Solid state NMR chemical shifts as an alternative to diffraction data in the determination of SIC polytypic structures

Silicon carbide, which has many polytypic modifications of a very simple and very symmetric structure, is an excellent model system for exploring, the relationship between chemical shift, long-range dipolar shielding, and crystal structure in network solids. A simple McConnell equation treatment of bond anisotropy effects in a poly type predicts chemical shifts for silicon and carbon sites which agree well with the experiment, provided that contributions from bonds up to 100 A are included in the calculation. The calculated chemical shifts depend on three factors: the layer stacking sequence, electrical centre of gravity, and the spacings between silicon and carbon layers. The assignment of peaks to lattice sites is proved possible for three polytypes (6H, 15R, and 3C). The fact that the calculated chemical shifts are very sensitive to layer spacings provides us a potential way to detennine and refine a crystal structure. In this work, the layer spacings of 6H SiC have been calculated and are within X-ray standard deviations. Under this premise, the layer spacings of 15R have been detennined. 29Si and 13C single crystal nmr studies of 6H SiC polytype indicate that all silicons and carbons are magnetically anisotropic. The relationship between a magnetic shielding tensor component and layer spacings has been derived. The comparisons between experimental and semi-empirical chemical shielding tensor components indicate that the paramagnetic shielding of silicon should be included in the single crystal chemical shift calculation.

Analysis of the late correspondence between our administration and Great Britain & France, with an attempt to show what are the real causes of the failure of the negotiation.

Ten pieces originally published in the Columbian Centinel. A later edition with imprint New York, Printed for E. Sargeant, 1809, contains two additional pieces.

Message from the President of the United States, transmitting communications from the plenipotentiaries of the United States charged with negotiating peace with Great Britain : showing the conditions on which alone that government is willing to put an end to the war. --

13th Congress, 3d session. House. Doc. 6.

A national monument to Laura Secord : why it should be erected, an appeal to the people of Canada /

Bibliography: p. 16.

An Act to authorise the stock held by private parties in the Welland Canal to be purchased on behalf of the Province [Welland Canal Stock Bill], 1841

The bill is a proposal by the government to purchase Welland Canal stock held in private hands. The bill was read for the first time on Wednesday 4 August, 1841, and received second reading on 10th August, 1841. One hundred and fifty copies were printed of the bill. This example was addressed to Samuel Street at the Falls of Niagara, by William Hamilton Merritt, September 1841.

An address, to the people of New-England

A vindication of Jefferson's administration.

A national monument to Laura Secord : why it should be erected, an appeal to the people of Canada

Bibliography: p. 16. Printed by Imrie, Graham and Co.

A Foucauldian Analysis of Power and Representation in an Attempt to Run a Photovoice Project with Youth

This project evolved out of a search for ways to conduct research on “others” in a way that does not exploit, stigmatize or misrepresent their experience. This thesis is an ethnographic study in leisure research and youth work and an experiment in running a photovoice project. Photovoice is a participatory visual method that embodies the emancipatory ideal of empowering others through self-representation. The literature on photovoice lacks a comprehensive discussion on the complexity of power and representation. Postmodern theorists have proposed that participatory methods are not benign and that initiatives are acts of power in themselves that produce effects (Cook & Kothari, 2001). A Foucauldian analysis of power is used to deconstruct the researcher’s practice and reflect on why and how youth are “engaged”. This project seeks to embrace the principle of working “with” others, but also work from a postmodern perspective that acknowledges power and representation as ongoing problems.

Letter - Wilfrid Laurier to A. Munro Grier, 18 September 1901

A letter from Prime Minister Wilfrid Laurier to A. Munro Grier regarding an invitation to His Royal Highness. This is possibly referencing the Royal visit of the Duke of Cornwall in the year 1901. The Royals were due to tour Canada September and October of that year, with a stop in the Niagara area October 13th.

Funeral Invitation - February 5, 1856

An invitation to the funeral of Mrs. John W. Ball. The invitation reads: Niagara, February 5th, 1856. Sir--- You are requested to attend the Funeral of the late Mrs. John W. Ball, from the Residence of her husband to the Place of Internment, on Thursday the 7th Instant, at the hour of Two O'Clock in the afternoon.

Invitation: 61st Inter-Parliamentary Conference Tokyo 1974 Inaugural Ceremony

An invitation to the Inaugural Ceremony of the 61st Inter-Parliamentary Conference in Japan October 1974. The invitation reads: "The Japanese Group of the Inter-Parliamentary Union has the honour of inviting you to attend the Inaugural Ceremony of the 61st Inter-Parliamentary Conference to be held in the Chamber of the House of Councillors on Wednesday the 2nd of October 1974, at 3 p.m. The Ceremony will be honoured by the presence of Their Majesties the Emperor and Empress of Japan".

Father Sean O'Sullivan Ordination Invitation

An invitation to the ordination of Father Sean O'Sullivan, October 1981. The ordination took place at St. Michael's Cathedral in Toronto, 3 October 1981. His first Mass of Thanksgiving took place the next day at St. John's Church in Toronto.