959 resultados para Chiral symmetry restoration


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For a toric Del Pezzo surface S, a new instance of mirror symmetry, said relative, is introduced and developed. On the A-model, this relative mirror symmetry conjecture concerns genus 0 relative Gromov-Witten of maximal tangency of S. These correspond, on the B-model, to relative periods of the mirror to S. Furthermore, for S not necessarily toric, two conjectures for BPS state counts are related. It is proven that the integrality of BPS state counts of the total space of the canonical bundle on S implies the integrality for the relative BPS state counts of S. Finally, a prediction of homological mirror symmetry for the open complement is explored. The B-model prediction is calculated in all cases and matches the known A-model computation for the projective plane.

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Projects of the scope of the restoration of the Florida Everglades require substantial information regarding ecological mechanisms, and these are often poorly understood. We provide critical base knowledge for Everglades restoration by characterizing the existing vegetation communities of an Everglades remnant, describing how present and historic hydrology affect wetland vegetation community composition, and documenting change from communities described in previous studies. Vegetation biomass samples were collected along transects across Water Conservation Area 3A South (3AS).

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We address the influence of the orbital symmetry and the molecular alignment with respect to the laser-field polarization on laser-induced nonsequential double ionization of diatomic molecules, in the length and velocity gauges. We work within the strong-field approximation and assume that the second electron is dislodged by electron-impact ionization, and also consider the classical limit of this model. We show that the electron-momentum distributions exhibit interference maxima and minima due to electron emission at spatially separated centers. The interference patterns survive integration over the transverse momenta for a small range of alignment angles, and are sharpest for parallel-aligned molecules. Due to the contributions of the transverse-momentum components, these patterns become less defined as the alignment angle increases, until they disappear for perpendicular alignment. This behavior influences the shapes and the peaks of the electron-momentum distributions.

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A set of coupled-channel differential equations based on a rotationally distorted optical potential is used to calculate the wave functions required to evaluate the gamma ray transition rate from the first excited state to the ground state in ^(13)C and ^(13)N. The bremsstrahlung differential cross section of low energy protons is also calculated and compared with existing data. The marked similarity between the potentials determined at each resonance level in both nuclei supports the hypothesis of the charge symmetry of nuclear forces by explaining the deviation of the ratios of the experimental E1 transition strengths from unity.

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The use of pseudoephedrine as a practical chiral auxiliary for asymmetric synthesis is describe. Both enantiomers of pseudoephedrine are inexpensive commodity chemicals and can be N-acylated in high yields to form tertiary amides. In the presence of lithium chloride, the enolates of the corresponding pseudoephedrine amides undergo highly diastereoselective a1kylations with a wide range of alkyl halides to afford α-substituted products in high yields. These products can then be transformed in a single operation into highly enantiomerically enriched carboxylic acids, alcohols, and aldehydes. Lithium amidotrihydroborate (LAB) is shown to be a powerful reductant for the selective reduction of tertiary amides in general and pseudoephedrine amides in particular to form primary alcohols.

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Loch Fleet is a small upland lake in the hills of Galloway in southwest Scotland. In the 1970s the waters of the loch became more acidic and a brown trout fishery failed. This account summarises an experimental project, the "Loch Fleet Project" initiated in 1984, designed to reverse acidification of the loch by liming parts of the catchment. Liming about 40% of the catchment in 1986 and 1987 raised the pH and calcium levels, and reduced toxic aluminium concentrations. The improved conditions had been maintained up to 1994, but water in the loch, and its principal inflow stream, is now falling close to the desired threshold of quality. After liming, restocking with local strains of trout in 1987 was successful, and a self-recruiting population became established within 2 years. Recruitment is highly variable, however, and was attributed to severe spring conditions and the limited spawning capacity of the nursery stream, rather than to water quality.

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The authors present the findings of a restoration project in Loch Enoch in Scotland. There are historical references that brown trout was present in Loch Enoch up to the 1920s but it is believed the acidity of loch triggered the disappearance of Salmo trutta. The recent observed reduction in the acidity of L. Enoch to a level close to that found in nearby lochs with trout populations, suggested that trout might now survive in L. Enoch. For a population to survive, all stages in the life-cycle of a species must be able to develop. Accordingly, tests were undertaken, first with eggs and fry. The availability of food was also studied. In October 1994, 3,000 yearling trout of L. Grannoch origin which had been reared in a local hatchery were distributed throughout the loch. The fish population was studied from 1995-98. The authors conclude that survival of the trout population is possible if the acidity of the loch water remains low.