2.1GeV Kr离子在聚碳酸酯膜中引起的辐照效应研究

用傅立叶变换红外光 (FTIR)谱仪和紫外 /可见光 (UV/VIS)谱仪研究了2 1GeVKr离子在聚碳酸酯 (PC)膜中产生的效应 .研究结果表明 ,在高能Kr离子辐照下 ,PC膜中发生了断键、断链和键的重组 ,炔基的出现是键的断裂和重组的结果 .这些效应与辐照剂量和电子能损有关 .辐照也使PC膜中发生了从氢化非晶态碳向非晶态碳的转变 ,在UV/VIS中 ,波长为 3 80 ,4 50和 50 0nm处的相对吸光度随能量沉积密度的增加近似按线性变化

Void swelling in MA956 ODS steel irradiated with 122 MeV Ne-ions at elevated temperatures

An investigation of a commercial oxide dispersion-strengthened steel (MA9561) irradiated with high energy Ne-ions to high doses at elevated temperatures is presented. Specimens of MA956 oxide dispersion strengthened steel together with a 9% Cr ferritic/martensitic steel, e.g., Grade 92 steel were irradiated simultaneously with 20Ne-ions (with 122 MeV) to successively increasing damage levels of 1, 5 and 10 dpa at the damage peak at 440 C and 570 C, respectively. Cross-sectional microstructures of the specimens were investigated with transmission electron microscopy. MA956 oxide dispersion strengthened steel showed a higher resistance to void swelling especially to void growth at the grain boundaries than the ferritic/martensitic steel, e.g., Grade 92 steel did, and thus exhibited a prominence for an application in the situation of a high He production at high temperatures. The suppression of the growth of voids especially at the grain boundaries in MA956 is ascribed to an enhanced recombination of the point defects and a trapping of Ne atoms at the interfaces of the yttrium–aluminum oxide particles and the matrix.

Void swelling in a 9Cr ferritic/martensitic steel irradiated with energetic Ne-ions at elevated temperatures

In this work the void swelling behavior of a 9Cr ferritic/martensitic steel irradiated with energetic Ne-ions is studied. Specimens of Grade 92 steel (a 9%Cr ferritic/martensitic steel) were subjected to an irradiation of Ne-20-ions (with 122 MeV) to successively increasing damage levels of 1, 5 and 10 dpa at a damage peak at 440 and 570 degrees C, respectively. And another specimen was irradiated at a temperature ramp condition (high flux condition) with the temperature increasing from 440 up to 630 degrees C during the irradiation. Cross-sectional microstructures were investigated with a transmission electron microscopy (TEM). A high concentration of cavities was observed in the peak damage region in the Grade 92 steel irradiated to 5 dpa, and higher doses. The concentration and mean size of the cavities showed a strong dependence on the dose and irradiation temperature. Enhanced growth of the cavities at the grain boundaries, especially at the grain boundary junctions, was observed. The void swelling behavior in similar 9Cr steels irradiated at different conditions are discussed by using a classic void formation theory. (c) 2008 Elsevier B.V. All rights reserved.

Transfer ionization of helium in collisions with Cq+ and Oq+ (q=1-3)

Cross-section ratios sigma(TI)/sigma(SC) of transfer ionization (TI) to single capture (SC) of Cq+- and Oq+-He (q = 1 - 3) collisions in the energy range of 15-440 keV/u (0.8-4.2 v(Bohr)) are experimentally determined. It is shown that sigma(TI)/sigma(SC) strongly depends on the projectile velocity, and there is a maximum for E(keV/u)/q(1/2) approximate to 150. Combining the Bohr-Lindhard model and the statistical model, a theoretical estimate is presented, in reasonable agreement with the experimental data when E(keV/u)/q(1/2) > 35.

初步的IMP重离子治疗计划系统；A Preliminary Version of Heavy Ion Treatment Planning System at IMP

中国科学院近代物理研究所基于兰州重离子研究装置(HIRFL/HIRFL-CSR),在被动型束流配送系统下采用二维分层适形照射治疗技术开展重离子治癌临床试验研究。为了更好地利用重离子束在肿瘤放射治疗中的生物物理优势并保障重离子临床治疗试验的顺利实施,一个初级版本的重离子治疗计划系统已经设计完成。此计划系统是针对被动型束流配送系统下的二维分层适形照射治疗方式来进行设计的。介绍了此系统的设计框架、可提供的功能以及利用宽束算法进行剂量计算在此系统中的实现。通过人体仿真体模实验证实由该治疗计划系统给出的靶区计划剂量与实测剂量的偏差在5%之内。最后讨论了设计较为完备的重离子治疗计划系统仍需解决的问题。

Quantitative analysis analysis of element concentration in Al alloy by using laser-induced breakdown spectroscopy

Laser-induced breakdown plasma is produced by using Q-switched Nd: YAG laser operating at 532 nm, which interacts with the Al alloy sample target in air. The spectral lines in the 230-440 nm wavelength range have been identified, and based on the calibration-free method, the mass concentration of Al alloy are obtained, which is in good agreement with the standard value of the sample.

长期施肥对黑土中Cu、Cd含量及其剖面分布的影响

以经过8个不同施肥处理的黑土样品为材料,研究长期不同施肥处理下,黑土中Cu、Cd含量的差异。采用原子吸收分光光度法和Tessier-连续提取法,研究黑土中全Cu、全Cd和有效Cu、有效Cd的含量差异。结果表明,有机肥的长期施用,会使土壤中Cu、Cd与有机质发生络合并使Cu、Cd在土壤表层累积;秸秆和氮磷钾(S+NPK)化肥的长期配合施用,有利于作物对有效Cu和Cd的吸收,从而使Cu、Cd在土壤中没有明显积累;NP及NPK处理下,二铵、氯化钾肥对土壤中Cu、Cd积累的影响不明显。长期耕作不施肥(CK)处理时,因无外源Cu、Cd,以及作物对有效Cu、Cd的长期吸收,土壤中Cu、Cd含量低于不耕作不施肥(休闲)处理的。从垂直剖面上看,Cu、Cd主要积累在黑土表层,而表层以下不同施肥处理间Cu、Cd含量的差异和变幅不大。有机肥料能明显地向土壤中带入Cu、Cd,造成Cu、Cd在土壤表层的积累,并由于植物体的吸收对人体造成潜在危害,而其他化学肥料对土壤中Cu和Cd积累的影响不明显。本研究为人们的生产实践提供了施肥理论和依据,并且对土壤的污染防治也具有现实意义。

Development of a precolumn derivatization method for the determination of free amines in wastewater by high-performance liquid chromatography via fluorescent detection with 9-(2-hydroxyethyl)acridone

A simple, sensitive, and mild method for the determination of amino compounds based on a condensation reaction with fluorescence detection has been developed. 9-(2-Hydroxyethyl)acridone reacts with coupling agent N,N-carbonyldiimidazole at ambient temperature to form activated amide intermediate 9-(2-acridone)oxyethylcarbonylimidazole (AOCD). The amide intermediate (AOCD) preferably reacts with amino compounds under mild reactions in the presence of 4-(dimethylamino)pyridine (base catalyst) in acetonitrile to give the corresponding sensitively fluorescent derivatives with an excitation maximum lambda(ex) 404 mn and an emission maximum at lambda(em) 440 nm. The labeled derivatives exhibit high stability under reversed-phase conditions. The fluorescence intensities of derivatives in various solvents or at different temperatures were investigated. The method, in conjunction with a gradient elution, offers a baseline resolution of the common amine derivatives on a reversed-phase C-18 column. The LC separation for the derivatized amines shows good reproducibility with acetonitrile-water including 2.5% DMF as mobile phase. The relative standard deviations (n = 6) for each amine derivative are <4.5%. The detection limits (at a signal-to-noise ratio of 3) per injection were 0.16-12.8 ng/mL. Further research for the field of application, based on the AOCD amide intermediate as derivatization reagent, for the determination of free amines in real water samples is achieved.

Genomic organization, nucleotide sequence analysis of the core histone genes cluster in Chlamys farreri and molecular evolution assessment of the H2A and H2B

This work represents the nucleotide sequence of the core histone gene cluster from scallop Chlamys farreri. The tandemly repeated unit of 5671 bp containing a copy of the four core histone genes H4, H2B, H2A and H3 was amplified and identified by the techniques of homology cloning and genomic DNA walking. All the histone genes in the cluster had the structures in their 3' flanking region which related to the evolution of histone gene expression patterns throughout the cell cycle, including two different termination signals, the hairpin structure and at least one AATAAA polyadenylation signal. In their 5' region, the transcription initiation sites with a conserved sequence of 5'-PyATTCPu-3' known as the CAP site were present in all genes except to H2B, generally 37-45 bp upstream of the start code. Canonical TATA and CAAT boxes were identified only in certain histone genes. In the case of the promoters of H2B and H2A genes, there was a 5'-GATCC-3' element, which had been found to be essential to start transcription at the appropriate site. After this element, in the promoter of H2B, there was another sequence, 5'-GGATCGAAACGTTC-3', which was similar to the consensus sequence of 5'-GGAATAAACGTATTC-3' corresponding to the H2B-specific promoter element. The presence of enhancer sequences (5'-TGATATATG-3') was identified from the H4 and H3 genes, matching perfectly with the consensus sequence defined for histone genes. There were several slightly more complex repetitive DNA in the intergene regions. The presence of the series of conserved sequences and reiterated sequences was consistent with the view that mollusc histone gene cluster arose by duplicating of an ancestral precursor histone gene, the birth-and-death evolution model with strong purifying selection enabled the histone cluster less variation and more conserved function. Meanwhile, the H2A and the H2B were demonstrated to be potential good marks for phylogenetic analysis. All the results will be contributed to the characterization of repeating histone gene families in molluscs.

黄土塬区三种豆科牧草的竞争生长

通过田间试验研究了沙打旺、紫花苜蓿和达乌里胡枝子3种豆科牧草在黄土旱塬以不同密度单播、混播时的竞争生长能力及水分利用效率。单播时苜蓿生长次年3个密度的生产力分别为15349kg·hm-2、20582kg·hm-2、21531kg·hm-2,沙打旺和胡枝子3个密度的生产力分别为7979kg·hm-2、16 440 kg·hm-2、21055kg·hm-2和2412kg·hm-2、5270kg·hm-2、7102kg·hm-2。混播草地生产力以苜蓿+胡枝子最高(平均19227kg·hm-2),沙打旺与胡枝子混播的生产力最低(平均11977kg·hm-2)。和生产力较高的参混种苜蓿、沙打旺单播相比,苜蓿与沙打旺混播及沙打旺与胡枝子混播的生产力在3种密度下均有不同程度的降低。苜蓿主根下扎深度2m,0~60cm根系占总根量的66%,沙打旺和胡枝子根系最大下扎深度分别为1.8 m和1.5m,0~60cm根系占总根量比例分别是80%、91%。3种牧草中苜蓿的平均水分利用效率最高,为25.75kg·mm-1·hm-2,胡枝子最低为7.71kg·mm-1·hm-2,沙打旺居中。苜蓿群体种内个体间竞争强度高于沙打旺和胡枝子。结果...

景观植被生态系统水平衡模拟与分析

景观或区域的水平衡状况是全球变化的重要指标。本研究建立了一个空间显式景观过程模型,模拟了长白山自然保护区的水循环过程,并对水分收入、支出和平衡的总体状况、季节动态和空间分布格局进行了分析。整个保护区单位面积上水分盈余0.225±0.255m.a-1,总计盈余4.379×108m3.a-1,但空间变异相当大。阔叶红松林的水分有略微亏缺,其他类型植被生态系统每年均有不同程度的水分盈余。从总面积上看,云冷杉林每年的水分盈余最多(可达1.696×108m3.a-1),占整个保护区的40.56%。整个保护区6月水分