Vein mineral ages of oceanic crust from the Atlantic Ocean

Vein smectites with large Rb/Sr enrichments from extensively altered basaltic oceanic crust in Deep Sea Drilling Project hole 417A in the western Atlantic define a highly constrained Rb/Sr isochron age of 108 +/- 3 m.y. This age is identical to a less well constrained age of 108 +/- 17 m.y. for vein smectites with lower Rb/Sr enrichments from adjacent hole 418A and to the 108 m.y. age of crust formation derived by paleontological and magnetic anomaly correlation. Reasonable agreement exists between the 87Sr/86Sr ratio of vein calcites from both sites and the seawater 87Sr/86Sr ratio at the time. Pervasive low-temperature alteration in the contrasting environments of sites 417 and 418 appears to be coeval and essentially coincident with basement formation. Alteration may be used to advantage in determining ages of old oceanic crust.

Geochemistry on Holocene sediments from the Mediterranean

The enhanced accumulation of organic matter in Eastern Mediterranean sapropels and their unusually low d15N values have been attributed to either enhanced nutrient availability which led to elevated primary production and carbon sequestration or to enhanced organic matter preservation under anoxic conditions. In order to evaluate these two hypothesis we have determined Ba/Al ratios, amino acid composition, N and organic C concentrations and d15N in sinking particles, surface sediments, eight spatially distributed core records of the youngest sapropel S1 (10-6 ka) and older sapropels (S5, S6) from two locations. These data suggest that (i) temporal and spatial variations in d15N of sedimentary N are driven by different degrees of diagenesis at different sites rather than by changes in N-sources or primary productivity and (ii) present day TOC export production would suffice to create a sapropel like S1 under conditions of deep-water anoxia. This implies that both enhanced TOC accumulation and d15N depletion in sapropels were due to the absence of oxygen in deep waters. Thus preservation plays a major role for the accumulation of organic-rich sediments casting doubt on the need of enhanced primary production for sapropel formation.

Rb-Sr isotope systematics and Sr/Ca-Ba/Ca ratios at DSDP Hole 89-462A

Four samples of Nauru Basin basalts (Cores 94 to 109 of Hole 462A, sub-bottom depth 1077-1209 m) have 87Sr/86Sr ratios in the range 0.7037 to 0.7038, which is distinctly higher than the ratios of N-type MORB. The Rb contents of the samples are depleted in comparison with those of MORB and ocean-island basalts. These chemical and isotopic characteristics are identical to those of the basalts previously drilled during Leg 61 (Cores 75 to 90 of Hole 462A), and are explained in terms of inhomogeneity of the source region in the mantle or later alteration effects. Sr/Ca-Ba/Ca systematics of 15 samples from Cores 462A-94 to 462A-109 and 14 samples from Cores 462A-75 to 462A-90 suggest that the Nauru Basin basalts are derived from a mantle peridotite by 20 to 30% partial melting with subsequent Plagioclase crystallization.

Auxiliary material and basic geochemical and benthic foraminiferal stable isotope data for the interval bracketing Eocene Thermal Maximum 2 (ETM2) at DSDP Sites 401 and 550 in the northeastern Atlantic Ocean

Ever since its discovery, Eocene Thermal Maximum 2 (ETM2; ~53.7 Ma) has been considered as one of the "little brothers" of the Paleocene-Eocene Thermal Maximum (PETM; ~56 Ma) as it displays similar characteristics including abrupt warming, ocean acidification, and biotic shifts. One of the remaining key questions is what effect these lesser climate perturbations had on ocean circulation and ventilation and, ultimately, biotic disruptions. Here we characterize ETM2 sections of the NE Atlantic (Deep Sea Drilling Project Sites 401 and 550) using multispecies benthic foraminiferal stable isotopes, grain size analysis, XRF core scanning, and carbonate content. The magnitude of the carbon isotope excursion (0.85-1.10 per mil) and bottom water warming (2-2.5°C) during ETM2 seems slightly smaller than in South Atlantic records. The comparison of the lateral d13C gradient between the North and South Atlantic reveals that a transient circulation switch took place during ETM2, a similar pattern as observed for the PETM. New grain size and published faunal data support this hypothesis by indicating a reduction in deepwater current velocity. Following ETM2, we record a distinct intensification of bottom water currents influencing Atlantic carbonate accumulation and biotic communities, while a dramatic and persistent clay reduction hints at a weakening of the regional hydrological cycle. Our findings highlight the similarities and differences between the PETM and ETM2. Moreover, the heterogeneity of hyperthermal expression emphasizes the need to specifically characterize each hyperthermal event and its background conditions to minimalize artifacts in global climate and carbonate burial models for the early Paleogene.

Calcium carbonate, sedimentation and mass accumulation rates at DSDP Site 85-572

At Site 572, located at 1°N, 114° W (3903 m water depth), we recovered a continuous hydraulic piston cored section of upper Miocene to upper Pleistocene pelagic sediments. The sediment is composed of biogenic carbonate and silica with nonbiogenic material as a minor component. Detailed analysis of the calcium carbonate content shows that the degree of variability in carbonate deposition apparently changed markedly between the late Miocene and Pliocene at this equatorial Pacific site. During this interval carbonate mass accumulation rates decreased from 2.6 to 0.8 g/cm**2 per 10**3 yr. If we assume that variations in CaCO3 content reflect changes in the degree of dissolution, then the detailed carbonate analysis would suggest that the degree of variability in carbonate deposition decreases by a factor of 5 as the dominant wavelength of variations increases significantly. However, if the variability in carbonate concentration is described in terms of changes in mean mass accumulation, calculations then suggest that relatively small changes in noncarbonate rates may be important in controlling the observed carbonate records. In addition, the analysis suggests that the degree of variability observed in pelagic carbonate data may in part reflect total accumulation rates. Intervals with high sedimentation rates show lower amplitude variations in concentration than intervals with lower sedimentation rates for the same degree of change in the carbonate accumulation rate.