氟离子碰撞引起的钽L壳层X射线产生截面测量

测量了20~55 MeV F5+离子和Ta原子碰撞中Ta产生的L壳层X射线。计算了Ta的L各支壳层产生截面的比值和总截面的比值。利用L壳层的辐射跃迁几率、Croster-Kroning跃迁几率和L亚壳层的荧光产额,将平面波波恩近似(PWBA)和ECPSSR理论计算的电离截面转换为L层X射线产生截面,并与实验结果进行比较。结果表明,σ(Ll)/σ(Lα)、σ(Lγ)/σ(Lα)和σ(Ltotal)/σ(Lα)与ECPSSR理论预测结果吻合较好,σ(Lβ)/σ(Lα)较两种理论预测值均偏小。

p53腺病毒重组体转染对p53缺失肿瘤细胞辐射敏感性的影响

目的观察p53腺病毒重组体(AdCMV-p53)转染对p53缺失肿瘤细胞辐射敏感性的影响。方法用腺病毒重组体(AdCMV-p53/GFP)转染经0、0.25、0.5、1.0、1.5、2.0Gyγ射线辐射的H1299(nullp53)和PC-3(nullp53)细胞,用流式细胞分析法检测外源性p53表达,用克隆形成法检测肿瘤细胞增殖能力。结果辐射联合AdCMV-p53转染组p53阳性细胞所占比例均明显高于单纯辐射组、单纯AdCMV-p53转染组和辐射联合AdCMV-GFP转染组同种细胞p53阳性率(P<0.05);AdCMV-p53转染不仅明显提高肿瘤细胞辐射敏感性,而且与肿瘤细胞组织来源有关。结论p53腺病毒重组体转染对p53基因缺失肿瘤细胞低剂量辐射敏感性的增强作用与肿瘤细胞来源的组织器官和细胞类型有关。

锇的一个重同位素:~(197)Os

利用14 MeV中子轰击天然铂靶,通过~(198)Pt(n,2p)~(197)Os反应产生锇的一种同位素~(197)Os,以γ(X)谱学方法鉴别了它,同时研究了它的衰变性质。观测到了能量为41.2、50.7、196.8、199.6、223.9、233.1、250.2、342.1、403.6和406.4keV的10条新γ射线,并指定为~(197)Os的衰变。测定它的半衰期为2.8±0.6 min。

~(141)Nd激发态的在束γ谱学研究

通过1 3 0 Te(1 6O ,5nγ) 1 4 1 Nd反应布居了1 4 1 Nd的高自旋态能级 .对反应产生的在束γ射线进行了γ射线单谱和γ -γ符合测量 .建立了激发能达 76 1 4 .5keV的1 4 1 Nd能级纲图 ,新发现了 1 2条γ射线和 1 5个能级 .基于实验测量的γ跃迁各向异性 ,建议了1 4 1 Nd部分能级的自旋值 .用一个h1 1 2 价中子空穴与1 4 2 Nd核芯晕态的耦合可以定性地解释1 4 1 Nd的能级结构

加速器自动调束系统的研究

描述了加速器自动调束系统的设计方法,介绍了加速器调束工作的现状和实现自动调束的意义,阐述了基于遗传算法进行加速器自动调束的原理和加速器自动调束系统的设计方法,给出了计算机仿真实验结果,并指出了自动调束研究的发展方向.

Thermodynamic study of ibuprofen by adiabatic calorimetry and thermal analysis

Molar heat capacities of ibuprofen were precisely measured with a small sample precision automated adiabatic calorimeter over the temperature range from 80 to 400 K. The polynomial functions of C-p,C-m (J K-1 mol(-1)) versus T were established on the heat capacity measurements by means of the least fitting square method. The functions are as follows: for solid ibuprofen, at the temperature range of 79.105 K less than or equal to T less than or equal to 333.297 K, C-p,C-m = 144.27 + 77.046X + 3.5171X(2) + 10.925X(3) + 11.224X(4), where X = (T - 206.201)/127.096; for liquid ibuprofen, at the temperature range of 353.406 K less than or equal to T less than or equal to 378.785 K, C-p,C-m = 325.79 + 8.9696X - 1.6073X(2) - 1.5145 X-3, where X = (T - 366.095)/12.690. A fusion transition at T = 348.02 K was found from the C-p-T curve. The molar enthalpy and entropy of the fusion transition were determined to be 26.65 kJ mol(-1) and 76.58 J mol(-1) K-1, respectively. The thermodynamic functions on the base of the reference temperature of 298.15 K, (H-T - H-298.15) and (S-T - S-298.15), were derived. Thermal characteristic of ibuprofen was studied by thermo-gravimetric analysis (TG-DTG) and differential scanning calorimeter (DSC). The temperature of fusion, the molar enthalpy and entropy of fusion obtained by DSC were well consistent with those obtained by adiabatic calorimeter. The evaporation process of ibuprofen was investigated further by TG and DTG, and the activation energy of the evaporation process was determined to be 80.3 +/- 1.4 kJ mol(-1). (C) 2003 Elsevier B.V. All rights reserved.

长白山各植被带主要树种凋落物分解速率及模型模拟的试验研究

2001～2003年在长白山自然保护区内3个垂直植被带的典型群落红松阔叶林、云冷杉林和岳桦林内,利用网袋埋藏法对群落内的6个主要优势乔木树种凋落物进行埋藏分解试验,研究凋落物分解速率及其变化动态;同时利用分解模型,模拟预测凋落物的分解进展,为深入研究这6个树种的营养策略、群落养分循环等奠定基础,也为森林生态系统管理提供理论依据。研究结果表明,所研究的6个树种凋落物都表现出随时间进程失重率增大的现象,但失重率并不与时间呈线性相关。在分解的638d(1.75a)后,6种叶凋落物的分解速率明显升高。到分解实验结止时(699d),叶凋落物干重剩余率从小至大依次为白桦(24.56%)、紫椴(24.81%)、红松(38.48%)、鱼鳞云杉(41.15%)、岳桦(41.53%)和臭冷杉(42.62%)。枝凋落物分解速率明显低于叶,枝干重剩余率从小至大依次为紫椴(44.98%)、臭冷杉(64.62%)、红松(72.07%)、鱼鳞云杉(73.51%)、白桦(77.37%)和岳桦(80.35%)。在同一海拔高度,阔叶树种叶凋落物分解速率大于针叶树种。并且随着海拔的升高,叶凋落物分解速率逐渐减慢。模型分析预测结果表明,长白山北坡各垂直植被带的优势树种叶凋落物分解95%需4.5～8.0a;年分解系数为紫椴(0.686)>白桦(0.624)>红松(0.441)>鱼鳞云杉(0.406)>臭冷杉(0.397)>岳桦(0.385);枝凋落物分解95%需7.8～29.3a,不同树种间的差异明显。枝年分解系数为紫椴(0.391)>臭冷杉(0.204)>红松(0.176)>鱼鳞云杉(0.157)>白桦(0.148)>岳桦(0.102)。

Molecular imprinting of nitrophenol and hydroxybenzoic acid isomers: effect of molecular structure and acidity on imprinting

Three nitrophenol isomer-imprinted polymers were prepared under the same conditions using 4-vinylpyridine as a functional monomer. Different recognition capacities for template molecules were observed for the three polymers. Another imprinting system with stronger acidity than nitrophenol isomers, 2-hydroxybenzoic acid (salicylic acid) and 4-hydroxybenzoic acid, was imprinted using 4-vinylpyridine or acrylamide as functional monomer respectively. Both 4-hydroxybenzoic acid-imprinted polymers using the two monomers showed recognition ability for the template molecule. However, when acrylamide was chosen as functional monomer, the salicylic acid-imprinted polymer showed very weak recognition for the template molecule, whereas strong recognition ability of the resultant polymer for salicylic acid was observed with 4-vinylpyridine as functional monomer. It seems that the structure and acidity of template molecules is responsible for the difference in recognition, by influencing the formation and strength of interaction between template molecule and functional monomer during the imprinting process. An understanding of the mechanism of molecular imprinting and molecular recognition of MIPs will help to predict the selectivity of MIPs on the basis of template molecule properties. Copyright (C) 2003 John Wiley Sons, Ltd.

timng of the last glacial maximum from observed sea level minima

During the Last Glacial Maximum, ice sheets covered large areas in northern latitudes, and global temperatures were significantly lower than today. But few direct estimates exist of the volume of the ice sheets, or the timing and rates of change during their advance and retreat. Here we analyze four distinct sediment facies in the shallow, tectonically stable Bonaparte Gulf, Australia - each of which is characteristic of a distinct range in sea level - to estimate the maximum volume of land-based ice during the last glaciation and the timing of the initial melting phase. We use faunal assemblages and preservation status of the sediments to distinguish open marine, shallow marine, marginal marine and brackish conditions, and estimate the timing and the mass of the ice sheets using radiocarbon dating and glacio-hydroisostatic modelling. Our results indicate that from at least 22,000 to 19,000 (calendar) years before present, land-based ice volume was at its maximum, exceeding today's grounded ice sheets by 52.5 x 10 exp 6 cu km. A rapid decrease in ice volume by about 10 percent within a few hundred years terminated the Last Glacial Maximum at 19,000 +/- 250 years.

土壤有机质对土霉素在土壤中吸附-解吸的影响

采用批量平衡方法,研究了土霉素在原土及去除有机质土壤中的吸附和解吸.结果表明,土霉素在原土和去除有机质土壤中的吸附和解吸等温线均不同程度地偏离线性模型,其中Freundlich模型可以对吸附和解吸数据进行良好的非线性拟合,在不同土壤以及不同土壤处理中的拟合相关系数(r)均达到极显著水平.去除有机质能够降低土霉素在土壤中的吸附容量(lgKf),但增加了吸附强度(1/n).土霉素在土壤上的解吸过程存在明显的滞后现象,在所设土霉素浓度范围内,土霉素在褐土和红壤中的平均滞后系数(HIa)分别为0.039和0.015;去除有机质后的褐土和红壤对土霉素的解吸滞后现象显著增强(P<0.01),其HIa分别增加到0.068和0.028.

畜禽粪便堆肥过程中各种氮化合物的动态变化及腐熟度评价指标

对不同畜禽粪便在堆肥过程中各种含氮化合物的动态变化进行了研究,结合综合性腐熟度评价指标——种子发芽指数(GI),探讨了畜禽粪便堆肥过程中与氮有关的腐熟度评价指标.结果表明:随着堆肥的进行,除奶牛粪外,其它畜禽粪便的全氮(TN)含量均呈先下降而后平稳变化趋势,奶牛粪则呈先增加而后平稳变化趋势;各种畜禽粪便中,碱解性氮(HN)含量先增后降;NH4+-N含量先下降而后保持平稳;NO3--N含量则持续增加;NH4+-N/NO3--N迅速降低.堆肥腐熟度指标中,除综合性评价指标GI值外,HN/TN和NH4+-N/TN也可作为评价畜禽粪便腐熟程度的优选指标,而NO3--N/TN只能作为一般性评价指标.根据综合性评价指标GI值达到腐熟要求的标准(GI>0.50),除仔猪粪外,其它畜禽粪便在HN/TN<20.77%、NH4+-N/TN<10.06%及NO3--N/TN>0.38%时基本达到腐熟要求.