Water temperature reconstruction for Terminations I and II of sediment core MD01-2378

We present centennial records of sea surface and upper thermocline temperatures in Core MD01-2378 from the Timor Sea, which provide new insights into the variability of the Indonesian outflow across the last two glacial terminations. Mg/Ca in Globigerinoides ruber (white s. s.) indicates an overall increase of 3.2 °C in sea surface temperature (SST) over Termination I. Following an early Holocene plateau at 11.3-6.4 ka, SSTs cooled by 0.6 °C during the middle to late Holocene (6.4-0.7 ka). The early Holocene warming occurred in phase with increasing northern hemisphere summer insolation, coinciding with northward displacement of the Intertropical Convergence Zone, enhanced boreal summer monsoon and expansion of the Indo-Pacific Warm Pool. Thermocline temperatures (Pulleniatina obliquiloculata Mg/Ca) gradually decreased from 24.5 to 21.5 °C since 10.3 ka, reflecting intensification of a cool thermocline throughflow. The vertical structure of the upper ocean in the Timor Sea evolved in similar fashion during the Holocene and MIS5e, although the duration of SST plateaux differed (11.3 to 6.4 ka in Termination I and from 129 to 119 ka in Termination II), which was probably due to the more intense northern hemisphere summer insolation during MIS 5e. During both terminations, SST increased simultaneously in the southern high latitudes and the tropical eastern Indian Ocean, suggesting virtually instantaneous atmospheric climate feedbacks between the high and low latitudes.

A Middle Pleistocene nannofossil record of sediment core MD03-2699

Changes in paleoclimate and paleoproductivity patterns have been identified by analysing, in conjunction with other available proxy data, the coccolithophore assemblages from core MD03-2699, located in the Portuguese margin in the time interval from the Marine Isotope Stage (MIS) 13/14 boundary to MIS 9 (535 to 300 ka). During the Mid-Brunhes event, the assemblages associated with the eccentricity minima are characterised by higher nannoplankton accumulation rate (NAR) values and by the blooming of the opportunistic genus Gephyrocapsa. Changes in coccolithophore abundance are also related to glacial-interglacial cycles. Higher NAR and numbers of coccoliths/g mainly occurred during the interglacial periods, while these values decreased during the glacial periods. Superimposed on the glacial/interglacial cycles, climatic and paleoceanographic variability has been observed on precessional timescales. The structure of the assemblages highlights the prevailing long-term influence of the Portugal (PC) and Iberian Poleward (IPC) Currents, following half and full precession harmonics, related to the migration of the Azores High (AH) Pressure System. Small Gephyrocapsa and Coccolithus pelagicus braarudii are regarded as good indicators for periods of prevailing PC influence. Gephyrocapsa caribbeanica, Syracosphaera spp., Rhabdosphaera spp. and Umbilicosphaera sibogae denote periods of IPC influence. Our data also highlights the increased percentages of Coccolithus pelagicus pelagicus during the occurrence of episodes of very cold and low salinity surface water, probably related to abrupt climatic events and millennial-scale oscillations of the AH/Icelandic Low (IL) System.

Faunal analysis and Mg/Ca records of planktic foraminifera in sediment core SO189/2_039KL

Climate phenomena like the monsoon system, El Niño Southern Oscillation (ENSO) and the Indian Ocean Dipole (IOD) are interconnected via various feedback mechanisms and control the climate of the Indian Ocean and its surrounding continents on various timescales. The eastern tropical Indian Ocean is a key area for the interplay of these phenomena and for reconstructing their past changes and forcing mechanisms. Here we present records of upper ocean thermal gradient, thermocline temperatures (TT) and relative abundances of planktic foraminifera in core SO 189-39KL taken off western Sumatra (0°47.400' S, 99°54.510' E) for the last 8 ka that we use as proxies for changes in upper ocean structure. The records suggest a deeper thermocline between 8 ka and ca 3 ka compared to the late Holocene. We find a shoaling of the thermocline after 3 ka, most likely indicating an increased occurrence of upwelling during the late Holocene compared to the mid-Holocene which might represent changes in the IOD-like mean state of the Indian Ocean with a more negative IOD-like mean state during the mid-Holocene and a more positive IOD-like mean state during the past 3 ka. This interpretation is supported by a transient Holocene climate model simulation in which an IOD-like mode is identified that involves an insolation-forced long-term trend of increasing anomalous surface easterlies over the equatorial eastern Indian Ocean.

Palaeoceanographic data of sediment core MD01-2416

We present an SiF4 separation line, coupled to a laser fluorination system, which allows for an efficient combined silica d18O and d30Si analysis (50 min per sample). The required sample weight of 1.5-2.0 mg allows for high-resolution isotope studies on biogenic opal. Besides analytical tests, the new instrumentation set-up was used to analyse two marine diatom fractions (>63 µm, 10-20 µm) with different diatom species compositions extracted from a Bølling/Allerød-Holocene core section [MD01-2416, North-West (NW) Pacific] to evaluate the palaeoceanographic significance of the diatom isotopic signals and to address isotopic effects related to contamination and species-related isotope effects (vital and environmental effects). While d30Si offsets between the two fractions were not discernible, supporting the absence of species-related silicon isotope effects, systematic offsets occur between the d18O records. Although small, these offsets point to species-related isotope effects, as bias by contamination can be discarded. The new records strengthen the palaeoceanographic history during the last deglaciation in the NW Pacific characterized by a sequence of events with varying surface water structure and biological productivity. With such palaeoceanographic evolution it becomes unlikely that the observed systematic d18O offsets signal seasonal temperature variability. This calls for reconsideration of vital effects, generally excluded to affect d18O measurements.

Prominent deformation features and interpretation of sediment core CRP-2/2A (Table 1)

Sediment deformation features in CRP-2/2A were described during normal logging procedures and from core-scan images. In this paper the origin of soft-sediment folding, contorted bedding, microfaulting, clastic dykes, shear zones and intraformational breccias is discussed. The features have a stratigraphic distribution related to major unconformities and sequence boundaries. Hypotheses for the origins of sediment deformation include hydrofracturing, subglacial shearing, slumping, and gas hydrate formation. Shear zones, microfaults, clastic dykes and contorted bedding within rapidly deposited sediments, suggest that slumping in an ice-distal environment occurred in the early Oligocene. A till wedge beneath a diamictite at 364 mbsf the mid-Oligocene section represents the oldest evidence of grounded ice in CRP-2/2A. Shear zones with a subglacial origin in the early late Oligocene and early Miocene sections of the core are evidence of further grounding events. The interpretation of sediment deformation in CRP-2/2A is compared to other Antarctic stratigraphic records and global eustatic change between the late Eocenel/early Oligocene and the middle Miocene.

Barium/Calcium and Cadmium/Calcium ratios of sediment core RC13-229

A new benthic foraminiferal Ba/Ca and Cd/Ca data set from core RC13-229 in the deep Cape Basin indicates only small variations in bottom water nutrient concentrations in Circumpolar Deep Water (CPDW) over the last 450 kyr. Variability in the Ba record is characterized by somewhat higher values during glacial periods, consistent with a reduction in the flux of Ba-depleted North Atlantic Deep Water to the Southern Ocean during glacial periods. The small changes in the Ba and Cd records contrast with the large and systematic increase in CPDW nutrients during glacial periods implied by the benthic delta13C record. This discrepancy, essentially an extension of the well-known Southern Ocean Cd-delta13C conflict, is evaluated by transforming RC13-229 paleochemical data into carbonate parameters using the modern oceanic relationships between delta13C, Cd, and SumCO2 and between Ba and alkalinity. Calculations using Cd/Ca to estimate past variations in CPDW SumCO2 and Ba/Ca to estimate past variations in CPDW alkalinity yield carbonate ion concentrations that exceed calcite saturation throughout the record length, with generally higher carbonate ion values associated with glacial intervals (opposite in sense to the RC13-229 %CaCO3 record). Substituting delta13C to estimate SumCO2 leads to extreme calcite undersaturation at this site during glacial periods, clearly inconsistent with the preservation of calcite throughout the length of RC13-229. Accepting the carbon isotope record as a direct measure of past variations in CPDW SumCO2 concentrations requires that both the Cd and Ba evidence for limited nutrient and alkalinity changes be disregarded.

Helium-3 in different carriers from pelagic clays of DSDP Hole 91-596B and Core LR-44-GPC-3

To better understand the composition, characteristics of helium diffusion, and size distribution of interplanetary dust particles (IDPs) responsible for the long-term retention of extraterrestrial 3He, we carried out leaching, stepped heating, and sieving experiments on pelagic clays that varied in age from 0.5 Ma to ~90 Myr. The leaching experiments suggest that the host phase(s) of 3He in geologically old sediments are neither organic matter nor refractory phases, such as diamond, graphite, Al2O3, and SiC, but are consistent with extraterrestrial silicates, Fe-Ni sulfides, and possibly magnetite. Stepped heating experiments demonstrate that the 3He release profiles from the magnetic and non-magnetic components of the pelagic clays are remarkably similar. Because helium diffusion is likely to be controlled by mineral chemistry and structure, the stepped heating results suggest a single carrier that may be magnetite, or more probably a phase associated with magnetite. Furthermore, the stepped outgassing experiments indicate that about 20% of the 3He will be lost through diffusion at seafloor temperatures after 50 Myrs, while sedimentary rocks exposed on the Earth's surface for the same amount of time would lose up to 60%. The absolute magnitude of the 3He loss is, however, likely to depend upon the 3He concentration profile within the IDPs, which is not well known. Contrary to previous suggestions that micrometeorites in the size range of 50-100 µm in diameter are responsible for the extraterrestrial 3He in geologically old sediments [Stuart, F.M., Harrop, P.J., Knott, S., Turner, G., 1999. Laser extraction of helium isotopes from Antarctic micrometeorites: source of He and implications for the flux of extraterrestrial 3He flux to earth. Geochimica et Cosmochimica Acta, 63, 2653-2665, doi:10.1016/S0016-7037(99)00161-1], our sieving experiment demonstrates that at most 20% of the 3He is carried by particles greater than 50 µm in diameter. The size-distribution of the 3He-bearing particles implies that extraterrestrial 3He in sediments record the IDP flux rather than the micrometeorite flux.

Shifts in the microbial community structure in different temperatures during sample storage from IODP Hole 325-M0058A

The objective of this study was to determine shifts in the microbial community structure and potential function based on standard Integrated Ocean Drilling Program (IODP) storage procedures for sediment cores. Standard long-term storage protocols maintain sediment temperature at 4°C for mineralogy, geochemical, and/or geotechnical analysis whereas standard microbiological sampling immediately preserves sediments at -80°C. Storage at 4°C does not take into account populations may remain active over geologic time scales at temperatures similar to storage conditions. Identification of active populations within the stored core would suggest geochemical and geophysical conditions within the core change over time. To test this potential, the metabolically active fraction of the total microbial community was characterized from IODP Expedition 325 Great Barrier Reef sediment cores prior to and following a 3-month storage period. Total RNA was extracted from complementary 2, 20, and 40 m below sea floor sediment samples, reverse transcribed to complementary DNA and then sequenced using 454 FLX sequencing technology, yielding over 14,800 sequences from the six samples. Interestingly, 97.3% of the sequences detected were associated with lineages that changed in detection frequency during the storage period including key biogeochemically relevant lineages associated with nitrogen, iron, and sulfur cycling. These lineages have the potential to permanently alter the physical and chemical characteristics of the sediment promoting misleading conclusions about the in situ biogeochemical environment. In addition, the detection of new lineages after storage increases the potential for a wider range of viable lineages within the subsurface that may be underestimated during standard community characterizations.

Pore water chemistry of sediment core GeoB15101-7 and water chemistry of CTD casts GeoB15101-1 and GeoB15101-6

Submarine brine lakes feature sharp and persistent concentration gradients between seawater and brine, though these should be smoothed out by free diffusion in open ocean settings. The anoxic Urania basin of the Eastern Mediterranean contains an ultra sulfidic, hypersaline brine of Messinian origin above a thick layer of suspended sediments. With a dual modeling approach we reconstruct its contemporary stratification by geochemical solute transport fundamentals, and show that thermal convection is required to maintain mixing in the brine and mud layer. The origin of the Urania basin stratification was dated to 1650 years before present, which may be linked to a major earthquake in the region. The persistence of the chemoclines may be key to the development of diverse and specialized microbial communities. Ongoing thermal convection in the fluid mud layer may have important, yet unresolved consequences for sedimentological and geochemical processes, also in similar environments.