Chemical composition of a manganese nodule from the Pacific Ocean

By means of spectrographic analysis 96 samples of marine sediments were analyzed quantitatively for V, Ti, Zr, Co, Ni, Sc, Cr, and La, and semi-quantitatively for Ba and Sr. Ca has been estimated by visual comparison of spectrographic plates, and several Fe values have also been determined in the same way. Geographically 40 of these samples are from the Pacific Ocean basin, one of which is a manganese nodule, 21 from the Gulf of Mexico, 11 from Atchafalaya Bay, 8 from American Devonian to Miocene sedimentary rocks, 4 from the Mississippi Delta, 3 from the San Diego trough, 3 from off Grand Isle, 3 from Lake Pontchartrain, from Bay Rambour, 1 from Laguna Madre off the Texas coast, and 1 from the Guadalupe River, Texas. The afore-mentioned elements were sought using PdCl2 as an internal standard, after the method developed by Ahrens (1950) and his co-workers. Samples were run in duplicate, and standard deviations varied from 5 to 14 percent. Working curves, from which final values were obtained, were constructed with the use of standard granite, G1, and the standard diabase, W1, as standards. See Fairbairn and others (1951). An experiment was carried out to determine the effect of matrix change, involving CaCO3, on the spectral line intensities of the quantitatively analyzed elements. The distribution of each of the elements is discussed separately, and particular emphasis is given to oceanic "red clay", in which many elements are enriched. A general discussion is given to mineralogy of the sediments, cation exchange in its bearing on this thesis, and a brief recount of the two hypotheses of origin of oceanic "red clay". An application of the findings of this thesis to aid in the choice of the more likely hypothesis is made.

Age models and summer sea surface temperature and winter sea ice concentration for the EPILOG-LGM time slice in the Pacific Southern Ocean

Sea surface temperatures and sea-ice extent are the most critical variables to evaluate the Southern Ocean paleoceanographic evolution in relation to the development of the global carbon cycle, atmospheric CO2 variability and ocean-atmosphere circulation. In contrast to the Atlantic and the Indian sectors, the Pacific sector of the Southern Ocean has been insufficiently investigated so far. To cover this gap of information we present diatom-based estimates of summer sea surface temperature (SSST) and winter sea-ice concentration (WSI) from 17 sites in the polar South Pacific to study the Last Glacial Maximum (LGM) at the EPILOG time slice (19,000-23,000 cal. years BP). Applied statistical methods are the Imbrie and Kipp Method (IKM) and the Modern Analog Technique (MAT) to estimate temperature and sea-ice concentration, respectively. Our data display a distinct LGM east-west differentiation in SSST and WSI with steeper latitudinal temperature gradients and a winter sea-ice edge located consistently north of the Pacific-Antarctic Ridge in the Ross sea sector. In the eastern sector of our study area, which is governed by the Amundsen Abyssal Plain, the estimates yield weaker latitudinal SSST gradients together with a variable extended winter sea-ice field. In this sector, sea-ice extent may have reached sporadically the area of the present Subantarctic Front at its maximum LGM expansion. This pattern points to topographic forcing as major controller of the frontal system location and sea-ice extent in the western Pacific sector whereas atmospheric conditions like the Southern Annular Mode and the ENSO affected the oceanographic conditions in the eastern Pacific sector. Although it is difficult to depict the location and the physical nature of frontal systems separating the glacial Southern Ocean water masses into different zones, we found a distinct temperature gradient in latitudes straddled by the modern Southern Subtropical Front. Considering that the glacial temperatures north of this zone are similar to the modern, we suggest that this represents the Glacial Southern Subtropical Front (GSSTF), which delimits the zone of strongest glacial SSST cooling (>4K) to its North. The southern boundary of the zone of maximum cooling is close to the glacial 4°C isotherm. This isotherm, which is in the range of SSST at the modern Antarctic Polar Front (APF), represents a circum-Antarctic feature and marks the northern edge of the glacial Antarctic Circumpolar Current (ACC). We also assume that a glacial front was established at the northern average winter sea ice edge, comparable with the modern Southern Antarctic Circumpolar Current Front (SACCF). During the glacial, this front would be located in the area of the modern APF. The northward deflection of colder than modern surface waters along the South American continent leads to a significant cooling of the glacial Humboldt Current surface waters (4-8K), which affects the temperature regimes as far north as into tropical latitudes. The glacial reduction of ACC temperatures may also result in the significant cooling in the Atlantic and Indian Southern Ocean, thus may enhance thermal differentiation of the Southern Ocean and Antarctic continental cooling. Comparison with temperature and sea ice simulations for the last glacial based on numerical simulations show that the majority of modern models overestimate summer and winter sea ice cover and that there exists few models that reproduce our temperature data rather well.

Global distributions of coccolithophores abundance and biomass - Gridded data product (NetCDF) - Contribution to the MAREDAT World Ocean Atlas of Plankton Functional Types

Coccolithophores are calcifying marine phytoplankton of the class Prymnesiophyceae. They are considered to play an import role in the global carbon cycle through the production and export of organic carbon and calcite. We have compiled observations of global coccolithophore abundance from several existing databases as well as individual contributions of published and unpublished datasets. We estimate carbon biomass using standardised conversion methods and provide estimates of uncertainty associated with these values. The database contains 58 384 individual observations at various taxonomic levels. This corresponds to 12 391 observations of total coccolithophore abundance and biomass. The data span a time period of 1929-2008, with observations from all ocean basins and all seasons, and at depths ranging from the surface to 500 m. Highest biomass values are reported in the North Atlantic, with a maximum of 501.7 ?gCl-1. Lower values are reported for the Pacific (maximum of 79.4 ?gCl-1) and Indian Ocean (up to 178.3 ?gCl-1). Coccolithophores are reported across all latitudes in the Northern Hemisphere, from the Equator to 89degN, although biomass values fall below 3 ?gCl-1 north of 70degN. In the Southern Hemisphere, biomass values fall rapidly south of 50degS, with only a single non-zero observation south of 60degS. Biomass values show a clear seasonal cycle in the Northern Hemisphere, reaching a maximum in the summer months (June-July). In the Southern Hemisphere the seasonal cycle is less evident, possibly due to a greater proportion of low-latitude data.