稀土冠醚配合物的研究XX．Schiff碱型双冠醚N，N’－对苯二甲亚基双（4’－氨基苯并－15－冠－5）稀土配合物的合成和性质

合成了一种Ｓｃｈｉｆｆ碱型双冠醚Ｎ，Ｎ’－对苯二甲亚基双（４’－氨基苯并－１５－冠－５）及其稀土硝酸盐的固体配合物，通过元素分析、摩尔电导、ＩＲ、ＵＶ、１ＨＮＭＲ和热分析等对其性质作了表征与比较。

PE-MAH的合成及其对PE/NBR的增容作用

聚乙烯(PE)、马来酸酐(MAH)和过氧化二异丙苯(DCP)在溶液中反应,其产物经多次纯化和红外光谱分析证明,MAH以化学键连接到PE分子链上,接枝率达0.5MAH/100E,即相当于平均每个PE上接枝有10个MAH。用不同接枝率的聚乙烯接枝马来酸酐共聚物(PE-MAH)作为极性差别较大的PE和丁腈橡胶(NBR)的相容剂,分别研究其接枝率和用量对共混物的拉伸强度和低温冲击强度的影响,结果发现:PE-MAH增加了PE/NBR的相容性。低温脆断面的扫描电子显微镜观察清楚地反映出PE-MAH的增容作用。本文还提出了增容模型。

STRUCTURE OF [LA(NO3)(3)(OH2)(2)(OHME)(BIPY)].15-CROWN-5

[La(NO3)(3)(OH2)(2)(OHMe)(bipy).15-crown-5 is monoclinic, P2(1)/n, with a = 11.239(6), b = 19.302(7), c = 14.458(8) Angstrom, beta = 92.47(5)degrees, and D-calc = 1.63 g cm(-3) for Z = 4. In the complex, two nitrogen atoms (from bipy) and nine oxygen atom

5，10，15，20－四（对－山嵛酸乙酯－α－氧代苯基）卟啉LB膜结构研究

５，１０，１５，２０－四（对－山嵛酸乙酯－α－氧代苯基）卟啉ＬＢ膜结构研究王海水，曾广赋，谷淑珍，席时权（中国科学院长春应用化学研究所长春１３００２２）利用ＬＢ膜技术将分子组装成有序的分子单层或多层体系，研究膜内分子间相互作用和分子的结构，对了解结构...

5,10,15,20-四(对-乙酯苯基)卟啉LB膜的结构

对卟啉类化合物LB膜的结构、电性质和气敏性的研究已见报道。本文利用膜天平和UV-Vis分光光度计研究了标题化合物在气-液界面上的成膜特性、分子间相互作用和LB膜的结构。5,10,15,20-四(对-乙酯苯基)卟啉(TPEPP)由5,10,15,20-四(对-氰苯基)卟啉和乙醇酯化得到。元素分析测定值与计算值相符。λ(CHCl_3,nm):421,515,550,590,645;ν(KBr压

仲碳伯胺萃取铈(Ⅳ)机理的~1H,~(15)N核磁共振谱研究

仲碳伯胺N_(1923)萃取铈(Ⅳ)的~1H,~(15)N-NMR研究表明,在萃取铈(Ⅳ)时也同时萃取H_2O和H_2SO_4进入有机相,当铈(Ⅳ)浓度较高时,铈(Ⅳ)与N_(1923)生成配合物。

原子吸收光谱法测定人参中15个微量元素

本文研究了火焰原子吸收,石墨炉原子吸收,结合基体改进剂和平台技术,测定了人参中Pb、Ca、Co、Ni、Cr、Ba、K、Na、Cd、Mg、Fe、Cu、Zu、Mn、Sr等十五个微量元素,结果满意。

Pr_xLa_(1-x)P_5O_(15)晶体的荧光动力学研究

本文利用 Pr~(3+)离子在 Pr_xLa_(1-x)P_5O_(14)晶体中的光谱性质和能级,在考虑~3P_o-~1D_2和~3H_4-~3H_6,~1D_2-~1D_4和~3H_4-~3F_4两个能级对交叉弛豫的情况下,详细研究了 Pr~(3+)离子的荧光动力学过程,给出了~3P_o,~1D_2和~1G_4能级的荧光发射规律。

稀土硝酸盐15-冠-5络合物的一些性质

稀土冠醚络合物的组成和稳定性不但与稀土离子直径和冠醚孔径是否匹配,而且也和阴离子及合成用的溶剂有关.因15-冠-5(简写15C5)的孔径(2.2?)和大部分稀土离子直径相近.因此它们的络合物是研究孔径匹配关系的理想模型. Bunzli在乙腈中合成了大部分镧系硝酸盐15C5络合物,轻镧系(La-Gd)生成1:1无水络合物,重镧系(Tb-Lu)为含1—3分子水的1:1络合物.我们在无水丙酮中制备

Diterpenes, sesquiterpenes, and a C-15-acetogenin from the marine red alga Laurencia mariannensis

In addition to 10 known compounds (7-16), one new brominated diterpene, 10-hydroxykahukuene B (1), two new sesquiterpenes, 9-deoxyelatol (2) and isodactyloxene A (3), one new brominated C-15-acetogenin, laurenmariallene (4), and two new naturally occurring halogenated sesquiterpenes (5 and 6) that were previously obtained as intemediates in a biomimetic synthetic study of rhodolaureol and rhodolauradiol have been isolated and identified from the organic extract of the marine red alga Laurencia mariannensis. The structures of these compounds were established by spectroscopic methods. The antibacterial and antifungal activities of new compounds 1-4 were evaluated.

Laurendecumallenes A-B and laurendecumenynes A-B, halogenated nonterpenoid C-15-Acetogenins from the marine red alga Laurencia decumbens

Four new halogenated nonterpenoid C-15-acetogenins, 4:7,6:13-bisepoxy-9,10-diol-1,12-dibromopentadeca-1,2-diene (1, laurendecumallene A), 4:7,6:12-bisepoxy-9,10-diol-1,13-dibromopentadeca-1,2-diene (2, laurendecumallene 13), (3Z)-6:10,7:13-bisepoxy-12-bromo-9-hydroperoxylpentadeca-3-en-1-yne (3, laurendecumenyne A), and (3Z)-6:10,9:13-bisepoxy-12-bromo-7-chloropentadeca-3-en-1-yne (4, laurendecumenyne 13), together with one known halogenated C-15-acetogenin elatenyne (5) were isolated and identified from the organic extract of the marine red alga Laurencia decumbens. Their structures and relative stereochemistry were established by means of spectroscopic analysis including UV, IR, high-resolution electrospray ionization mass spectrometry (HRESIMS), and ID and 2D NMR techniques. All these metabolites were submitted for the cytotoxic assay against tumor cell line A549 (human lung adenocarcinoma), but all of them were found inactive (IC50 > 10 mu g/mL).

Halogenated Terpenes and a C-15-Acetogenin from the Marine Red Alga Laurencia saitoi

Seven parguerane diterpenes: 15-bromo-2,7,19-triacetoxyparguer-9(11)-en-16-ol (1), 15-bromo-2,7,16,19-tetraacetoxyparguer-9(11)-ene (2), 15-bromo-2,19-diacetoxyparguer-9(11)-en-7,16-diol (3), 15-bromo-2,16,19-triacetoxyparguer-9(11)-en-7-ol (4), 15bromo-2,16-diacetoxyparguer-9(11)-en-7-ol (5), 15-bromoparguer-9(11)-en-16-ol (6), 15-bromoparguer-7-en-16-ol (7), two polyether triterpenes: thyrsiferol (8) and thyrsiferyl 23-acetate (9), and one C15-acetogenin, neolaurallene (10), were isolated from a sample of marine red alga Laurencia saitoi collected off the coast of Yantai. Their structures were established by detailed NMR spectroscopic analysis and comparison with literature data.

Laurenidificin, a new brominated C-15-acetogenin from the marine red alga Laurencia nidifica

new brominated C-15-acetogenin, namely, laurenidificin, was isolated from the marine red alga Laurencia nidifica. Its structure was determined on the basis of spectroscopic methods. (C) 2010 Bin Gui Wang. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.

Inheritance of 15 microsatellites in the Pacific oyster Crassostrea gigas: segregation and null allele identification for linkage analysis

Microsatellites were screened in a backcross family of the Pacific oyster, Crassostrea gigas. Fifteen microsatellite loci were distinguishable and polymorphic with 6 types of allele-combinations. Null alleles were detected in 46.7% of loci, accounting for 11.7% of the total alleles. Four loci did not segregate in Mendelian Ratios. Three linkage groups were identified among 7 of the 15 segregating loci. Fluorescence-based automated capillary electrophoresis (ABI 310 Genetic Analyzer) that used to detect the microsatellite loci, has been proved a fast, precise, and reliable method in microsatellite genotyping.