黄土塬区三种豆科牧草的竞争生长

通过田间试验研究了沙打旺、紫花苜蓿和达乌里胡枝子3种豆科牧草在黄土旱塬以不同密度单播、混播时的竞争生长能力及水分利用效率。单播时苜蓿生长次年3个密度的生产力分别为15349kg·hm-2、20582kg·hm-2、21531kg·hm-2,沙打旺和胡枝子3个密度的生产力分别为7979kg·hm-2、16 440 kg·hm-2、21055kg·hm-2和2412kg·hm-2、5270kg·hm-2、7102kg·hm-2。混播草地生产力以苜蓿+胡枝子最高(平均19227kg·hm-2),沙打旺与胡枝子混播的生产力最低(平均11977kg·hm-2)。和生产力较高的参混种苜蓿、沙打旺单播相比,苜蓿与沙打旺混播及沙打旺与胡枝子混播的生产力在3种密度下均有不同程度的降低。苜蓿主根下扎深度2m,0~60cm根系占总根量的66%,沙打旺和胡枝子根系最大下扎深度分别为1.8 m和1.5m,0~60cm根系占总根量比例分别是80%、91%。3种牧草中苜蓿的平均水分利用效率最高,为25.75kg·mm-1·hm-2,胡枝子最低为7.71kg·mm-1·hm-2,沙打旺居中。苜蓿群体种内个体间竞争强度高于沙打旺和胡枝子。结果...

水土保持林土壤改良效益评价研究

森林效益评价是目前林业研究的热点 ,也是难点问题。通过评价水土保持林土壤改良效益 ,对效益评价的方法和思路进行了探索。指出水土保持林土壤改良效益指标体系的总目标层为效益评价综合指数 ,准则层包括土壤肥力、抗蚀性能和抗冲性能 3个方面 ,指标层由水稳性团聚体含量、有机质含量、土壤酶活性、p H值、平均重量直径、团聚度、分散率、土壤硬度和渗透系数构成。在计算效益评价综合指数时 ,首先要对各项指标的实测数据进行处理 ,使之转化为无量纲的标度值 ;然后可根据层次单排序的权值分步进行计算 ,也可按照层次总排序的权值直接计算 ,获得效益评价综合指数。为消除立地因子的影响 ,要对效益评价综合指数进行校正 ,校正后的综合指数可以反映出不同水土保持林土壤改良效益的好坏。

污泥草地利用的初步研究

对经堆肥处理的污泥有机肥培育结缕草(Zoysiajaponica)的初步研究表明,在污泥符合农用标准条件下,以Cd为施污泥肥量的限制因子,在施污泥有机肥45t·hm-2(干重)以下时,在微酸性土壤(pH<6.5),土壤中Cd含量低于Cd的土壤环境质量标准(0.3mg·kg-1),地下水NO3--N含量低于地面水Ⅰ、Ⅱ类标准(NO3--N10mg·kg-1,P0.1mg·kg-1).土壤中有机质、速效N、总N、总P分别比对照增加16%、78%、61和140%,结缕草生物量比对照区高1倍.可以认为,污泥草地利用是一种良好途径.

Heavy Metals in Soil and Crops of an Intensively Farmed Area: A Case Study in Yucheng City, Shandong Province, China

lThe study was supported by the Knowledge Innovation Foundation of the institute of Geographical Sciences and Natural Resource, Chinese Academy of Sciences (Grant No. 200906002) and Key Directional Project of Knowledge Innovation of Chinese Academy of Sciences (Grant No. KSCX2-YW-N-46-01). The authors would like to thank to Luke Driskell for his kind help and hard work on English language polishing of the article.

The microstructure and mechanical properties of Mg-3Al-3RE alloys

The Mg-3Al-3RE alloys (RE, the cerium-rich or the yttrium-rich misch metal) were smelted in a resistance furnace under the protective flux from the Mg-RE master alloys and pure magnesium ingots. The microstructure and mechanical properties of samples prepared by steel mould casting method were investigated.

One-step preparation of hybrid materials of polyacrylamide networks and gold nanoparticles

Hybrid materials of polyacrylamide networks and gold nanoparticles were prepared by directly heating an aqueous solution containing HAuCl4, acrylamide, N,N'-methylenebisacrylamide, and sodium sulfite (Na2SO3). Acrylamide, N,N'-methylenebisacrylamide, and Na2SO3 were used as monomers, crosslinking agent, and initiator, respectively.

The gadolinium complexes with polyoxometalates as potential MRI contrast agents

The two gadolinium (Gd) polyoxometalates, K-15[Gd(BW11O39)(2)] [Gd(BW11)(2)] and K-17[Gd(CuW11O39)(2)] [Gd(CuW11)(2)] have been evaluated by in vivo and in vitro experiments as the candidates of potential tissue-specific magnetic resonance imaging (MRI) contrast agents. T-1 relaxivities of 17.12 mM(-1) . s(-1) for Gd(BW11)(2) and 19.95 mM(-1) . s(-1) for Gd(CuW11)(2) (400MHz, 25 degrees C) were much higher than that of the commercial MRI contrast agent (GdDTPA). Their relaxivities in bovine serum albumin and human serum transferrin solutions were also reported. After administration of Gd(BW11)(2) and Gd(CuW11)(2) to Wistar rats, MRI showed longer and remarkable enhancement in rat liver and favorable renal excretion capability. The signal intensity increased by 37.63 +/- 3.45% for the liver during the whole imaging period (100 min) and by 61.47 +/- 10.03% for kidney within 5-40 min after injection at 40 +/- 1-mu mol . kg(-1) dose for Gd(CuW11)(2), and Gd(BW11)(2) induced 50.44 +/- 3.51% enhancement in the liver in 5-50-min range and 61.47 +/- 10.03% enhancement for kidney within 5-40 min after injection at 39 +/- 4 mu mol . kg(-1) dose. In vitro and in vivo study showed that Gd(BW11)(2) and Gd(CuW11)(2) are favorable candidates as tissue-specific contrast agents for MRI.

Preparation of In2O3 ceramic nanofibers by electrospinning and their optical properties

Electrospinning was employed to fabricate polymer-ceramic composite fibers from solutions containing polyvinyl pyrrolidone (PVP) and In(NO3)(3)center dot 4(1)/2H2O. Upon firing the composite fibers at 800 degrees C, In2O3 fibers with diameters ranging from 200 to 400 nm were synthesized. This indium oxide calcined at 800 degrees C is a body-centered cubic cell. The photoluminescence (PL) properties of the as-formed In2O3 nanofibers were investigated. The In2O3 nanofibers show a strong PL emission in the ultraviolet (UV) region under shorter UV light irradiation.

聚丙烯/多壁碳纳米管复合材料的热性能和流变性能

用熔融共混法制备了聚丙烯多壁碳纳米管(PP MWNTs)复合材料,TGA研究表明在氮气气氛下碳纳米管显著增加了聚丙烯基体的热稳定性.3wt%MWNTs可使PP热分解起始温度提高44℃.非等温结晶研究表明MWNTs对PP基体的结晶行为没有明显的影响.流变测试结果表明PP MWNTs复合材料的储能模量G′和损耗模量G″随着MWNTs含量增加逐渐增大.1wt%MWNTs的PP聚合物的零剪切粘度最低,5wt%MWNTs的PP聚合物的零剪切粘度最高,PP和3wt%MWNTs的PP纳米聚合物的零剪切粘度居于二者之间,随着频率的增加,剪切稀化作用越来越明显,呈现出假塑性流体行为.含5wt%MWNTs的PP复合材料的体积和表面电阻率与纯PP相比分别下降了9个和4个数量级,表明少量的MWNTs可以显著改变PP的电学性能.

Photochemical synthesis, characterization and X-ray crystal structure of dodecamolybdophosphate tetrabutylammonium heteropoly blue (Bu4N)(4)[PMo12O40]center dot 2DMF center dot H2O

In this paper, we will report the preparation of a mixed-valence polyoxometalate compound (Bu4N)(4)[PMo12O40].2DMF.H2O (TBA = tetrabutylammonium; DMF = N,N-dimethyl formamide). The title compound has been photochemically synthesized and characterized by using elemental analysis, IR, solid diffusion reflectance electronic spectra, ESR spectra, XPS, CV and X-ray single-crystal analysis. The crystal lographic data are as follows: monoclinic, P2(1)/c, a = 14.124(3), b = 17.481(4), c = 22.744(5) Angstrom, beta = 101.66(3)degrees, V = 5500(2) Angstrom(3), C70H160Mo12N6O43P, M-r = 2956.29, Z = 2, D-c = 1.785 g/cm(3), F(000) = 2970 and mu(MoKalpha) = 1.412 mm(-1). The structure has been refined to R = 0.0638 and wR = 0.1975 by full-matrix least-squares methods. The title compound is composed of four tetrabutylammonium cations, one [(PMoMo11O40)-Mo-V](4-) heteropoly anion, two N,N-dimethyl formamide and one H2O molecule.

An evaluation of gadolinium polyoxornetalates as possible MRI contrast agent

Two gadolinium polyoxometalates, K9GdW10O36 and K-11 [Gd(PW11O39)(2)], have been evaluated both in vivo and in vitro as candidates for tissue-specific MRI contrast agents. T-1-relaxivities of 6.89 mM(-1) . s(-1) for K9GdW10O36 and 5.27 mM(-1) . s(-1) for K-11[Gd(PW11O39)(2)] are slightly higher than that of the commercial MRI contrast agent (Gd-DTPA). Both compounds bind with bovine serum albumin and human serum transferrin and favorable liver-specific contrast enhancement in in vivo MRI with Sprague-Dawley rats after i.v. administration has been demonstrated. Imaging studies demonstrate that the two agents have a long residence time, showing MR signal enhancement in the liver for more than 40 min, longer than commercially available contrast agents. In vivo and in vitro assays showed that GdW10 and Gd(PW11)(2) are promising liver-specific MRI contrast agents and GdW10 may be used in the diagnosis of the pathological state. However, with the higher acute toxicity, the two gadolinium polyoxometalates need to be modified and studied further before clinical use.

Studies of electrochemical quantized capacitance charging of surface ensembles of silver nanoparticles

CTAB-stabilized silver nanoparticles were synthesized by NaBH4 reduction. The as-prepared nanoparticles can be self-assembled on 3-mercaptopropionic acid (MPA) modified gold electrode, which was supported strongly by XPS measurements. Exceptional long-term stability of the as-prepared colloidal silver aqueous solution and the desorption of silver nanoparticle ensemble on MPA after alcohol rinsing proved that these CTAB molecules adsorbed on silver core formed interdigitated bilayer structure. DPV and differential capacitance measurements were performed to characterize the as-prepared silver nanoparticle ensemble. and the interesting quantized capacitance charging behaviors were observed.