The determination of ethylene-propylene copolymer-grafted-glycidyl methacrylate by the contact angle method

The contact angles theta of some liquids on ethylene-propylene copolymer-grafted-glycidyl methacrylate (EPM-g-GMA) were measured. The critical surface tensions r(c) of EPM-g-GMA were evaluated by the Zisman Plot (cos theta versus r(L)), Young-Dupre-Good-Girifalco plot (1 + cos theta versus 1/r(L)(0.5)) and log (1 + cos theta) versus log(r(L)) plot. The following results were obtained: the r(c) values varied significantly with the estimation methods. The critical surface tension r(c) decreased with the increase of the degree of grafting of EPM-g-GMA.

Small angle X-ray scattering study of structural parameters of the aggregated state in polyamide 1010+BMI

The structural parameters of the aggregated state in the polyamide PA1010 and N,N'-bismaleimide-4,4'-diphenyl methane (BMI) system were computed by means of the desmearing intensity from SAXS and using the concept of the distance distribution function. The results revealed that the parameters Q, I(0), l(c) and L decreased with the increase BMI component, whereas O-s increased. The particle dimension Z for different BMI contents was less than 13.2 nm, and the maximum value of the distance distribution function P(Z) was found to be in the range Z = 6.5-7.0 nm.

SMALL-ANGLE X-RAY-SCATTERING STUDY ON THE INTERFACE IN BLOCK-COPOLYMERS WITH FRACTAL PROPERTIES

The interface thickness in two triblock copolymers were determined using small-angle x-ray scattering in the context of the theory proposed by Ruland. The thickness was found to be nonexistent for the samples at three different temperatures. By viewing th

Energy-dependent in-situ small-angle x-ray scattering study of nano-ceramics

R Winter, D Le Messurier, CM Martin; Cryst Rev 12 (2006) 3 Sponsorship: EPSRC, CCLRC, Pilkington

Small angle scattering characterisation of micellar systems and templated architectures

The work described in this thesis reports the structural changes induced on micelles under a variety of conditions. The micelles of a liquid crystal film and dilute solutions of micelles were subjected to high pressure CO2 and selected hydrocarbon environments. Using small angle neutron scattering (SANS) techniques the spacing between liquid crystal micelles was measured in-situ. The liquid crystals studied were templated from different surfactants with varying structural characteristics. Micelles of a dilute surfactant solution were also subjected to elevated pressures of varying gas atmospheres. Detailed modelling of the in-situ SANS experiments revealed information of the size and shape of the micelles at a number of different pressures. Also reported in this thesis is the characterisation of mesoporous materials in the confined channels of larger porous materials. Periodic mesoporous organosilicas (PMOs) were synthesised within the channels of anodic alumina membranes (AAM) under different conditions, including drying rates and precursor concentrations. In-situ small angle x-ray scattering (SAXS) and transmission electron microscopy (TEM) was used to determine the pore morphology of the PMO within the AAM channels. PMO materials were also used as templates in the deposition of gold nanoparticles and subsequently used in the synthesis of germanium nanostructures. Polymer thin films were also employed as templates for the directed deposition of gold nanoparticles which were again used as seeds for the production of germanium nanostructures. A supercritical CO2 (sc-CO2) technique was successfully used during the production of the germanium nanostructures.

Remembering from any angle: the flexibility of visual perspective during retrieval.

When recalling autobiographical memories, individuals often experience visual images associated with the event. These images can be constructed from two different perspectives: first person, in which the event is visualized from the viewpoint experienced at encoding, or third person, in which the event is visualized from an external vantage point. Using a novel technique to measure visual perspective, we examined where the external vantage point is situated in third-person images. Individuals in two studies were asked to recall either 10 or 15 events from their lives and describe the perspectives they experienced. Wide variation in spatial locations was observed within third-person perspectives, with the location of these perspectives relating to the event being recalled. Results suggest remembering from an external viewpoint may be more common than previous studies have demonstrated.

A regularized iterative algorithm for limited-angle inverse Radon transform

The tomography problem is investigated when the available projections are restricted to a limited angular domain. It is shown that a previous algorithm proposed for extrapolating the data to the missing cone in Fourier space is unstable in the presence of noise because of the ill-posedness of the problem. A regularized algorithm is proposed, which converges to stable solutions. The efficiency of both algorithms is tested by means of numerical simulations. © 1983 Taylor and Francis Group, LLC.

Resolution Limits in Full- and Limited-Angle Tomography

info:eu-repo/semantics/published

El problema de basilea. El año de Euler: 1707-2007

El pasado 15 de abril se cumplían 300 años del nacimiento de uno de los cuatro matemáticos más geniales de la historia, Leonhard Euler. Para mí, los otros tres, y que cada cual elija su orden, son Arquímedes, Newton y Gauss. Si la calificación la hiciésemos atendiendo a la cantidad de los trabajos de primer orden realizados por cada uno de ellos, sin duda Euler ocuparía el primer lugar. A lo largo de su extensa vida Euler produjo más de ochocientos libros y miles de artículos y trabajos. Sus obras completas Opera Omnia ocupan más de 80 volúmenes. Sin lugar a dudas es el matemático más prolífico de la Historia. Pero, con ser importante la cantidad de trabajos, el aprecio de los matemáticos contemporáneos y posteriores a él se debe más a la riqueza, originalidad, belleza y genial agudeza de su obra que a su volumen.

Euler y el número π

Uno de los más prolíficos matemáticos, sino el que más, que han existido a lo largo de toda la historia, ha sido el suizo Leonhard Euler (1707-1783). Además de, en nuestro caso, introducir el uso de la letra griega π (inicial de perímetro) para nuestro número, dió numerosas aproximaciones mediante desarrollos en serie de la relación existente entre la circunferencia y su diámetro. El presente articulo trata de explicar el ingenioso procedimiento de dos de dichas series: la serie de Jacques Bernouilli y, la serie de Leibniz.

Recta de Euler en cuadriláteros

El circuncentro (O), baricentro (G) y ortocentro (H) de todo triangulo estan alineados en la recta de Euler y verifican la relación mGH = 2 · mOG. En el presente artıculo se define baricentro (G) y ortocentro (H) de un cuadrilátero inscriptible de circuncentro (O) y se demuestra que dichos puntos están alineados y verifican la relación mGH = 3 · mOG.