous seismic profiling and diatom analysis) in the northeastern Sea of Japan including the Bogorov Rise an adjacent part of the Japan Basin and the continental slope, are presented. Two varied-age complexes were distinguished in the sedimentary cover of the continental slope of Primorye: Middle Miocene and Late Miocene - Pleistocene. These complexes formed in a stable tectonic setting with no significant vertical movements. A depression in the acoustic basement is located along the continental slope and it is divided from the Japan Basin by a group of volcanic structures, the most uplifted part of which forms the Bogorov Rise. The depression probably formed before Middle Miocene. In Middle Miocene the Bogorov Rise was already at depths close to modern ones. In the sedimentary cover near the Bogorov Rise buried zones were found. Probably they were channels for gas transportation in pre-Pleistocene. Deformations of sediments that occurred in the beginning of Pleistocene are established in the basin.

Sea surface temperature estimation of the South Tasman Rise

The Subtropical Front (STF) marking the northern boundary of the Southern Ocean has a steep gradient in sea surface temperature (SST) of approximately 4°C over 0.5° of latitude. Presently, in the region south of Tasmania, the STF lies nominally at 47°S in the summer and 45°S in the winter. We present here SST reconstructions in a latitudinal transect of cores across the South Tasman Rise, southeast of Australia, during the late Quaternary. SST reconstructions are based on two paleotemperature proxies, alkenones and faunal assemblages, which are used to assess past changes in SST in spring and summer. The north-south alignment in core locations allows reconstruction of movement of the STF over the last 100 ka. Surface water temperatures during the last glaciation in this region were ~4°C colder than today. Additional temperature changes greater in magnitude than 4°C seen in individual cores can be attributed to changes in the water mass overlying the core site caused by the movement of the front across that location. During the penultimate interglacial, SST was ~2°C warmer and the STF was largely positioned south of 47°S. Movement of the STF to the north occurred during cool climate periods such as the last marine isotope stages 3 and 4. In the last glaciation, the front was at its farthest north position, becoming pinned against the Tasmanian landmass. It moved south by 4° latitude to 47°S in summer during the deglaciation but remained north of 45°S in spring throughout the early deglaciation. After 11 ka B.P. inferred invigoration of the East Australia Current appears to have pushed the STF seasonally south of the East Tasman Plateau, until after 6 ka B.P. when it achieved its present configuration.

Magnetic and gravity measurements on North-South profiles across the Grosse Meteor Bank, North Atlantic

During the first section of the "Meteor" cruise No. 2 a profile was run from the Azores to the south across the flanks of the Mid-Atlantic Ridge with a chain of seamounts. The profile extended between the Cruiser (living) and the Hyeres seamounts, which, according to our soundings, form a connected massif, and across the centre of the Grosse Meteor Bank (30°N, 28.5 °W). These seamounts rise from a depth of more than 4000 m up till close to the surface of the sea forming there a large almost flat plateau. In the case of the Grosse Meteor Bank, this plateau has a N-S extension of approx. 30 nautical miles and an E-W extension of approx. 20 nautical miles and reaches a height of 275 m in water depth. The gravity measurements yielded a density of the topographic masses of 2.6 g/cm**3 for the Grosse Meteor Bank. Magnitude and shape of the measured free-air anomaly are very well shown in a model computation with this density. The theoretical gravity effects of the seismically detected swell of cristalline rock and of the Moho depression (mountain root) are not indicated by the observational data. It can, therefore, be assumed that the latter two neutralize each other. It seems, accordingly, that there is no local isostatic compensation of the topographic masses. Hence, the density of 2.6 g/cm**3 obtained would be about the true density of rock. In connection with the mean velocity of P waves (Aric et al., 1968) obtained by seismic refraction methods it must be concluded that the material of the 1200-4000 m thick surface layer of the Grosse Meteor Bank consists of consolidated sediments. This finding is supported by the total intensity of the Earth's magnetic field over the Grosse Meteor Bank. On the assumption of a homogeneous magnetization in the direction of the present Earth's field, the computed anomaly of the massif deviates considerably from the measured anomaly while the magnetic field of the seismically detected crystalline body is capable of interpreting the observed data. Deviating from the prevailing interpretation of the seamounts' plateau as a volcanic cone with submarine abrasion, the Grosse Meteor Bank and the seamounts in the vicinity are assumed to be of continental origin. The questions whether these seamounts submerged later on or whether the sealevel has risen subsequently are, therefore, largely nonexistent.

Chemical composition of East Pacific Rise basal sediments

Analyses by atomic absorption spectrophotometry and spark-source mass spectrography of 25 basal metalliferous sediment units from widely spaced locations on the western flank of the East Pacific Rise show that the deposits are enriched relative to normal pelagic sediment in Fe, Mn, Ni, Cu, Pb, Zn, and many trace elements. The elements are partitioned differently between the various mineralogic constituents of the sediment, with Fe and Mn largely in separate phases and many of the remaining elements primarily associated with reducible ferromanganese oxide minerals but also with iron minerals and other phases. Most of the iron in the deposits is probably of volcanic origin, and much of the manganese and minor elements is derived from sea water. The bulk composition of the deposits varies with age; this is thought to be due to variations in the incidence of volcanic activity at the East Pacific Rise crest where the deposits were formed.

Ages and tephra layers in Chatham Rise sediment cores

We present sea surface temperature (SST) estimates based on the relative abundances of long-chain C37 alkenones (UK37') in four sediment cores from a transect spanning the subtropical to subantarctic waters across the subtropical front east of New Zealand. SST estimates from UK37' are compared to those derived from foraminiferal assemblages (using the modern analog technique) in two of these cores. Reconstructions of SST in core tops and Holocene sediments agree well with modern average summer temperatures of ~18°C in subtropical waters and ~14°C in subpolar waters, with a 4°-5°C gradient across the front. Down core UK37' SST estimates indicate that the regional summer SST was 4°-5°C cooler during the last glaciation with an SST of ~10°C in subpolar waters and an SST of ~14°C in subtropical waters. Temperature reconstructions from foraminiferal assemblages agree with those derived from alkenones for the Holocene. In subtropical waters, reconstructions also agree with a glacial cooling of 4° to ~14°C. In contrast, reconstructions for subantarctic pre-Holocene waters indicate a cooling of 8°C with glacial age warm season water temperatures of ~6°C. Thus the alkenones suggest the glacial temperature gradient across the front was the same or reduced slightly to 3.5°-4°C, whereas foraminiferal reconstructions suggest it doubled to 8°C. Our results support previous work indicating that the STF remained fixed over the Chatham Rise during the Last Glacial Maximum. However, the differing results from the two techniques require additional explanation. A change in euphotic zone temperature profiles, seasonality of growth, or preferred growth depth must have affected the temperatures recorded by these biologically based proxies. Regardless of the specific reason, a differential response to the environmental changes between the two climate regimes by the organisms on which the estimates are based suggests increased upwelling associated with increased winds and/or a shallowing of the thermocline associated with increased stratification of the surface layer in the last glaciation.

Sedimentary records of ODP Site 198-1209 on Shatsky Rise

The accumulation of wind blown (eolian) dust in deep-sea sediments reflects the aridity/humidity conditions of the continental region supplying the dust, as well as the "gustiness" of the climate system. Detailed studies of Pleistocene glacial-interglacial dust fluxes suggest changes in accumulation rates corresponding to orbital variations in solar insolation (Milankovitch cycles). While the orbital cycles found in sedimentary archives of the Pleistocene are intricately related to glacial growth and decay, similar global orbital signals recognized in deep-sea sediments of early Paleogene age, the last major greenhouse interval ~65-45 million years ago, could not have been linked to the waxing and waning of large ice sheets. Thus orbital signals recorded in early Paleogene sediments must reflect some other climate response to changes in solar insolation. To explore the potential connection between orbital forcing and the climate processes that control dust accumulation, we generated a high-resolution dust record for ~58 Myr old sediments from Shatsky Rise (ODP Site 1209, paleolatitude ~15°N-20°N). The dust accumulation data provide the first evidence of a correlation between dust flux to the deep sea and orbital cyclicity during the early Paleogene, indicating dust supply responded to insolation forcing during the last major interval of greenhouse climate. Furthermore, the relative amplitude of the dust flux response during the early Paleogene greenhouse was comparable to that during icehouse climates. Thus, subtle variations in solar insolation driven by changes in Earth's orbit about the Sun may have had a similar impact on climate during intervals of overall warmth as they did during glacial-interglacial states.