Magnetic properties and geochemistry in DSDP Holes 69-504B an d 69-505B

More than 60 basalt samples from two Deep Sea Drilling Project holes on the Costa Rica Rift were studied for magnetic properties and were found to have no properties significantly different from other DSDP basalts. Opaque mineralogical and thermomagnetic properties of these samples, however, to some extent show differences from normal submarine basalts; a new type of thermomagnetic curve and wide range of chemical compositions were recognized. Oxidized samples possibly containing incipient ilmenite exsolution lamellae were reduced and re-equilibrated during heating. The Curie temperatures of the re-equilibrated titanomagnetites are interpreted to be those of the original crystallized phase before oxidation.

Paleomagneitc of early Cretaceous sediments from the western Central Atlantic

Drilling at Sites 534 and 603 of the Deep Sea Drilling Project recovered thick sections of Berriasian through Aptian white limestones to dark gray marls, interbedded with claystone and clastic turbidites. Progressive thermal demagnetization removed a normal-polarity overprint carried by goethite and/or pyrrhotite. The resulting characteristic magnetization is carried predominantly by magnetite. Directions and reliability of characteristic magnetization of each sample were computed by using least squares line-fits of magnetization vectors. The corrected true mean inclinations of the sites suggest that the western North Atlantic underwent approximately 6° of steady southward motion between the Berriasian and Aptian stages. The patterns of magnetic polarity of the two sites, when plotted on stratigraphic columns of the pelagic sediments without turbidite beds, display a fairly consistent magnetostratigraphy through most of the Hauterivian-Barremian interval, using dinoflagellate and nannofossil events and facies changes in pelagic sediment as controls on the correlations. The composite magnetostratigraphy appears to include most of the features of the M-sequence block model of magnetic anomalies from Ml to Ml ON (Barremian-Hauterivian) and from M16 to M23 (Berriasian-Tithonian). The Valanginian magnetostratigraphy of the sites does not exhibit reversed polarity intervals corresponding to Ml 1 to M13 of the M-sequence model; this may be the result of poor magnetization, of a major unrecognized hiatus in the early to middle Valanginian in the western North Atlantic, or of an error in the standard block model. Based on these tentative polarity-zone correlations, the Hauterivian/Barremian boundary occurs in or near the reversed-polarity Chron M7 or M5, depending upon whether the dinoflagellate or nannofossil zonation, respectively, is used; the Valanginian/Hauterivian boundary, as defined by the dinoflagellate zonation, is near reversed-polarity Chron M10N.

Geochemical data and magnetic measurements of IODP Expedition 308, Hole U1319A from the Gulf of Mexico

A 160 m mostly turbiditic late Pleistocene sediment sequence (IODP Expedition 308, Hole U1319A) from the Brazos-Trinity intraslope basin system off Texas was investigated with paleo- and rock magnetic methods. Numerous layers depleted in iron oxides and enriched by the ferrimagnetic iron-sulfide mineral greigite (Fe3S4) were detected by diagnostic magnetic properties. From the distribution of these layers, their stratigraphic context and the present geochemical zonation, we develop two conceptual reaction models of greigite formation in non-steady depositional environments. The "sulfidization model" predicts single or twin greigite layers by incomplete transformation of iron monosulfides with polysulfides around the sulfate methane transition (SMT). The "oxidation model" explains greigite formation by partial oxidation of iron monosulfides near the iron redox boundary during periods of downward shifting oxidation fronts. The stratigraphic record provides evidence that both these greigite formation processes act here at typical depths of about 12-14 mbsf and 3-4 mbsf. Numerous "fossil" greigite layers most likely preserved by rapid upward shifts of the redox zonation denote past SMT and sea floor positions characterized by stagnant hemipelagic sedimentation conditions. Six diagenetic stages from a pristine magnetite-dominated to a fully greigite-dominated magnetic mineralogy were differentiated by combination of various hysteresis and remanence parameters.

Chemical analysis of various geological samples from Northern Victoria Land, Antarctica

This paper reports the results of a preliminary palaeomagnetic investigation of the Admiralty Intrusives complex of northern Victoria Land, Antarctica. The samples were collected at Mt. Supernal and Inferno Peak, two pinions mainly formed of granodiorite and minor tonalite and emplaced at ab. 350 Ma at a high crustal level, as shown by amphibole geobarometric data and occurrence of miarolitic cavities. Microprobe and isothermal remanence analyses showed that magnetite. characterized by low coercivity and Curic point in the range 550-570 °C is the only primary ferromagnetic mineral. Stepwise thermaldemagnetization succeeded in isolatingamagnetization component. stable up to 530 °C. The virtual geomagnetic poles (VGPs) of the two plutons are different. That of Inferno Peak is consistent with the Australian palaeopoles of late Devonian-early Carboniferous age, whereas the location of the Mt. Supernal VGP probably results from the tectonic activity which affected the Ross Sea region during the Cenozoic.

Magnetic observation of ODP Site 152-919 in the Irminger Basin, North Atlantic

Component natural remanent magnetizations derived from u-channel and 1-qcm discrete samples from ODP Site 919 (Irminger Basin) indicate the existence of four intervals of negative inclinations in the upper Brunhes Chronozone. According to the age model based on planktic oxygen isotope data, these "excursional" intervals occur in sediments deposited during the following time intervals: 32-34 ka, 39-41 ka, 180-188 ka and 205-225 ka. These time intervals correspond to polarity excursions detected elsewhere, known as Mono Lake, Laschamp, Iceland Basin and Pringle Falls. The isotope-based age model is supported by the normalized remanence (paleointensity) record that can be correlated to other calibrated paleointensity records for the 0-500 ka interval, such as that from ODP Site 983. For the intervals associated with the Mono Lake and Laschamp excursions, virtual geomagnetic poles (VGPs) reach equatorial latitudes and mid-southerly latitudes, respectively. For intervals associated with the Iceland Basin and Pringle Falls excursions, repeated excursions of VGPs to high southerly latitudes indicate rapid directional swings rather than a single short-lived polarity reversal. The directional instability associated with polarity excursions is not often recorded, probably due to smoothing of the sedimentary record by the process of detrital remanence (DRM) acquisition.

Rock magnetic properties and radiocarbon dates of samples obtained on Ile de Possession, South Indian Ocean

A 6200 year old peat sequence, cored in a volcanic crater on the sub-Antarctic Ile de la Possession (Iles Crozet), has been investigated, based on a multi-proxy approach. The methods applied are macrobotanical (mosses, seeds and fruits) and diatom analyses, complemented by geochemical (Rock-Eval6) and rock magnetic measurements. The chronology of the core is based on 5 radiocarbon dates. When combining all the proxy data the following changes could be inferred. From the onset of the peat formation (6200 cal yr BP) until ca. 5550 cal yr BP, biological production was high and climatic conditions must have been relatively warm. At ca. 5550 cal yr BP a shift to low biological production occurred, lasting until ca. 4600 cal yr BP. During this period the organic matter is well preserved, pointing to a cold and/or wet environment. At ca. 4600 cal yr BP, biological production increased again. From ca. 4600 cal yr BP until ca. 4100 cal yr BP a 'hollow and hummock' micro topography developed at the peat surface, resulting in the presence of a mixture of wetter and drier species in the macrobotanical record. After ca. 4100 cal yr BP, the wet species disappear and a generally drier, acidic bog came into existence. A major shift in all the proxy data is observed at ca. 2800 cal yr BP, pointing to wetter and especially windier climatic conditions on the island probably caused by an intensification and/or latitudinal shift of the southern westerly belt. Caused by a stronger wind regime, erosion of the peat surface occurred at that time and a lake was formed in the peat deposits of the crater, which is still present today.

Chemical composition, age, and magnetic parameters of igneous rocks from the Franz Josef Land

A combined study of magnetic parameters of basalt and andesite samples has been carried out in the framework of geological investigations of the Franz Josef Land. This study has included determination of coercivity, saturation magnetization, Curie points, natural remanent magnetization (NRM), and magnetic susceptibility as well as examination of ferromagnetic minerals with a microscope. Data on chemical composition of the rocks have been obtained for all the samples, and radiological ages have been determined for the majority of the rocks. Thermomagnetic curves of the samples have been subdivided into four types depending on composition of ferromagnetic NRM carriers. Data showing multiple changes in the predominant composition of the igneous rocks have been obtained. Each stage of magmatism is characterized by a specific type of the ferromagnetic component in the rocks and, therefore, magnetomineralogical investigations can be used for differentiation and correlation of the igneous rocks.

A magneto-mineralogical study of basalt at DSDP Leg 73 Holes

The basalts in Holes 519A, 522B, and 524 were studied for intensity of natural remanent magnetization, magnetic hysteresis, magnetic susceptibility, stability of isothermal remanence, and thermomagnetic behavior. Some of these properties are sensitive to both the composition and the microstructure of the magnetic minerals, others to composition only. Thus it is possible to separate the two effects and to trace the variation of effective magnetic grain size and degree of alteration within a lithologic unit or over a yet larger distance or time interval. The flow in Hole 519A is highly maghemitized at the top, the degree of maghemitization decreasing with depth in the flow. Effective grain size increases with increasing depth. Electron microprobe analysis of the titanomaghemite grains in these samples provides no support for the leaching out of iron during alteration. The pillows and flows in Hole 522B are distributed among a number of cooling units, and no systematic downhole variations are apparent. The inferred magneto-petrology is consistent with the cooling and alteration history that might be expected within the units. The upper and lower sills in Hole 524 are more uniform and have a larger concentration of well-developed magnetic mineral grains than the pillows and flows in Holes 519A and 522B. Maghemitization appears to have developed from the boundaries of the sills that are in contact with the sediments between the sills.

Susceptibility, magnetization and S-ratio of ODP Sites 201-1225 and 201-1227

Samples were collected at Sites 1225 and 1227 to investigate the occurrence of fine-grained, biogenic magnetic particles (magnetosomes). Several magnetic methods, including anhysteretic remanent magnetization and isothermal remanent magnetization, were used to characterize the main magnetic carriers in the samples. Extracts were made to isolate the fine-grained fraction, which was then examined under a transmission electron microscope. Grains with the unique characteristics of magnetosomes were found in samples from regions in the core with both high and low concentrations of magnetic minerals. This suggests they have the potential to be a persistent proxy of paleoredox conditions.