Cartas enviadas por Aita Donostia (José Gonzalo Zulaika Arregi) a Justo Garate entre 1935 y 1953

5 cartas (manuscritas y mecanografiadas) ; 215x160mm. Ubicación: Caja 1 - Carpeta 12

Synthetic scope and DFT analysis of the chiral binap-gold(I) complex-catalyzed 1,3-dipolar cycloaddition of azlactones with alkenes

he 1,3-dipolar cycloaddition between glycine-derived azlactones with maleimides is efficiently catalyzed by the dimeric chiral complex [(S-a)-Binap.AuTFA](2). The alanine-derived oxazolone only reacts with tert-butyl acrylate giving anomalous regiochemistry, which is explained and supported by Natural Resonance Theory and Nucleus Independent Chemical Shifts calculations. The origin of the high enantiodiscrimination observed with maleimides and tert-butyl acrylate is analyzed using DFT computed at M06/Lanl2dz//ONIOM(b3lyp/Lanl2dz:UFF) level. Several applications of these cycloadducts in the synthesis of new proline derivatives with a 2,5-trans-arrangement and in the preparation of complex fused polycyclic molecules are described.

Diário da Constituinte [gravação de vídeo] : [programa n. 498]

Mauro Benevides; Ulysses Guimarães; Luiz Inácio Lula da Silva; Haroldo Lima; Bonifácio de Andrada; Sandra Cavalcanti; Siqueira Campos; Vivaldo Barbosa; Carlos Sant'anna; Roberto Freire; Arnaldo Faria de Sá; Marco Maciel; Plínio Arruda Sampaio; Mário Covas; Fernando Henrique Cardoso; Nelson Carneiro; Augusto Carvalho; Fernando Gasparian; Mansueto de Lavor

Ictiólogos de la Argentina: Francisco Juan José Risso Ceriani.

This series will include all those people who, by means of their contributions, great and small, played a part in the consolidation of ichthyology in Argentina. The general plan of this work consists of individual factsheets containing a list of works by each author, along with reference bibliography and, whenever possible, personal pictures and additional material. The datasheets will be published primarily in chronological order, although this is subject to change by the availability of materials for successive editions. This work represents another approach for the recovery and revalorization of those who set the foundations of Argentine ichthyology while in diverse historical circumstances. I expect this to be the beginning of a major work that achieves the description of such a significant part of the history of natural sciences in Argentina.

Chiral gold(I) vs chiral silver complexes as catalysts for the enantioselective synthesis of the second generation GSK-hepatitis C virus inhibitor

The synthesis of a GSK 2(nd) generation inhibitor of the hepatitis C virus, by enantioselective 1,3-dipolar cycloaddition between a leucine derived iminoester and tert-butyl acrylate, was studied. The comparison between silver(I) and gold(I) catalysts in this reaction was established by working with chiral phosphoramidites or with chiral BINAP. The best reaction conditions were used for the total synthesis of the hepatitis C virus inhibitor by a four step procedure affording this product in 99% ee and in 63% overall yield. The origin of the enantioselectivity of the chiral gold(I) catalyst was justified according to DFT calculations, the stabilizing coulombic interaction between the nitrogen atom of the thiazole moiety and one of the gold atoms being crucial.

Diário da Constituinte [gravação de vídeo] : [programa n. 411]

A Assembleia Nacional Constituinte começa hoje uma nova fase. Agora tudo o que for decidido e votado neste Plenário vai ter força de Lei. E força de Lei Maior, força de Constituição. Muita discussão e muitas horas sem dormir já foram gastas. Foram produzidos 66.197 documentos entre projetos e emendas. Foram enviadas 72.719 sugestões a Constituinte, de todas as partes do país. E mais de 10 milhões de brasileiros assinaram emendas populares. Mudanças importantes já foram discutidas e aprovadas nas etapas anteriores. A Constituição que começa a ser votada é a 7ª Carta que o Brasil tem. Há 164 anos o país começou a ser juridicamente organizado. Surgia a 1ª Constituição do Brasil, a Constituição do Império. A mudança surgiu com a Proclamação da República. A nova Carta foi votada em 1891. Serviu à Velha República e sofreu mudanças em 1934 e depois em 1937, com o Estado Novo. A redemocratização surgiu em 1946, durou até 1967, quando foi alterada depois da Revolução Militar, de março de 1964. A nova Carta começa a ser votada, com o compromisso dos constituintes de executá-la no tempo justo.

The Economics of "Why is it so hard to save a threatened Language?"

We study the language choice behavior of bilingual speakers in modern societies, such as the Basque Country, Ireland andWales. These countries have two o cial languages:A, spoken by all, and B, spoken by a minority. We think of the bilinguals in those societies as a population playing repeatedly a Bayesian game in which, they must choose strategically the language, A or B, that might be used in the interaction. The choice has to be made under imperfect information about the linguistic type of the interlocutors. We take the Nash equilibrium of the language use game as a model for real life language choice behavior. It is shown that the predictions made with this model t very well the data about the actual use, contained in the censuses, of Basque, Irish and Welsh languages. Then the question posed by Fishman (2001),which appears in the title, is answered as follows: it is hard, mainly, because bilingual speakers have reached an equilibrium which is evolutionary stable. This means that to solve fast and in a re ex manner their frequent language coordination problem, bilinguals have developed linguistic conventions based chie y on the strategy 'Use the same language as your interlocutor', which weakens the actual use of B.1

Design and synthesis of quasi-diastereomeric molecules with unchanging central, regenerating axial and switchable helical chirality via cleavage and formation of Ni(II)–O and Ni(II)–N coordination bonds

9 p.

Cartas enviadas por Ramón María de Aldasoro a Justo Garate en 1940

8 cartas (mecanografiadas) ; 225x285 mmm. Ubicación: Caja 1 - Carpeta 20

Cartas enviadas por Ramón Ansoain Garraza a Justo Garate entre 1982 y 1983

1 tarjeta, 1 felicitación de Navidad, 1 carta, 1 tarjeta de vistita (manuscritas y mecanografiadas) ; entre 231x165mm y 10x60mm. Ubicación: Caja 1 - Carpeta 30

Cartas enviadas por José Antonio Arana Martija a Justo Garate entre 1985 y 1993

9 cartas (mecanografiadas) ; 207x300mm. Ubicación: Caja 1 - Carpeta 36

Carta enviada por José Ignacio de Arana a Justo Garate en 1940

1 carta (manuscrita) ; 270x180mm. Ubicación: Caja 1 - Carpeta 37

Carta enviada por José de Ariztimuño a Justo Garate en 1933

1 carta (mecanografiada) ; 215x135mm. Ubicación: Caja 1 - Carpeta 51

Carta enviada por José de Arriga a Justo Garate en 1947

1 carta (mecanografiada) ; 340x165mm. Ubicación: Caja 1 - Carpeta 61