957 resultados para COBALT


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Includes index.

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Includes bibliographical references.

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Reprinted from the Journal of the American chemical society, v. 22, no. 8, Ag. 1900.

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Mode of access: Internet.

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Thesis--University of California.

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Thesis (M.S.)--University of Illinois, 1965.

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Mode of access: Internet.

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At head of title: Imperial Mineral Resources Bureau.

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At head of title: Imperial Mineral Resources Bureau.

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"Draft for public comment."

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"A continuation of the work of Jones and Uhler on the absorption spectra of solutions (Carnegie publication no. 60)" cf. Pref.

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The synthesis of the pentadentate ligand 2,6-bis(3,3-dimethyl-2,4-dioxocyclohexanyl)-4-thiaheptane (N(4)Samp) is described. The synthetic pathway involves the coupling of two 1,3-(dimethylenedioxy)-2-methyl-2-(methylene-p-toluenesulfonyl)propane moieties with sodium sulfide and subsequent synthetic elaboration to prepare the final N4S donor system. The cobalt(III) complex [Co(N(4)Samp)Cl](2+) has been prepared and subsequently crystallized as the tetrachlorozincate salt. The X-ray structure analysis confirms the pentadentate nature of the ligand and shows the thioether donor occupying one apex with four equivalent amine donors effectively occupying the equatorial plane of the molecule. The sixth coordination site is occupied by a chloro ligand. The electronic absorption and C-13 NMR spectra have been studied. DFT calculations have been employed to explore structural and mechanistic comparisons between [Co(N(4)Samp)Cl](2+) and an analogous pentaamine complex.