Stable carbon and oxygen isotopes from samples of the Anaximander seamounts in the eastern Mediterranean Sea

Porous seep-carbonates are exposed at mud volcanoes in the eastern Mediterranean Sea. The 13C-depleted aragonitic carbonates formed as a consequence of the anaerobic oxidation of methane in a shallow sub-surface environment. Besides the macroscopically visible cavernous fabric, extensive carbonate corrosion was revealed by detailed analysis. After erosion of the background sediments, the carbonates became exposed to oxygenated bottom waters that are periodically influenced by the release of methane and upward diffusion of hydrogen sulphide. We suggest that carbonate corrosion resulted from acidity locally produced by aerobic oxidation of methane and hydrogen sulphide in the otherwise, with respect to aragonite, oversaturated bottom waters. Although it remains to be tested whether the mechanisms of carbonate dissolution suggested herein are valid, this study reveals that a better estimate of the significance of corrosion is required to assess the amount of methane-derived carbon that is permanently fixed in seep-carbonates.

Swath sonar bathymetry during POLARSTERN cruise ARK-XXII/1c (PS70) with links to multibeam raw data files

Multibeam data were measured as part of the project HERMES during R/V Polarstern cruise ARK-XXII/1 (2007-05-29 to 2007-07-25) along transits and survey profiles and partly during stationary work. Data were achieved mainly in the coastal areas of northern Norway, at the Hakon Mosby Mud Volcano at the continental margin approx. 200 nm off the norwegian coast and the AWI-Hausgarten area approx. 150 nm west of Svalbard. A number of surveys were carried out in the coastal areas of northern Norway (Sula Reef, Roest Reef, Traena area, Floholmen area, Sotbakken area) and around the area of the Hakon Mosby Mud Volcano. The multibeam sonar system Atlas Hydrosweep DS-2 (Atlas Hydrographic, http://www.atlashydro.com) was operated using 59 beams and 90° aperture angle. The refraction correction was achieved using CTD profiles measured during this cruise or, during transits, utilizing the system's own cross fan calibration. The quality of data might be reduced during bad weather periods or adverse sea ice conditions (only in the AWI-Hausgarten area). This dataset contains raw data that are not processed and thus may contain errors and blunders in depth and position.

Boron contents and boron, carbon, and oxygen isotope data for ODP Sites 160-970 and 160-971

Products of two mud volcanoes from the distal part of the Mediterranean Ridge accretionary complex have been investigated regarding their B, C, and O stable isotope signatures. The mud breccias have been divided into mud matrix, lithified clasts, biogenic deposits, and authigenic cements and crusts related to fluid flow and cementation. Isotope geochemistry is used to evaluate the depth of mobilization of each phase in the subduction zone. B contents and isotope ratios of the mud and mud clasts show a general trend of B enrichment and decreasing d11B values with increasing consolidation (i.e., depth). However, the majority of the clast and matrix samples relate to moderate depths of mobilization within the wedge (1-2 km below seafloor). The carbonate cements of most of these clasts as well as the authigenic crusts, however, provide evidence for a deep fluid influence, probably associated with the décollement at 5-6 km depth. This interpretation is supported by d13C ratios of the crust, which indicate precipitation of C from thermogenic methane, and by the d11B ratios of pore-water samples of mud-breccia drill cores. Clams (Vesicomya sp.) living adjacent to fluid vents have d11B and d18O values corresponding to brines known in the area, which acted as the parent solution for shell precipitation. Such brines are most likely Miocene pore waters trapped at deep levels within the backstop to the accretionary prism, probably prior to desiccation of the Mediterranean in the Messinian (6-5 Ma). Combining all results, deep fluid circulation and expulsion are identified as the main processes triggering mud liquefaction and extrusion, whereas brines contribute only locally. Given the high B contents, mud extrusion has to be considered a major backflux mechanism of B into the hydrosphere.