Deute públic europeu : els Eurobons

En el següent Treball de Fi de Carrera, s’explicarà l’origen i les causes de la crisi de deute sobirà europeu. Observarem també la situació de cada un dels 17 països que composen la unió monetària i veurem possibles solucions a adoptar en el curt, mig i llarg termini. Un cop vistes les possibles solucions, ens centrarem amb els Eurobons, un instrument innovador, el qual s’està valorant la seva implantació a la zona euro. Analitzarem les seves característiques, si seria convenient i quines propostes s’han fet perquè s’implantin.

Qualitat microbiològica dels productes vegetals frescos mínimament processats i desenvolupament de tecnologies de bioconservació mitjançant bacteris de l'àcid làctic

Food safety today is conditiones by the implementation of new Tecnologies for food preservation based on mild treatments and mínimum process, Novel foods, severe restrictions in the toxicològic profile of chemical preservatives, And the drastic limitation /prohibition of antibiotics, and as a consequence, by the New emergint pathogens or by the increase of classical food-borne pathogens. Biopreservatives appear within this context with strong expectations, because thei are safe microorganisms of ten isolated from foods, chemical compounds of natural origin -antimicrobial peptides and proteins, botanical extracts, enzymes- and sintetic compounds based on natural structures, but less toxic and more eficients, like the amtimicrobial peptides. Among the microbial biopreservatives, lactic acid bacteria have shown great possibilities in the preservation of cured meat products, ready to eat fresh fruit and vegetables, as well as to decrease microbial spoilage in food by products before processing for valorization. Our laboratory has performed an extense survey of the microbiological quality of fresh fruit and vegetables, and of ready-to-eat products, and have detect low levels, but significant of Salmonella sp., E. coli and Listeria spp., including L.monocytogenes, in retail markets and Supermarkets of Catalonia. Due to this reason, we started a project consisting of Developing application of lactic acid bacteria (LAB) obtained from these products, as biopreservatives. LAB were abundant in ready-to-eat fresh fruits and vegetables, specially in germinated seeds. From these products we obtained strains of Leuconostoc, Lactobacillus and Weissella, producing bacteriocins and with a Significant activity of control of L.monocytogenes in fresh apple and cut salad. Ather strains were efective in the inhibition of fungal rot during postharvest caused by Penicillium expansum

La competencia informacional en las bibliotecas de la Universitat Politècnica de Catalunya (UPC)

Las bibliotecas de la Universidad Politécnica de Catalunya (UPC) han desarrollado un completo mapa de formación para el desarrollo de habilidades informacionales dentro de los planes curriculares de grado, posgrado, máster y doctorado. En el presente artículo se describe la consolidación de acciones vinculadas a las competencias informacionales como parte de la estrategia de las bibliotecas para dar respuesta a los retos de aprendizaje e investigación de la Universidad, se exponen ejemplos de recursos utilizados y se plantean los retos de futuro para cada dimensión formativa.

Disseny, implementació i avaluació d'un joc tangible basat en puzles per aprendre concepte de les enginyeries TIC

L'interès per les carreres relacionades amb les enginyeries del camp de les Tecnologies de la Informació i la Comunicació (TIC) va caient any rere any i això es tradueix en menys matriculacions per cada any que passa. Una de les causes principals és la falta de motivació i interès envers aquestes carreres. Aquest problema s’atribueix a que les metodologies d’aprenentatge tradicionals no s’adeqüen a les necessitats i requeriments dels estudiants d’avui dia, que han crescut envoltats de tecnologia, i se’ls coneix amb el nom en anglès de digitalnatives.L’aprenentatge basat en jocs sorgeix com a una possible solució per afrontar aquesta falta d’interès per les àrees del coneixement relacionades amb les enginyeries TIC. Aquest mètode d'aprenentatge consisteix en que els estudiants aprenguin conceptes de les TIC mentre estan jugant a un joc. Per tant, en el context d’aquest PFC, ens centrarem en el disseny i implementació d’un joc per aprendre conceptes bàsics de les enginyeries TIC. En concret, el disseny d’aquest joc segueix les característiques definides per un model conceptual que descriuquins són els elements necessaris per crear jocs basats en puzles: quins són els elements principals que componen aquests tipus de joc i quines pistes es poden afegir per guiar a l’estudiant en el procés d’aprenentatge amb el joc. Per altra banda, pel que fa a laimplementació del joc, s’utilitzarà tecnologia basada en interfícies tangibles.Per tal d’analitzar el joc basat en puzles que s’ha dissenyat i implementat per aprendre conceptes basics de les Enginyeries TIC, s’ha portat a terme una avaluació amb estudiants d’un centre educatiu. Aspectes com el disseny de pistes, l’experiència dels estudiants amb el joc il’aprenentatge amb el joc seran analitzats per extreure les conclusions oportunes.

Les comunitats segetals de la Cerdanya. Consideracions generals sobre la vegetació medioeuropea de la classe Secalietea a Catalunya

Aquest article estudia la vegetació dels sembrats (classe Secalietea Br.-Bl. 1952) de la Baixa Cerdanya i zones adjacents mitjançant el mètode fitocenològic i fa un repàs d'aquest tipus de comunitats a la Catalunya extramediterrània. Els sembrats dels terrenys àcids són referits a l'associació Scleranthetum anuui Br.-Bl. 1915, de l'aliança Scleranthion annui, força rara a la Cerdanya. Pel que fa a les comunitats neutròfiles, adscrites a l'aliança Caucalidion lappulae, discutim de primer el tractament sintaxonòmic rebut per aquest tipus de vegetació als Pirineus i altres zones peninsulars en treballs precedents. Hi reconeixem tres associacions: Kickxio-Nigelletum gallicae Fanlo 1988, coneguda només dels Pirineus centrals; Violo-Legousietum Hybridae O. Bolòs 1959, estesa pels Prepirineus calcaris i la Catalunya central; i Biforo radiantis-Centaureetum cyani Vigo, Carreras, Carrillo et I. Soriano, ass nova, dins de la qual proposem d'incloure les comunitats cerdanes

Optical-geometrical effects on the photoluminescence spectra of Si nanocrystals embedded in SiO2

We demonstrate that thickness, optical constants, and details of the multilayer stack, together with the detection setting, strongly influence the photoluminescence spectra of Si nanocrystals embedded in SiO2. Due to multiple reflections of the visible light against the opaque silicon substrate, an interference pattern is built inside the oxide layer, which is responsible for the modifications in the measured spectra. This interference effect is complicated by the depth dependence of (i) the intensity of the excitation laser and (ii) the concentration of the emitting nanocrystals. These variations can give rise to apparent features in the recorded spectra, such as peak shifts, satellite shoulders, and even splittings, which can be mistaken as intrinsic material features. Thus, they can give rise to an erroneous attribution of optical bands or estimate of the average particle size, while they are only optical-geometrical artifacts. We have analyzed these effects as a function of material composition (Si excess fraction) and thickness, and also evaluated how the geometry of the detection setup affects the measurements. To correct the experimental photoluminescence spectra and extract the true spectral shape of the emission from Si nanocrystals, we have developed an algorithm based on a modulation function, which depends on both the multilayer sequence and the experimental configuration. This procedure can be easily extended to other heterogeneous systems.

Conduction mechanisms and charge storage in Si-nanocrystals metal-oxide-semiconductor memory devices studied with conducting atomic force microscopy

In this work, we demonstrate that conductive atomic force microscopy (C-AFM) is a very powerful tool to investigate, at the nanoscale, metal-oxide-semiconductor structures with silicon nanocrystals (Si-nc) embedded in the gate oxide as memory devices. The high lateral resolution of this technique allows us to study extremely small areas ( ~ 300nm2) and, therefore, the electrical properties of a reduced number of Si-nc. C-AFM experiments have demonstrated that Si-nc enhance the gate oxide electrical conduction due to trap-assisted tunneling. On the other hand, Si-nc can act as trapping centers. The amount of charge stored in Si-nc has been estimated through the change induced in the barrier height measured from the I-V characteristics. The results show that only ~ 20% of the Si-nc are charged, demonstrating that the electrical behavior at the nanoscale is consistent with the macroscopic characterization.

Metal-Nitride-oxide-semiconductor light-emitting devices for general lighting.

The potential for application of silicon nitride-based light sources to general lighting is reported. The mechanism of current injection and transport in silicon nitride layers and silicon oxide tunnel layers is determined by electro-optical characterization of both bi- and tri-layers. It is shown that red luminescence is due to bipolar injection by direct tunneling, whereas Poole-Frenkel ionization is responsible for blue-green emission. The emission appears warm white to the eye, and the technology has potential for large-area lighting devices. A photometric study, including color rendering, color quality and luminous efficacy of radiation, measured under various AC excitation conditions, is given for a spectrum deemed promising for lighting. A correlated color temperature of 4800K was obtained using a 35% duty cycle of the AC excitation signal. Under these conditions, values for general color rendering index of 93 and luminous efficacy of radiation of 112 lm/W are demonstrated. This proof of concept demonstrates that mature silicon technology, which is extendable to lowcost, large-area lamps, can be used for general lighting purposes. Once the external quantum efficiency is improved to exceed 10%, this technique could be competitive with other energy-efficient solid-state lighting options. ©2011 Optical Society of America OCIS codes: (230.2090) Electro-optical devices; (150.2950) Illumination.

Direct modulation of electroluminescence from silicon nanocrystals beyond radiative recombination rates

We propose a light emitting transistor based on silicon nanocrystals provided with 200 Mbits/ s built-in modulation. Suppression of electroluminescence from silicon nanocrystals embedded into the gate oxide of a field effect transistor is achieved by fast Auger quenching. In this process, a modulating drain signal causes heating of carriers in the channel and facilitates the charge injection into the nanocrystals. This excess of charge enables fast nonradiative processes that are used to obtain 100% modulation depths at modulating voltages of 1 V.

Si nanocrystal-based LEDs fabricated by ionimplantation and plasma-enhanced chemical vapourdeposition

Dept. Electrònica

The First World War and coal trade geography in Latin America and the Caribbean (1890-1930)

This paper aims to illustrate the dynamics of coal trade between Latin America and its main trade partners, i.e. the USA, Great Britain and Germany, before and after the enormous disruption caused by the First World War. The coal trade was used as an indicator of modernization for Latin American countries, given that oil was at that time of secondary importance. Energy imports have determined the possibilities of each Latin American country in its process of development. Here we address this question and place special emphasis on supply channels, concluding that the trade link with main suppliers was of key significance. Although this was very clear by the end of the period, the process had started well before the First World War, at least for the majority of LA&C countries. These points are developed through a gravity model applied to the bilateral coal trade. The importance of the market supplier share is addressed through cluster methodologies.

Influence of RF power on the properties of sputtered ZnO:Al thin films

Transparent conducting, aluminium doped zinc oxide thin films (ZnO:Al) were deposited by radio frequency (RF) magnetron sputtering. The RF power was varied from 60 to 350Wwhereas the substrate temperature was kept at 160 °C. The structural, electrical and optical properties of the as-deposited films were found to be influenced by the deposition power. The X-ray diffraction analysis showed that all the films have a strong preferred orientation along the [001] direction. The crystallite size was varied from 14 to 36 nm, however no significant change was observed in the case of lattice constant. The optical band gap varied in the range 3.44-3.58 eV. The lowest resistivity of 1.2×10 -3Vcm was shown by the films deposited at 250 W. The mobility of the films was found to increase with the deposition power.

Transparent conducting thin films by the co-sputtering of ZnO-ITO targets

Transparent and conductive Zn-In-Sn-O (ZITO) amorphous thin films have been deposited at room temperature by the rf magnetron co-sputtering of ITO and ZnO targets. Co-sputtering gives the possibility to deposit multicomponent oxide thin films with different compositions by varying the power to one of the targets. In order to make ZITO films with different Zn content, a constant rf power of 50 W was used for the ITO target, where as the rf power to ZnO target was varied from 25 W to 150 W. The as deposited films showed an increase in Zn content ratio from 17 to 67 % as the power to ZnO target was increased from 25 to 150 W. The structural, electrical and optical properties of the as deposited films are reported. The films showed an average transmittance over 80% in the visible wavelength range. The electrical resistivity and optical band gap of the ZITO films were found to depend on the Zn content in the film. The ZITO films deposited at room temperature with lower Zn content ratios showed better optical transmission and electrical properties compared to ITO film.