982 resultados para Reflectance Spectroscopy
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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)
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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
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Pós-graduação em Química - IQ
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Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
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In this work were studied associations of ZnO with the natural products caffeic and feluric acids. Two preparation methods were used, that is, the sol-gel and a reflux procedure. In the sol-gel method, ZnO is produced by the basics hydrolysis of precursors in the presence of the organic filters (caffeic and feluric acids), which results in 30 nm (or less) ZnO particles with the organic filters (in dissociated form) bonded to the surface of ZnO. In the reflux method, a dispersion of ZnO in a water/ethanol mixture was kept under reflux (50oC/4h) in the presence of the organic acids. The ZnO particles used in the reflux method have a higher diameter than sol-gel ZnO particles, but the prepared associated product ZnO/Organic acids were similar. Despite of the difference in relation to crystallinity between the products, the preparation methods resulted in analogous associations with respect to the interaction of the organic filters with the ZnO surface. The caffeic/ZnO associations presented low photostability, which lead to the degradation of the organic filter. The other associations (feluric acid/ZnO) presented satisfactory results. The FT-IR spectroscopy confirmed the formation of the association, and the nature of the bond formed compared with the Zn-O bond in Zn2+/Felutic acid complexes. The isolated organic and inorganic filters, along with the associations were analyzed by diffuse reflectance spectroscopy and Uv-vis spectroscopy. The absorption edges and the critical wavelengths were analyzed and the effects of Zn-O bonds in feluric acid/ZnO associations described as a function of the relative position of the π/π* system of the organic filter. Finally the performance of the hybrid filters were investigated in terms of the absorption of UVA and UVB radiations, with the UVA/UVB ratio, an efficiency parameter largely used in the description of solar filters, sunscreen and suncare products
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Pós-graduação em Agronomia (Ciência do Solo) - FCAV
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Pós-graduação em Agronomia (Ciência do Solo) - FCAV
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Pós-graduação em Ciências Odontológicas - FOAR
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Pós-graduação em Química - IQ
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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)
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Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
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The objective of this work was to evaluate the possibility of mapping adsorbed phosphorus through soil color and magnetic susceptibility. The experiment was done in a 380-ha sugarcane area, which included four types of Oxisols, with different texture and natural fertility. Two hundred and forty-one soil samples were collected at 0.00-0.25-m depth. The soil redness index was calculated from sample values of hue, value, and chroma, obtained with diffuse reflectance spectroscopy. Regression models were adjusted between adsorbed phosphorus and soil magnetic susceptibility or redness index. Data spatial dependence was evaluated with geostatistics. Magnetic susceptibility is significantly correlated to adsorbed phosphorus, which allows it to be used as a component in pedotransfer functions for indirect quantification of soil adsorbed phosphorus. The redness index and the magnetic susceptibility show spatial dependency with adsorbed phosphorus. Soil magnetic susceptibility and redness index, evaluated with diffuse reflectance spectroscopy, can aid in the mapping and identification of areas with different phosphorus adsorption potential.