Pub/Sub系统中分布式复合事件检测技术研究

随着信息技术的发展，Pub/Sub系统由于具有异步和松耦合的特点，被越来越广泛的应用到金融、供应链管理、物流等领域。在这些应用中，用户对具有各种特定逻辑或时序关系的复合事件的订阅需求越来越迫切，这使得Pub/Sub系统中的分布式复合事件检测技术成为研究的热点，分布式复合事件检测技术包括复合订阅语言、复合匹配算法、以及订阅和事件的路由算法。 目前已有的Pub/Sub系统提供的复合订阅语言比较简单，对时序支持较弱，不能满足实际应用的需要，已有的复合匹配算法也不能有效的支持具有丰富时序关系的复合事件的检测。在路由方面，基于内容的Pub/Sub系统大都是在树结构或者无环图结构的覆盖网络上，采用基于过滤的原子路由方法，该路由方法需要将原子订阅传遍几乎整个网络，以减少订阅匹配的延迟，但这种路由方法很难适应网络的拓扑变化。而目前基于事件空间划分的路由方法不支持事件空间的动态划分和事件空间在不同服务器之间的移动，并且没有提供专门针对事件空间划分的复合事件检测方法。 本文在调研了各种应用需求的基础上，提出了能够表达事件丰富的时序关系、逻辑关系和事件实例关系的复合订阅语言，并且定义了两种事件排序方式。在消费语义采用配对模式的情况下，给出了该语言在两种事件排序方式下的检测结果集的定义。针对该复合订阅语言提出并实现了图结构和时间事件发生器相结合的复合匹配算法，该匹配算法使图结构可以有效的支持时序关系和非触发式事件的检测。在路由方面，首先实现了基于过滤的逆向路径转发的原子路由方法，并在此基础上，实现了就近检测协议，该协议优化了复合订阅匹配结构在网络中的部署。最后，设计和实现了基于事件空间划分的原子路由方法，该路由方法实现了事件空间的动态划分，并可以根据系统中服务器的负载情况实现事件空间的移动，从而有效的平衡服务器的负载。在此基础上，通过对复合订阅的拆分，并利用可移动的复合事件检测器实现了复合订阅的分布式部署和复合事件的分布式检测，同时通过对复合事件检测器的复用，进一步减少了网络负载和服务器的匹配负载。本文还通过实验验证了匹配算法和两种路由方法的性能和开销。

Isolated sub-30-as pulse generation of an He+ ion by an intense few-cycle chirped laser and its high-order harmonic pulses

We present an efficient method to generate a ultrashort attosecond (as) pulse when a model He+ ion is exposed to the combination of an intense few-cycle chirped laser pulse and its 27th harmonics. By solving the time-dependent Schroumldinger equation, we found that high-order harmonic generation (HHG) from He+ ion is enhanced by seven orders of magnitude due to the presence of the harmonic pulse. After optimizing the chirp of the fundamental pulse, we show that the cut-off energy of the generated harmonics is extended effectively to I-p+25.5U(p). As a result, an isolated 26-as pulse with a bandwidth of 170.5 eV can be obtained directly from the supercontinuum around the cut-off of HHG. To better understand the physical origin of HHG enhancement and attosecond pulse emission, we perform semiclassical simulations and analyze the time-frequency characteristics of attosecond pulse.

Large-scale, rapid synthesis and application in surface-enhanced Raman spectroscopy of sub-micrometer polyhedral gold nanocrystals

Macromolecule-protected sub-micrometer polyhedral gold nanocrystals have been facilely prepared by heating an aqueous solution containing poly (N-vinyl-2-pyrrolidone) (PVP) and HAuCl4 without adding other reducing agents. Scanning electron microscopy (SEM), energy-dispersive x-ray spectroscopy (EDX), ultraviolet-visible-near-infrared spectroscopy (UV-vis-NIR), and x-ray diffraction (XRD) were employed to characterize the obtained polyhedral gold nanocrystals. It is found that the 10:1 molar ratio of PVP to gold is a key factor for obtaining quasi-monodisperse polyhedral gold nanocrystals. Furthermore, the application of polyhedral gold nanocrystals in surface-enhanced Raman scattering (SERS) was investigated by using 4-aminothiophenol (4-ATP) as a probe molecule. The results indicated that the sub-micrometer polyhedral gold nanocrystals modified on the ITO substrate exhibited higher SERS activity compared to the traditional gold nanoparticle modified film. The enhancement factor (EF) on polyhedral gold nanocrystals was about six times larger than that obtained on aggregated gold nanoparticles (similar to 25 nm).

Deformation mechanism of polystyrene toughened with sub-micrometer monodisperse rubber particles

Core-shell polybutadiene-graft-polystyrene (PB-g-PS) rubber particles with different ratios of polybutadiene to polystyrene were prepared by emulsion polymerization through grafting styrene onto polybutadiene latex. The weight ratio of polybutadiene to polystyrene ranged from 50/50 to 90/10. These core-shell rubber particles were then blended with polystyrene to prepare PS/PB-g-PS blends with a constant rubber content of 20 wt%. PB-g-PS particles with a lower PB/PS ratio (<= 570/30) form a homogeneous dispersion in the polystyrene matrix, and the Izod notched impact strength of these blends is higher than that of commercial high-impact polystyrene (HIPS). It is generally accepted that polystyrene can only be toughened effectively by 1-3 mu m rubber particles through a toughening mechanism of multiple crazings. However, the experimental results show that polystyrene can actually be toughened by monodisperse sub-micrometer rubber particles. Scanning electron micrographs of the fracture surface and stress-whitening zone of blends with a PB/PS ratio of 70/30 in PB-g-PS copolymer reveal a novel toughening mechanism of modified polystyrene, which may be shear yielding of the matrix, promoted by cavitation.

Carbon ceramic electrodes modified with sub-micron particles of new methylene blue (NMB) intercalated alpha-zirconium phosphate

New methylene blue-intercalated a-zirconium phosphate (NMBZrP) was synthesized in the presence of n-butylamine and characterized by powder XRD, FTIR, TEM and elemental analysis. Sub-micron particles of NMBZrP in deionized water were apt to deposit onto the surface of graphite powder to yield graphite powder-supported NMBZrP, which was subsequently dispersed into methyltrimethoxysilane-derived gels to fabricate surface-renewable, stable, rigid carbon ceramic electrodes containing new methylene blue. Cyclic voltammetric studies revealed that peak currents of the NMBZrP-modified electrode were surface-confined at low scan rates but diffusion-controlled. at high scan rates. In addition, NMBZrP immobilized in a carbon ceramic matrix presented a two-electron, three-proton redox process in acidic aqueous solution in the pH range from 0.52 to 3.95.

Molecular dynamics simulation of sub-transition for polyethersulfone

Molecular dynamics (MD) simulations of a polyethersulfone (PES) chain are carried out in the amorphous state by using the Dreiding 2.21 force field at four temperatures. Two types of molecular motion, i.e, rotations of phenylene rings and torsions of large segments containing two oxygen atoms, two sulfur atoms, and five phenylene rings on the backbone, are simulated. The modeling results show that the successive phenylene rings should be in-phase cooperative rotations, whereas the successive large segments should be out-of-phase cooperative torsions. By calculating the diffusion coefficient for the phenylene ring rotations, it is found that this rotation contributes to the beta -transition of PES.