Memoires de monsieur du Guay-Trouin, lieutenant general des armees navales de France, et commandeur de l'ordre royal & militaire de Saint Louis

Notas tipográficas retiradas de Brunet, v. 2, col. 1780.

Second mémoire présenté par les Etats Unis du Brésil au gouvernement de la Confédération Suisse, arbitre choisi selon les stipulations du Traité conclu a Rio de Janeiro, le 10 Avril 1897, entre le Brésil et la France : frontières entre le Brésil et la Guyane Française

Nota de conteúdo : V.1. Memoire en reponse aux allegations de la France, accompagne de quelques cartes -- V. 2-3. Documents accompagnes de notes explicatives ou rectificatives, 1. ptie, 1536-1713 ; 2. ptie, 1713-1896 -- V. 4. Texte original de documents traduits dans les tomes 2 et 3 -- V. 5. Album : fac-simile de quelques documents reproduits aux tomes 2, 3 et 4 -- V. 6. Atlas : contenant 86 cartes.

Voyages dans la partie septentrionale du Bresil, depuis 1809 jusqu'en 1815, comprenant les provinces de Pernambuco, Fernambouc, Seara, Paraiba, Maragnan, etc.

Titulo original : travels in brazil : in the years from 1809, to 1815.

Insights into the mechanism of human erythrocyte hexose transport : a transferred NOE study of glucose binding to GLUT1

This study examines binding of α- and β-D-glucose in their equilibrium mixture to the glucose transporter (GLUT1) in human erythrocyte membrane preparations by an ^1H NMR method, the transferred NOE (TRNOE). This method is shown theoretically and experimentally to be a sensitive probe of weak ligand-macromolecule interactions. The TRNOEs observed are shown to arise solely from glucose binding to GLUT1. Sites at both membrane faces contribute to the TRNOEs. Binding curves obtained are consistent with a homogeneous class of sugar sites, with an apparent K_D which varies (from ~30 mM to ~70 mM for both anomers) depending on the membrane preparation examined. Preparations with a higher proportion of the cytoplasmic membrane face exposed to bulk solution yield higher apparent KK_Ds. The glucose transport inhibitor cytochalasin B essentially eliminates the TRNOE. Nonlinearity was found in the dependence on sugar concentration of the apparent inhibition constant for cytochalasin B reversal of the TRNOE observed in the α anomer (and probably the β anomer); such nonlinearity implies the existence of ternary complexes of sugar, inhibitor and transporter. The inhibition results furthermore imply the presence of a class of relatively high-affinity (K_D < 2mM) sugar sites specific for the α anomer which do not contribute to NMR-observable binding. The presence of two classes of sugar-sensitive cytochalasin B sites is also indicated. These results are compared with predictions of the alternating conformer model of glucose transport. Variation of apparent K_D in the NMR-observable sites, the formation of ternary complexes and the presence of an anomer-specific site are shown to be inconsistent with this model. An alternate model is developed which reconciles these results with the known transport behavior of GLUT1. In this model, the transporter possesses (at minimum) three classes of sugar sites: (i) transport sites, which are alternately exposed to the cytoplasmic or the extracellular compartment, but never to both simultaneously, (ii) a class of sites (probably relatively low-affinity) which are confined to one compartment, and (iii) the high-affinity α anomer-specific sites, which are confined to the cytoplasmic compartment.

Reaction of glucose catalyzed by framework and extraframework tin sites in zeolite beta

The isomerization of glucose into fructose is a large-scale reaction for the production of high-fructose corn syrup, and is now being considered as an intermediate step in the possible route of biomass conversion into fuels and chemicals. Recently, it has been shown that a hydrophobic, large pore, silica molecular sieve having the zeolite beta structure and containing framework Sn⁴⁺ (Sn-Beta) is able to isomerize glucose into fructose in aqueous media. Here, I have investigated how this catalyst converts glucose to fructose and show that it is analogous to that achieved with metalloenzymes. Specifically, glucose partitions into the molecular sieve in the pyranose form, ring opens to the acyclic form in the presence of the Lewis acid center (framework Sn⁴⁺), isomerizes into the acyclic form of fructose and finally ring closes to yield the furanose product. Akin to the metalloenzyme, the isomerization step proceeds by intramolecular hydride transfer from C2 to C1. Extraframework tin oxides located within hydrophobic channels of the molecular sieve that exclude liquid water can also isomerize glucose to fructose in aqueous media, but do so through a base-catalyzed proton abstraction mechanism. Extraframework tin oxide particles located at the external surface of the molecular sieve crystals or on amorphous silica supports are not active in aqueous media but are able to perform the isomerization in methanol by a base-catalyzed proton abstraction mechanism. Post-synthetic exchange of Na⁺ with Sn-Beta alters the glucose reaction pathway from the 1,2 intramolecular hydrogen shift (isomerization) to produce fructose towards the 1,2 intramolecular carbon shift (epimerization) that forms mannose. Na⁺ remains exchanged onto silanol groups during reaction in methanol solvent, leading to a near complete shift in selectivity towards glucose epimerization to mannose. In contrast, decationation occurs during reaction in aqueous solutions and gradually increases the reaction selectivity to isomerization at the expense of epimerization. Decationation and concomitant changes in selectivity can be eliminated by addition of NaCl to the aqueous reaction solution. Thus, framework tin sites with a proximal silanol group are the active sites for the 1, 2 intramolecular hydride shift in the isomerization of glucose to fructose, while these sites with Na-exchanged silanol group are the active sites for the 1, 2 intramolecular carbon shift in epimerization of glucose to mannose.

Ratio of natural isotopes of nitrogen. I. Primary results: soils of Dombes [Translation from: Revue d'Ecologie et de Biologie du Sol 14, 279-287, 1977]

Utilization of the heavy isotope of nitrogen as a tracer has found numerous applications in soil biology. It allows better definition of different stages of the nitrogen cycle, in particular the immobilization-mineralization cycle. In this work, the authors report the results of calculations of natural isotope ratios of nitrogen in samples of water, soil and vegetation prevailing in Dombes and discuss the possibilities of errors and coefficients of fractionation.

Vision 2050: changement climatique, pêche et aquaculture en Afrique de l’Ouest Du 14 au 16 avril 2010, Dakar, Sénégal

Ce rapport présente les activités et les résultats de l’atelier Vision 2050: Changement climatique, pêche et aquaculture en Afrique de l’Ouest. Les objectifs de l’atelier étaient de discuter les questions critiques et les incertitudes auxquelles est confronté le secteur de la pêche et de l’aquaculture au Ghana, au Sénégal et en Mauritanie, d’élaborer des scénarios sectoriels pour 2050 et de discuter de l’implication de ces scénarios dans le contexte du changement climatique pour ces pays et la région ouest africaine.

A nonlinear systems model for the control mechanism of free fatty acid-glucose metabolosm in normal humans

A mathematical model is proposed in this thesis for the control mechanism of free fatty acid-glucose metabolism in healthy individuals under resting conditions. The objective is to explain in a consistent manner some clinical laboratory observations such as glucose, insulin and free fatty acid responses to intravenous injection of glucose, insulin, etc. Responses up to only about two hours from the beginning of infusion are considered. The model is an extension of the one for glucose homeostasis proposed by Charette, Kadish and Sridhar (Modeling and Control Aspects of Glucose Homeostasis. Mathematical Biosciences, 1969). It is based upon a systems approach and agrees with the current theories of glucose and free fatty acid metabolism. The description is in terms of ordinary differential equations. Validation of the model is based on clinical laboratory data available at the present time. Finally procedures are suggested for systematically identifying the parameters associated with the free fatty acid portion of the model.

Ecologie benthique de la Lagune Ebrié. Détermination du rapport de stabilité biocoenotique (RSB)

The 1912 Jaccard index modification led to the formulation of the Biocoenotic Stability Report (BSR). It is another similarity index based on the evaluation of two opposite ecological states affecting both compared biotopes.

Eléments nutritifs et production primaire dans les lagunes du Côte d'Ivoire : cycle annuel

This paper collects most of the information gathered between October 1974 and July 1976 within the framework of a research program concerning the hydrobioclimate of ivorian lagoons and especially the Ebrié lagoon. Monthly surveys concerning the latter were carried out during 1975. The following parameters - and their vertical distribution wherever it had a meaning - were systematically gathered in a system of fifty-five stations: Transparency (Secchi), Temperature, Salinity, Chlorophylla, Dissolved oxygen, phosphate, nitrate, nitrite. These data provide an outline of the annual cycle of nutrients and primary production of the Ivoirian lagoons

Variation saisonniere des structures hydrologique et dynamique du plateau continental ivoirien (VASPI I, II, III)

This data report contains all the meteorological, hydrological and dynamic data gathered during the VASPI cruises (I : from December 8th to December 13th 1982, II : from March 5th to March 9th 1983, and III : from October 6th to October 10th 1983) carried out along the continental shelf of Ivory Coast by the oceanographic ship "Andre NIZERY". These cruises, which represent a part of a coastal programme, are included in the more general scientific program FOCAL, whose main scientific objective is the study of the thermal context of the intertropical atlantic area.

Bibliographie courante des traveaux du centre (1958-1978)

This publication is an up-to-date review of the papers published by the researchers of the Oceanographic Research Center of Abidjan, since its beginnings (1958-1978).

Campagnes Chalci, Chalci 84-01 (du 17 au 25-01-84) et Chalci 84-02 (du 03 au 11-07-84): resultats des chalutages

This publication gives the results of bottom trawlings made during the cruises CHALCI 84-01 and CHALCI 84-02 by the oceanographic research vessel "Andre NIZERY" sur le plateau continental ivoirien.

Observations hydrologique et dynamique le long de deux radiales du plateau continental ivoirien durant l'année focale 1983

In this report, vertical distributions of the temperature and horizontal velocity components of the currents, got from the two sections BELIER (305 1'W) and VRIDI (4°O 5'W), carried out once a week during the 1983 year, on the Continental shelf of Ivory Coast, are shown.

Les acadjas traditionnels dans le sud-est du Bénin

This study mission on acadja, the traditional way of fishing in the lagoons of the South-East part of Benin, permits us to understand how well-established this fishing practice is, in terms of time and spatial extention. The exploitation of acadja has a great profitability but it also represents the source of some problems as deterioration of branches, deforestation and social conflits. However, when acadjas are rationally exploited, they constitute a hope for waters which are in the process of losing their biological richness.