Convento de S. José da Esperança - Évora: proposta de valorização histórico-arquitectónica

A presente dissertação de mestrado visa a apresentação de uma proposta de valorização para o espaço edificado do Convento de S. José da Esperança, da cidade de Évora. Procurámos traçar a história do Convento de S. José ao longo de um período de cerca de 200 anos, apresentando ainda as várias funções do imóvel, desde a sua extinção até à atualidade. Abordámos a questão da instalação física do cenóbio, relacionando-a com as razões da escolha da Ordem Carmelita Descalça. Contextualizámos este especto com as origens da Ordem do Carmo, a reforma desta Ordem, originando o nascimento da Ordem Carmelita Descalça, e a sua entrada em Portugal. Sublinhámos a importância das fundadoras e o seu legado testamentário para a subsistência desta instituição religiosa e como essa subsistência conheceu vicissitudes e contrariedades várias ao longo da vida da comunidade. Procurámos depois entender o espaço conventual edificado, pelo que procedemos a uma análise histórico-arquitetónica do conjunto conventual, nomeadamente a ampliação dos espaços, e depois da extinção e da mudança de propriedade, a adaptação a novas funções e as necessárias intervenções nele ocorridas. Por fim, atendendo à história do Convento, à riqueza patrimonial que ele representa tanto para a sociedade em geral como para os Eborenses em particular, atendendo à sua inserção no Centro Histórico de Évora - CHE, com a classificação de Património Mundial atribuída pela UNESCO em 1986, e atendendo ao vasto quadro legislativo nacional e internacional relativo à proteção e valorização do património cultural, apresentámos a nossa proposta de valorização do Conjunto Conventual, que nos parece, em conformidade com o exposto, a mais apropriada àquele espaço. ABSTRACT: This master's thesis aims to propose a recovery area for the valorization of the building space of Convento de S. José da Esperança, in Évora. We traced the history of the Convent of S. José over a period of about 200 years, by exploring the various functions of the building, since its extinction as religious community until now. We addressed the question of the physical installation the life of the religious community, linking it with the reasons for the choice of the Ordem Carmelita Descalça's to settle there. This aspect was then contextualized with the origins of the Ordem do Carmo, the reform of the Order, resulting in the birth of the Ordem Carmelita Descalça, and its entry into Portugal. We emphasized the importance of the founders and their legacy to the livelihood of the subsistence of this religious institution. Along the history the Ordem experienced several setbacks and problems over the life of the community. Our study led to an understanding of the conventual space as a physical building. For that we undertook an historical and architectonical analysis of the conventual set, namely the enlargement of spaces, and after the extinction and the property change, the adaptation to new functions and the necessary interventions that it suffered. We presented our proposal of historical and architectonical valorization of the convent, taking into account the history of the Convent, as a rich heritage, not only for the city of Évora, but also to the country, as a whole. We took into account the fact that the convent is inside the historical centre of Évora (World Heritage City- UNESCO- since 1986), and it must comply to national and international legislative framework for the protection and enhancement of cultural heritage. Our proposal of recovery of the conventual set is, in line with the above, the most appropriate to that space.

Local productive arrangements for biodiesel production in Brazil: Environmental assessment of small-holders integrated oleaginous crops management.

Sustainability assessments were carried out in small-holders? farms in four territories where productive arrangements have been organized for production of minor oleagi- nous crops under the Brazilian biodiesel program. The study aimed at checking local impacts of the biodiesel productive chains at the rural establishment scale, and pro- moting the environmental performance of the selected farms, henceforth proposed as sustainable management demonstration units. Assessments were carried out with the APOIA-NovoRural system, which integrates 62 objective and quantitative indicators re- lated to five sustainability dimensions: i) Landscape Ecology, ii) Environmental Quality (Atmosphere, Water and Soil), iii) Socio-cultural Values, iv) Economic Values and v) Management and Administration. The main results point out that, in general, the eco- logical dimensions of sustainability, that is, the Landscape Ecology and Atmosphere, Water, and Soil quality indicators, show adequate field conditions, seemingly not yet negatively affected by increases in chemical inputs and natural resources use predicted as important potential impacts of the agro-energy sector. The Economic Values indica- tors have been favorably influenced in the studied farms, due to a steadier demand and improved prices for the oleaginous crops. On the other hand, valuable positive conse- quences expected for favoring farmers? market insertion, such as improved Socio-cultural Values and Management & Administration indicators, are still opportunities to be ma-terialized. The Environmental Management Reports issued to the farmers, based on the presented sustainability assessment procedures, offer valuable documentation and com-munication means for consolidating the organizational influence of the local productive arrangements studied. These productive arrangements were shown to be determinant for the selection of crop associations and diversification, as well as for the provision of technical assistance and the stabilization of demand - conditions that promote value aggregation and income improvements, favoring small-holders? insertion in the market. More importantly, these locally organized productive arrangements have been shown to strongly influence the valorization of natural resources and environmental assets, which are fundamental if sustainable rural development is to take place under the emerging agro-energy scenario.

Valorização integrada de resíduos e subprodutos da extração do azeite: extração e caraterização de compostos bioativos do bagaço de azeitona

Dissertação de Mestrado, Tecnologia de Alimentos, Instituto Superior de Engenharia, Universidade do Algarve, 2016

Bebidas espirituosas do Algarve

Tese de Doutoramento, Química, Faculdade de Ciências e Tecnologia, Universidade do Algarve, 2016

Geografia da dominação: um estudo sobre a organização espacial da terra do sal (Macau-RN)

This work aims to understand the spatial organization in the Town of Macau, State of Rio Grande do Norte, Brazil. This approach focus on bringing back the history of the town, the main personages responsible for the construction of this place, denominated "social agents", as well as its social processes and the spatial forms derived from them. As the personages and their practices were identified, it was found out the existence of a driving force for structuring, interlocking, and maintaining the actions carried out by the social agents during the time. Such actions were materialized in the urban space: "the social segregation". The social segregation takes place as a specific geography of domination. The outcome of those owning the best areas" and ways of accessibility in the urban space, varies from the enrichment by property valorization, because of the concentration of public investments of infrastructure, to the comfort of easily reaching all the daily needs related to the displacements in the urban space. In the latter case, such facility has contributed to improve life quality. While one takes advantage of the location in the urban space, others are negatively affected by the same process. This research identified the salina worker as the weakest element of this social structure, occupying the urban periphery of the town of Macau. Such area is characterized by the lack of services and urban equipment in opposition to the center of the town, the locus of elite. This way, it is established the most known segregation pattern: center x periphery, in which the space acts as a mechanism of segregation

Paisagem, um patrimônio esquecido: subsídios para a construção de uma metodologia de valoração e proteção do cenário natural litorâneo

The so-called "residential tourism" came to intensify the previous occupation of the coastal zones, characterized by traditional beach houses, and brought significant consequences for their spatial configuration, and especially for its scenic value of the landscape. Although there is the intention to regulate the activities of enterprising groups by some legal instruments to control the use and occupation of land, and to contain some negative effects, the actions of government are still inefficient in trying to follow the implications on the landscape from the accelerated growth of the real estate and touristic sectors. Supported in the speech of economic development and income generation, public managers prioritize areas to attract tourists to the detriment of preserving important physical attributes of the natural environment that contribute significantly to the quality of life. The result can be noticed in the use of natural elements as one of the major components in the land valorization, and in the immediate attraction of investors and enterprising. Therefore, the objective of this work is to contribute to the debate on the landscape preservation a little detailed thematic in view of their relevance in the current context - by indicating subsidies to the creation of a methodology for the evaluation and protection of coastal zones that may assist the government in creating new instruments, and better prepare it in control of the occupation of these areas. For such, was followed two ways to analysis: the indirect method and the direct method. The first is grounded in the evaluation of landscape attributes, which is based on the work of Raquel Tardin (2008) and Eduardo Cuesta, Encarnación Algarra and Isabel Pastor (2001). The second, based on the research of Leticia and Carlos Hardt (2010) and on the concepts of phenomenology - expressed by Antonio Christofoletti (1985) and Yi-Fu Tuan (1983) - considers the population perspective on the quality of the natural scenery. Developed through cartographic materials, photographic collections and quantitative tables, this dissertation utilized as a case study the beaches of Barra de Tabatinga and Camurupim, located in the city of Nísia Floresta/RN. Despite already being sighted spaces of advanced stage of landscape degradation in these locations, areas of remarkable scenic value can still be found, what reinforce the urgency in adopting preservationists actions. The absence of laws focused on the management and protection of the landscape singularities associated with the inefficiency of the government to invigilate the land occupation in coastal zones, encourage the excessive action of the real estate-tourism, and consequently make the government the main responsible for the environmental and landscape impacts in these areas - by its omission or by their connivance. Therefore, the legislation permeates this entire process and constitutes itself as the most effective way to guarantee the right to the landscape to present and future generations. Are also pointed some important considerations to build a methodology, especially concerning possibilities of improvements and adaptations of its applicability in each case

Urban Agriculture Oriented towards Self-Supply, Social and Commercial Purpose: A Typology

Urban agriculture, a dynamic multifunctional phenomenon, affects the spatial diversification of urban land use, its valorization and its governance. Literature acknowledges its contribution to the development of sustainable cities. The dimension and extent of this contribution depends significantly on the particular form and function of urban agriculture. However, the complexity of interests and dimensions is insufficiently covered by theory. This paper proposes a typology for urban agriculture, supporting both theory building and practical decision processes. We reviewed and mapped the diversity of the types of agriculture found along three beneficial dimensions (self-supply, socio-cultural, commercial) for product distribution scale and actors. We distinguish between ideal types, subtypes and mixed types. Our intention is to include a dynamic perspective in the typology of urban agricultural land use because transition processes between types are observable due to the existence of complex motivations and influences. In a pilot study of 52 urban agriculture initiatives in Germany, we tested the validity of the typology and discussed it with stakeholders, proving novelty and relevance for profiling discussions.

On The Use of Genetic Algorithms for Parameter Identification in Anaerobic Digestion Modelling

Anaerobic digestion (AD) of wastewater is a very interesting option for waste valorization, energy production and environment protection. It is a complex, naturally occurring process that can take place inside bioreactors. The capability of predicting the operation of such bioreactors is important to optimize the design and the operation conditions of the reactors, which, in part, justifies the numerous AD models presently available. The existing AD models are not universal, have to be inferred from prior knowledge and rely on existing experimental data. Among the tasks involved in the process of developing a dynamical model for AD, the estimation of parameters is one of the most challenging. This paper presents the identifiability analysis of a nonlinear dynamical model for a batch reactor. Particular attention is given to the structural identifiability of the model, which considers the uniqueness of the estimated parameters. To perform this analysis, the GenSSI toolbox was used. The estimation of the model parameters is achieved with genetic algorithms (GA) which have already been used in the context of AD modelling, although not commonly. The paper discusses its advantages and disadvantages.

Histoire et projet dans la valorisation du patrimoine de la soie : Le Filatoio di Caraglio (Coni. Italie) et le Real Filatório de Chacim (Trás-os-Montes, Portugal)

O objetivo deste trabalho é explorar a temática da valorização do patrimônio arquitetónico, herdado pela indústria da seda, baseando-se na história das técnicas, na gestão e na valorização do patrimônio industrial. É a partir do estudo de duas fábricas de seda na Europa: o Filatoio di Caraglio em Itália (data de construção: 1676-1678) e o Real Filatório de Chacim em Portugal (data de construção: 1788) que serão discutidas as estratégias encontradas para a conservação/restauração dos dois casos em questão, com base em suas histórias e contextos atuais. O Filatoio di Caraglio é uma das fábricas de seda mais antigas da Europa tendo como técnica o moinho alia piemontese publicado na Encyclopédie como uma das melhores invenções. No caso do Real Filatório de Chacim, constata-se que a introdução deste moinho por meio de técnicos italianos constituiu uma transferência tecnológica entre os dois países. RÉSUMÉ: L'objective de ce travail est d'explorer la thématique de la mise en valeur du patrimoine architectural hérité de industrie de la soie en se basent sur l'histoire des techniques, la gestion et la valorisation du patrimoine industriei. C'est à partir de l'étude de deux fabriques à soie en Europe: le Filatoio di Caraglio en Italie (date de construction: 1676-1678) et le Real Filatório de Chacim au Portugal (date de construction: 1788) que sont discutées les stratégies employées pour la conservation/restauration de ces deux cas basées sur leur histoire et sur les contextes actuels. Le Filatoio di Caraglio est une des soieries plus anciennes de l'Europe et était caractérisée par une technique du moulin alla piemontese publié dans l'Encyclopédie come une des meilleures inventions. Dans le cas du Real Filatório de Chacim, on constate que l'introduction de ce type de moulin par des techniciens italiens a constitué un transfert technique entre les deux pays. ABSTRACT: The purpose of this research is to examine the enhancement of architectural heritage inherited from the silk industry, focusing on technical history, and the management and valorization of industrial heritage. Conservation/restoration strategies are discussed by analyzing solutions proposed in two European silk mills: The Filatoio di Caraglio, in Italy (date of construction: 1676-1678) and the Real Filatório de Chacim, in Portugal (date of construction: 1788), taking into consideration their histories and current context. While the former is one of the oldest European silk mills, employing the alla piemontese technique, which was praised by the Encyclopédie, the latter was set up by ltalian technicians, establishing a technology transfer between the two countries.

Proposta de valorização de espaço aberto público da aldeia da Luz

A construção da barragem do Alqueva causou várias transformações na paisagem ao nível sócioeconómico e ecológico. A submersão da antiga aldeia da Luz foi resultado desta construção, com consequente construção de uma nova aldeia. Um acontecimento que é marcante na história do Alqueva. O objetivo do trabalho de projeto é valorizar os espaços abertos públicos da nova aldeia e espaço envolvente. Esta estratégia assentou no reconhecimento e valorização dos sistemas ecológicos e culturais aí presentes, e na valorização do potencial turístico que lhe está associada. A metodologia do trabalho inclui uma análise das aldeias e realização de um inquérito à população (habitantes, residentes ocasionais e visitantes) com o fim de melhor responder aos seus anseios no presente. O trabalho culmina com a Proposta de Valorização de Espaço Aberto Público para a aldeia da Luz e espaço próximo envolvente e com o Plano de Estrutura Ecológica e Cultural (urbana e rural); Aldeia da Luz: towards the open public spaces valorization ABSTRACT: The construction of the Alqueva dam has caused several landscape transformations, in the socioeconomical, ecological matter. The submersion of the old Luz village was a direct result of this construction, with the consequent construction of a new Luz village. An event, which is remarkable in the Alqueva history. The project work objective is to value the public open spaces of the new village and its surrounding space. This strategy settled on the recognition and appreciation of the existing ecological and cultural systems, and in the touristic potential that is associated with it. The work methodology includes analysis of the villages and a survey fulfilment targeting the population (habitants, occasional residents and visitors) with the intent of better answering their current desires. The work culminates with the Public Open Space Appreciation Proposal for the Luz village and nearby surrounding space, and with the Ecological and Cultural Structures Plan (urban and rural).

Innovazione sociale, sviluppo e turismo: quale legame? Uno studio teorico ed empirico nella citta di Bologna.

La ricerca è nata dalla volontà di indagare il legame tra innovazione sociale, sviluppo e turismo. La domanda di ricerca che ha guidato questo lavoro ha assunto una duplice natura. Il primo obiettivo, di natura teorica, è stato quello di concettualizzare l’IS attraverso uno studio comparativo della letteratura internazionale, definendone le dimensioni e i processi di diffusione. Dal punto di vista empirico, è stata effettuata una ricerca-azione di tipo qualitativo nella città di Bologna. Partendo da un approfondimento storico che ha analizzato alcune peculiarità territoriali – il movimento cooperativo, i distretti industriali, etc. – l’indagine ha fornito una prima panoramica del fenomeno attraverso una mappatura delle realtà bolognesi. I risultati emersi hanno dimostrato che i legami tra IS, sviluppo e turismo sono complessi. L’IS comporta delle conseguenze per il territorio, andando ad intervenire all’interno dei processi di sviluppo. Nel rispondere a bisogni emergenti, essa promuove agency ed empowerment, creatività e capitale sociale abilitante. In un’ottica di sviluppo territoriale integrato, l’IS agisce sul processo di capacitazione, sia attraverso la valorizzazione del capitale sociale e la creazione di reti, sia attraverso processi di negoziazione e conflitto. L’indagine ha mostrato che tra turismo e IS esiste una triplice relazione. Innanzitutto, il turismo può essere considerato come uno strumento di analisi per osservare l’IS, ma la relazione avviene soprattutto a livello di pratiche sociali. Esistono, infatti, a Bologna diversi casi di iniziative di IS che diventano esperienze turistiche e viceversa. Citando Lefebvre, quando IS e turismo trovano spazi di intersezione emerge un duplice diritto alla città. Un diritto che si manifesta nella (ri)appropriazione di spazi fisici e simbolici dove si collocano le relazioni sociali e dove si elaborano progettualità condivise e dove la comunità può partecipare, supportando la capacità di aspirare dei soggetti locali

Development of a thermochemical/biological process to convert waste biomass into new resources

The increasing attention to environmental issues of recent times encourages us to find new methods for the production of energy from renewable sources, and to improve existing ones, increasing their energy yield. Most of the waste and agricultural residues, with a high content of lignin and non-hydrolysable polymers, cannot be effectively transformed into biofuels with existing technology. The purpose of the study was to develop a new thermochemical/ biological process (named Py-AD) for the valorization of scarcely biodegradable substances. A complete continuous prototype was design built and run for 1 year. This consists into a slow pyrolysis system coupled with two sequential digesters and showed to produce a clean pyrobiogas (a biogas with significant amount of C2-C3 hydrocarbons and residual CO/H2), biochar and bio-oil. Py-AD yielded 31.7% w/w biochar 32.5% w/w oil and 24.8% w/w pyrobiogas. The oil condensate obtained was fractionated in its aqueous and organic fraction (87% and 13% respectively). Subsequently, the anaerobic digestion of aqueous fraction was tested in a UASB reactor, for 180 days, in increasing organic loading rate (OLR). The maximum convertible concentration without undergoing instability phenomena and with complete degradation of pyrogenic chemicals was 1.25 gCOD L digester-1 d-1. The final yield of biomethane was equal to 40% of the theoretical yield and with a noticeable additional production equal to 20% of volatile fatty acids. The final results confirm that anaerobic digestion can be used as a useful tool for cleaning of slow pyrolysis products (both gas and condensable fraction) and the obtaining of relatively clean pyrobiogas that could be directly used in internal combustion engine.

Appropriate technologies and natural systems for wastewater treatment in low- and middle-income countries

Wastewater management is an environmental and social burden that primarily affects populations in Low- and Middle-Income Countries and the global environment. Wastewater collection, treatment, and reuse have become urgent, especially considering that 80% of the world's wastewater is untreated or improperly treated and discharged directly into water bodies. In recent years, the role of wastewater treatment plants in a sustainable water cycle has become even more critical, as they are the final destination of the collected wastewater. Indeed, the management of wastewater treatment plants should play an essential role in achieving SDG target 6.3 of the United Nations 2030 Agenda for SD. In this context, water reuse, especially wastewater reuse, plays a key role. This research focuses on investigating the valorization of wastewater resources applying Appropriate Technologies and Natural Systems for wastewater treatment in two different Low- and Middle-Income Countries, the Palestinian Territories and Sub-Saharan Africa. The research objectives are: (1) Determine the characteristics and quality of wastewater in the two case studies analysed. (2) Identify Appropriate Technology to be used in the Palestinian Territories to treat wastewater for reuse in agriculture. (3) Assess the environmental, economic, and social impacts of this project. (4) Assess the feasibility of using natural wetlands for household wastewater treatment in Sub-Saharan region. The first study, conducted in Rafah, Gaza Strip, showed that implementing existing primary treatment plant with a natural secondary treatment plant properly optimized the wastewater quality for reuse in agriculture and was suitable for the study area. The second case study was conducted in Cape Coast, Ghana. It shows that the natural wetland studied is currently overly polluted and threatened by various anthropogenic factors that cannot remove pollutants from the incoming domestic wastewater. Therefore, some recommendations were made in order to improve the efficiency of this natural wetland.

Catalytic reduction of levulinic acid derivatives to bio-fuel components

Levulinic Acid and its esters are polyfunctional molecules obtained by biomass conversion. The most investigated strategy for the valorization of LA is its hydrogenation towards fuel additives, solvents and other added-value bio-based chemicals and, in this context, heterogeneous and homogeneous catalysts are widely used. Most commonly, it is typically performed with molecular hydrogen (H2) in batch systems, with high H2 pressures and noble metal catalysts. Several works reported the batch liquid-phase hydrogenation of LA and its esters by heterogenous catalysts which contained support with Brønsted acidity in order to obtain valeric acid and its esters. Furthermore, bimetallic and monometallic systems composed by both a metal for hydrogen activation and a promoter were demonstrated to be suitable catalysts for reduction of carboxylic group. However, there were no studies in the literature reporting the hydrogenation of alkyl levulinates to 1-pentanol (1-PAO). Therefore, bimetallic and monometallic catalysts were tested for one-pot hydrogenation of methyl levulinate to 1-PAO. Re-based catalysts were investigated, this way proving the crucial role of the support for promoting the ring-opening of GVL and its consecutive reduction to valeric compounds. All the reactions were performed in neat without the need of any additional solvents. In these conditions, bimetallic Re-Ru-O/HZSM-5 afforded methyl valerate and valeric acid (VA) with a productivity of 512 mmol gmetal-1 h-1, one of the highest reported in literature to date. Rhenium can also promote the reduction of valeric acid/esters to PV through the formation of 1-pentanol and its efficient esterification/transesterification with the starting material. However, it was proved that Re-based catalysts may undergo leaching of active phase in presence of carboxylic acids, especially by working in neat with VA. Furthermore, the over-reduction of rhenium affects catalytic performance, suggesting not only that a pre-reduction step is unnecessary but also that it could be detrimental for catalyst’s activity.

Toward wellbeing: investigation of traditional, classical and innovative approaches to improve population and environmental health

As the word population continues to grow and global resources are limited, the WHO definition of health is difficult to achieve for a large part of the population. Humanity is facing the need to improve both environmental and human wellbeing. This can be done through careful planning and management of natural resources, ensuring food safety and reducing and converting wastes. This work aims to contribute to the improvement of population and environmental health exploring different research fields: urban park ecosystem services, food chemical risk assessment and agri-food by-product valorization. To highlight the importance of urban parks and their ecosystem services, an ethnobotanical study was carried out in the Ausa urban park in Rimini, using a citizen science approach. The results showed that Ausa Park is an important focal point for plant gatherers in Rimini, as it allows for plant foraging and contributes to preserve the knowledge of the use of plants. Two food safety studies were carried out, looking at the exposure of Poles to bisphenol A through the consumption of soft drinks and to cadmium through the consumption of chocolate bars. The results, compared with EFSA’s scientific opinion, show that the exposure of the Polish population to BPA is of health concern, while cadmium is not. In the agri-food by-product valorization, a green extraction method was optimized to recover valuable phenolic compounds from red-fleshed apple pomace; moreover, the possibility of recovering pectin from the residue was evaluated. Furthermore, valuable compounds in four different types of wheat milling by-products, considered as an alternative source of bioactive compounds with potential human health benefits, were investigated. In conclusion, this work produced usable data in urban green area management and planning, in food chemical risk assessment and in business production decisions, thus contributing to improving environmental and people wellbeing.