1000 resultados para reações de substituição aromática nucleofílica
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Pós-graduação em Odontologia Restauradora - ICT
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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
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The aim of this article is to introduce the context when was created the Brazilian oil industry during the period known as “process of substitution of importation”, under influence of the 1930´s Liberal Revolution. The absence of national private capital, ally to disinterest of multinationals oil companies for developing this sector, particularly during the 1930´s, forced Brazilian State to structuralize a system to regulate and to stimulate oil production from a new entity: the National Oil Council, which takes for itself the task to building the Brazilian oil industry during the period 1938-1953.
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Pós-graduação em Ciência e Tecnologia Animal - FEIS
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Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
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Given the increasing demand for fossil fuels to power the engines of the global economy, and also the slow process of synthesis of oil, it becomes necessary to develop new sources of renewable energy in addition to improve promising sources that already exist, turning them competitive. Based on this, biomass is shown very promising between the most popular energy sources due to its availability, applicability, and above all, the fact of not emitting green house gases when analyzing the whole carbon cycle. In this sense, this work presents, through an environmental, technical and economic analysis, the impact in an aluminum mill of replacing the use of electricity, in one process, by a boiler fueled with biomass from waste process of packaging the finished product with pallets. Thus, besides the reduction of CO2 emissions, financial gains are targeted, since the main goal of the corporations that require such power is to maximize its profits
Durabilidade da argamassa mista de revestimento interno contendo dregs-grits em substituição à areia
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This paper concerns about the durability of new material in construction. It is noteworthy the fact that increases increasingly searching for alternative materials that do not depend only of natural resources and at the same time be an alternative for reuse of industrial waste. Since the construction materials have a long life and a high cost of civil works and maintenance, it is crucial to estimate the behavior of a new product. Thus , this work discuss the durability of mixed mortar lining , made with waste from the process Kraft pulp production , known as dregs and grits , in partial replacement of sand. Tests were conducted to simulate conditions as adverse environments of constant heat and fire, with the aim of analyzing the behavior of mortar mixed matched the behavior of standard mortar
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Cosmic radiation has been identi ed as one of the main hazard to crew, aircraft and sensitive equipments involved in long-term missions and even high-altitude commercial ights. Generally, shields are used in spatial units to avoid excessive exposure, by holding the incident radiation. Unfortunatelly, shielding in space is problematic, especially when high-energy cosmic particles are considered, due to the production of large number of secondary particles, mainly neutrons, protons and alpha particles, caused by spallation reactions and quasi-elastic processes of the corpuscular radiation with the shield. Good parameters for checking the secondary particle production at target material are diferential cross section and energy deposited in the shield. Addition experiments, some computer codes based on Monte Carlo method show themselves a suitable tool to calculate shield parameters, due to have evaluated nuclear data libraries implemented on the algorithm. In view of this, the aim of this work is determining the parameters evaluated in shielding materials, by using MCNPX code, who shows good agreement with experimental data from literature. Among the materials, Aluminium had lower emission and production of secondary particles
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Pós-graduação em Agronomia (Energia na Agricultura) - FCA
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Purpose of this monograph is a critical review of articles and publications worldwide. The insertion of green chemistry concepts in the curriculum components of general chemistry lab, plays a fundamental role in the early years of a Chemistry course towards early embed the philosophy of green chemistry. The fundamental concepts of green chemistry are highlighted in order to present the huge number of challenges in developing new chemistry l in research, industry and education. The practice of a chemical that takes into account ethical environmental attitudes thought since the formation of professionals, may lead to adoption of technical microscale, replacement of toxic agents, reduction of waste generation, etc. who snore a lot with the concept of sustainability
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Multicomponent Reactions are defined as reactions between three or more reagents in a single reaction step in the same reaction vial, forming a product that includes the majority of atoms and structural characteristics of the reagents. Thus these reactions save time and energy. One of the ways to improve the yield and reaction time of a multicomponent reaction is to use different catalysts, an example of catalyst that shows great potential and has been studied in recent years is the molecular iodine is known to be a Lewis acid with high catalytic power. The functionalized piperidines, also known as tetrahydropyridines, are alkaloids that have pharmacological potential, this is due to the piperidine ring present in many natural product structures with muscarinic activity, nicotine, analgesic, antipsychotic, anti-proliferative, among others. In this paper we describe studies about on the application of molecular iodine (I2) in the multicomponent reaction between aniline derivatives, benzaldehyde and β-ketoester (methyl acetoacetate) for the synthesis of functionalized piperidines and the synthesis of a corresponding piperidone by acid hydrolysis. Data analysis allowed us to demonstrate the efficacy of molecular iodine in the synthesis of functionalized piperidines, obtaining results with yields 44-87% and short reaction time of 8 to 24 hours, and the efficacy of acid hydrolysis of enamine in the structure of the tetrahydropyridine derivative in a yield of 81%
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Pós-graduação em Química - IQ
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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)