Diatom abundance and paleo-temperature reconstruction for sediment cores from the southeast Norwegian Sea

Although the pulsating nature and the abruptness of the last deglaciation are well documented in marine and land records, very few marine records have so far been able to capture the high-frequency climatic changes recorded in the Greenland ice core Dye 3. We studied high-resolution sediment cores from SE Norwegian Sea, which display a detailed climatic record during the last deglaciation comparable to that of Dye 3. Accelerator mass spectrometry age control of the cores enables us to correlate this record in detail with continental records. The results indicate that the surface waters of the SE Norwegian Sea were seasonally ice free after 13,400 B.P. The Bølling/Allerød interstadial complex (13,200-11,200 B.P.) was a climatically unstable period with changing Arctic-Subarctic conditions. This period was punctuated by four progressively more severe sea surface temperature (SST) minima: between 12,900-12,800 B.P. (BCP I); 12,500-12,400 B.P. (BCP II); 12,300-12,000 B.P. (OD I); and 11,800-11,500 B.P. (OD II). The Younger Dryas (YD) (11,200-10,200 B.P.) represents the severest and most prolonged cold episode of this series of climatic deteriorations. It was bounded by very rapid SST changes and characterized by Arctic-Polar conditions. The first true warm Atlantic water incursion to the SE Norwegian Sea took place around 10,100 B.P., followed by a brief cooler condition between 9900-9600 B.P. (YD II). The early Holocene climatic optimum occurred between 8000-5000 B.P. A conceptual model is proposed where meltwater fluxes are suggested to cause the observed instability in the SST record.

Mineralogy of sediment cores from the continental slope of Chile

Marine sediment cores from the continental slope off mid-latitude Chile (33°S) were studied with regard to grain-size distributions and clay mineral composition. The data provide a 28,000-yr14C accelerator mass spectrometry-dated record of variations in the terrigenous sediment supply reflecting modifications of weathering conditions and sediment source areas in the continental hinterland. These variations can be interpreted in terms of the paleoclimatic evolution of mid-latitude Chile and are compared to existing terrestrial records. Glacial climates (28,000-18,000 cal yr B.P.) were generally cold-humid with a cold-semiarid interval between 26,000 and 22,000 cal yr B.P. The deglaciation was characterized by a trend toward more arid conditions. During the middle Holocene (8000-4000 cal yr B.P.), comparatively stable climatic conditions prevailed with increased aridity in the Coastal Range. The late Holocene (4000-0 cal yr B.P.) was marked by more variable paleoclimates with generally more humid conditions. Variations of rainfall in mid-latitude Chile are most likely controlled by shifts of the latitudinal position of the Southern Westerlies. Compared to the Holocene, the southern westerly wind belt was located significantly farther north during the last glacial maximum. Less important variations of the latitudinal position of the Southern Westerlies also occurred on shorter time scales.

X-ray fluorescence (XRF) Ca intensity of sediment cores MD04-2760 and MD04-2788

Accelerator mass spectrometry (AMS) radiocarbon dating of ostracod and gastropod shells from the southwestern Black Sea cores combined with tephrochronology provides the basis for studying reservoir age changes in the lateglacial Black Sea. The comparison of our data with records from the northwestern Black Sea shows that an apparent reservoir age of ~1450 14C yr found in the glacial is characteristic of a homogenized water column. This apparent reservoir age is most likely due to the hardwater effect. Though data indicate that a reservoir age of ~1450 14C yr may have persisted until the Bølling-Allerød warm period, a comparison with the GISP2 ice-core record suggests a gradual reduction of the reservoir age to ~1000 14C yr, which might have been caused by dilution effects of inflowing meltwater. During the Bølling-Allerød warm period, soil development and increased vegetation cover in the catchment area of the Black Sea could have hampered erosion of carbonate bedrock, and hence diminished contamination by "old" carbon brought to the Black Sea basin by rivers. A further reduction of the reservoir age most probably occurred contemporary to the precipitation of inorganic carbonates triggered by increased phytoplankton activity, and was confined to the upper water column. Intensified deep water formation subsequently enhanced the mixing/convection and renewal of intermediate water. During the Younger Dryas, the age of the upper water column was close to 0 yr, while the intermediate water was ~900 14C yr older. The first inflow of saline Mediterranean water, at ~8300 14C yr BP, shifted the surface water age towards the recent value of ~400 14C yr.

Age determination of sediment cores from the Weddell Sea

We report here the results of a study aimed at providing radiometric age control on glacial events in the Weddell Sea during the late Quaternary. Sediment cores from the eastern continental shelf, where the East Antarctic ice sheet was grounded, have recovered glacial-marine sediments resting on tills and the latter deposits predate the isotope stage 2 last glacial maximum. Sediment cores from the continental slope and rise sampled a prominent ice-rafted debris layer, and radiocarbon ages indicate that this ice-rafting event took place prior to 26 000 yr B.P. Thus, the combined data indicate that significant deglaciation of the Weddell Sea continental shelf took place prior to the last glacial maximum. Our data also suggest that the ice masses that border the Weddell Sea are more extensive than they were during the previous glacial minimum.

Age determination of sediment cores from the northern Mid-Atlantic Ridge

We construct age models for a suite of cores from the northeast Atlantic Ocean by means of accelerator mass spectrometer dating of a key core, BOFS 5K, and correlation with the rest of the suite. The effects of bioturbation and foraminiferal species abundance gradients upon the age record are modeled using a simple equation. The degree of bioturbation is estimated by comparing modeled profiles with dispersal of the Vedde Ash layer in core 5K, and we find a mixing depth of roughly 8 cm for sand-sized material. Using this value, we estimate that age offsets between unbioturbated sediment and some foraminifera species after mixing may be up to 2500 years, with lesser effect on fine carbonate (< 10 µm) ages. The bioturbation model illustrates problems associated with the dating of 'instantaneous' events such as ash layers and the 'Heinrich' peaks of ice-rafted detritus. Correlations between core 5K and the other cores from the BOFS suite are made on the basis of similarities in the downcore profiles of oxygen and carbon isotopes, magnetic susceptibility, water and carbonate content, and via marker horizons in X radiographs and ash beds.

Mg/Ca-temperature proxy in benthic foraminifera from the Florida Strait

Over the past decade, the ratio of Mg to Ca in foraminiferal tests has emerged as a valuable paleotemperature proxy. However, large uncertainties remain in the relationships between benthic foraminiferal Mg/Ca and temperature. Mg/Ca was measured in benthic foraminifera from 31 high-quality multicore tops collected in the Florida Straits, spanning a temperature range of 5.8° to 18.6°C. New calibrations are presented for Uvigerina peregrina, Planulina ariminensis, Planulina foveolata, and Hoeglundina elegans. The Mg/Ca values and temperature sensitivities vary among species, but all species exhibit a positive correlation that decreases in slope at higher temperatures. The decrease in the sensitivity of Mg/Ca to temperature may potentially be explained by Mg/Ca suppression at high carbonate ion concentrations. It is suggested that a carbonate ion influence on Mg/Ca may be adjusted for by dividing Mg/Ca by Li/Ca. The Mg/Li ratio displays stronger correlations to temperature, with up to 90% of variance explained, than Mg/Ca alone. These new calibrations are tested on several Last Glacial Maximum (LGM) samples from the Florida Straits. LGM temperatures reconstructed from Mg/Ca and Mg/Li are generally more scattered than core top measurements and may be contaminated by high-Mg overgrowths. The potential for Mg/Ca and Mg/Li as temperature proxies warrants further testing.

Paleomagnetic and radiocarbon-based chronologies of sediment cores MD99-2269 and MD99-2322

We report the intercalibration of paleomagnetic secular variation (PSV) and radiocarbon dates of two expanded postglacial sediment cores from geographically proximal, but oceanographically and sedimentologically contrasting settings. The objective is to improve relative correlation and chronology over what can be achieved with either method alone. Core MD99-2269 was taken from the Húnaflóaáll Trough on the north Iceland shelf. Core MD99-2322 was collected from the Kangerlussuaq Trough on the east Greenland margin. Both cores are well dated, with 27 and 20 accelerator mass spectrometry 14C dates for cores 2269 and 2322, respectively. Paleomagnetic measurements made on u channel samples document a strong, stable, single-component magnetization. The temporal similarities of paleomagnetic inclination and declination records are shown using each core's independent calibrated radiocarbon age model. Comparison of the PSV records reveals that the relative correlation between the two cores could be further improved. Starting in the depth domain, tie points initially based on calibrated 14C dates are either adjusted or added to maximize PSV correlations. Radiocarbon dates from both cores are then combined on a common depth scale resulting from the PSV correlation. Support for the correlation comes from the consistent interweaving of dates, correct alignment of the Saksunarvatn tephra, and the improved correlation of paleoceanographic proxy data (percent carbonate). These results demonstrate that PSV correlation used in conjunction with 14C dates can improve relative correlation and also regional chronologies by allowing dates from various stratigraphic sequences to be combined into a single, higher dating density, age-to-depth model.

Stable isotope record of planktonic foraminifera from the Sulu Sea

A high-resolution, accelerator mass spectroscopy 14C dated sediment record from the Sulu Sea clearly indicates that the Younger Dryas event affected the western equatorial Pacific. Planktonic foraminiferal delta18O and abundance data both record significant changes during Younger Dryas time. In particular, a 0.4 per mil increase in the delta18O value of Globigerinoides ruber and the reappearance of the cool water planktonic foraminifera, Neogloboquadrina pachyderma, occur during the Younger Dryas at this location. These isotopic and faunal changes are a response to either surface water temperature or salinity changes, or some combination of the two. Changes in surface salinities could have been accomplished through either local or global processes. Intensification of the monsoon climate system and increased precipitation at approximately 11 ka is one mechanism that may have resulted in local changes in salinity. A meltwater pulse derived from the Tibetan Plateau is another mechanism which may have caused local changes in salinity. The presence of the Younger Dryas in the tropical western Pacific clearly indicates that this climatic event is not restricted to the North Atlantic or high latitudes, but rather is global in extent.

Occurence and thickness of flood layers in varved sediments of Lake Ammersee

Microfacies analyses and X-ray fluorescence scanning (µ-XRF) at sub-mm resolution were conducted on the varved Mid- to Late Holocene interval of two sediment profiles from pre-alpine Lake Ammersee (southern Germany). The coring sites are located in a proximal (AS10prox) and distal (AS10dist) position towards the main tributary River Ammer, in 1.8 km distance from each other. To shed light on sediment distribution within the lake, particular emphasis was (1) the detection of intercalated detrital layers and their micro-sedimentological features, and (2) intra-basin correlation of these event deposits. Detrital layers were dated by microscopic varve counting, verified by accelerator mass spectrometry 14C dating of terrestrial plant macrofossils. Since ~5500 varve years (vyr) BP, in total 1573 detrital layers were detected in either one or both of the investigated sediment profiles. Based on their microfacies, geochemistry, and proximal-distal deposition pattern, detrital layers were interpreted as River Ammer flood deposits. Earlier studies on flood layer seasonality have proven that flood layer deposition occurs predominantly during spring and summer, the flood season at Lake Ammersee. Most prominent features of the record are the onset of regular flood layer deposition at ~5500 vyr BP in AS10prox and ~ 2800 vyr BP in AS10dist as well as three major increases in mean flood layer thickness at ~5500, 2800, and 400 vyr BP. Integrating information from both sediment profiles allowed to interpret these changes in terms of shifts towards higher mean flood intensity. Proposed triggering mechanisms are gradual reduction in Northern Hemisphere orbital summer forcing and superimposed centennial-scale solar activity minima. Likely responses to this forcing are enhanced equator-to-pole temperature gradients and changes in synoptic-scale atmospheric circulation. The consequences for the Ammersee region are more intense cyclones leading to extremer rainfall and flood events in spring and summer.

Age determination and sea surface temperature reconstruction for the Southern Ocean

The isotopic and micropaleontological deglacial records of three deep-sea cores from 44°S to 55°S have been dated by accelerator mass spectrometry. The available records did not allow accurate dating of the initiation of the deglaciation. By 13,000 years B.P., sea surface temperatures reached values similar to the present values. A cool oscillation abruptly interrupted this warm phase between 12,000 and 11,000 years B.P. Initiation of this cooling therefore preceded the northern hemisphere Younger Dryas by approximately 1000 years. Complete warming was reached by 10,000 years B.P., more or less synchronous with the northeast Atlantic Ocean.

Beryllium ages, sedimentology and weathering characteristics of Reedy Glacier deposits

Deposits corresponding to multiple periods of glaciation are preserved in ice-free areas adjacent to Reedy Glacier, southern Transantarctic Mountains. Glacial geologic mapping, supported by 10Be surface-exposure dating, shows that Reedy Glacier was significantly thicker than today multiple times during the mid-to-late Cenozoic. Longitudinal-surface profiles reconstructed from the upper limits of deposits indicate greater thickening at the glacier mouth than at the head during these episodes, indicating that Reedy Glacier responded primarily to changes in the thickness of the West Antarctic Ice Sheet. Surface-exposure ages suggest this relationship has been in place since at least 5 Ma. The last period of thickening of Reedy Glacier occurred during Marine Isotope Stage 2, at which time the glacier surface near its confluence with the West Antarctic Ice Sheet was at least 500 m higher than today.

Halogene concentrations and iodine isotopic composition in pore water on Hydrare Ridge, Cascadia continental margin

We report iodine and bromine concentrations in a total of 256 pore water samples collected from all nine sites of Ocean Drilling Program Leg 204, Hydrate Ridge. In a subset of these samples, we also determined iodine ages in the fluids using the cosmogenic isotope 129I (T1/2 = 15.7 Ma). The presence of this cosmogenic isotope, combined with the strong association of iodine with methane, allows the identification of the organic source material responsible for iodine and methane in gas hydrates. In all cores, iodine concentrations were found to increase strongly with depth from values close to that of seawater (0.0004 mM) to concentrations >0.5 mM. Several of the cores taken from the northwest flank of the southern summit show a pronounced maximum in iodine concentrations at depths between 100 and 150 meters below seafloor in the layer just above the bottom-simulating reflector. This maximum is especially visible at Site 1245, where concentrations reach values as high as 2.3 mM, but maxima are absent in the cores taken from the slope basin sites (Sites 1251 and 1252). Bromine concentrations follow similar trends, but enrichment factors for Br are only 4-8 times that of seawater (i.e., considerably lower than those for iodine). Iodine concentrations are sufficient to allow isotope determinations by accelerator mass spectrometry in individual pore water samples collected onboard (~5 mL). We report 129I/I ratios in a few samples from each core and a more complete profile for one flank site (Site 1245). All 129I/I ratios are below the marine input ratio (Ri = 1500x10**-15). The lowest values found at most sites are between 150 and 250x10**-15, which correspond to minimum ages between 40 and 55 Ma, respectively. These ages rule out derivation of most of the iodine (and, by association, of methane) from the sediments hosting the gas hydrates or from currently subducting sediments. The iodine maximum at Site 1245 is accompanied by an increase in 129I/I ratios, suggesting the presence of an additional source with an age younger than 10 Ma; there is indication that younger sources also contribute at other sites, but data coverage is not yet sufficient to allow a definitive identification of sources there. Likely sources for the older component are formations of early Eocene age close to the backstop in the overriding wedge, whereas the younger sources might be found in recent sediments underlying the current locations of the gas hydrates.