Pleistocene chronology of sediments from the Lomonosov Ridge

Despite its importance in the global climate system, age-calibrated marine geologic records reflecting the evolution of glacial cycles through the Pleistocene are largely absent from the central Arctic Ocean. This is especially true for sediments older than 200 ka. Three sites cored during the Integrated Ocean Drilling Program's Expedition 302, the Arctic Coring Expedition (ACEX), provide a 27 m continuous sedimentary section from the Lomonosov Ridge in the central Arctic Ocean. Two key biostratigraphic datums and constraints from the magnetic inclination data are used to anchor the chronology of these sediments back to the base of the Cobb Mountain subchron (1215 ka). Beyond 1215 ka, two best fitting geomagnetic models are used to investigate the nature of cyclostratigraphic change. Within this chronology we show that bulk and mineral magnetic properties of the sediments vary on predicted Milankovitch frequencies. These cyclic variations record "glacial" and "interglacial" modes of sediment deposition on the Lomonosov Ridge as evident in studies of ice-rafted debris and stable isotopic and faunal assemblages for the last two glacial cycles and were used to tune the age model. Potential errors, which largely arise from uncertainties in the nature of downhole paleomagnetic variability, and the choice of a tuning target are handled by defining an error envelope that is based on the best fitting cyclostratigraphic and geomagnetic solutions.

Grain-size distribution, sedimentation rate and x-ray fluorescence data of four sediment cores off the Senegal River estuary

Fine-grained sediment depocenters on continental shelves are of increased scientific interest since they record environmental changes sensitively. A north-south elongated mud depocenter extends along the Senegalese coast in mid-shelf position. Shallow-acoustic profiling was carried out to determine extent, geometry and internal structures of this sedimentary body. In addition, four sediment cores were retrieved with the main aim to identify how paleoclimatic signals and coastal changes have controlled the formation of this mud depocenter. A general paleoclimatic pattern in terms of fluvial input appears to be recorded in this depositional archive. Intervals characterized by high terrigenous input, high sedimentation rates and fine grain sizes occur roughly contemporaneously in all cores and are interpreted as corresponding to intensified river discharge related to more humid conditions in the hinterland. From 2750 to 1900 and from 1000 to 700 cal a BP, wetter conditions are recorded off Senegal, an observation which is in accordance with other records from NW-Africa. Nevertheless, the three employed proxies (sedimentation rate, grain size and elemental distribution) do not always display consistent inter-core patterns. Major differences between the individual core records are attributed to sediment remobilization which was linked to local hydrographic variations as well as reorganizations of the coastal system. The Senegal mud belt is a layered inhomogeneous sedimentary body deposited on an irregular erosive surface. Early Holocene deceleration in the rate of the sea-level rise could have enabled initial mud deposition on the shelf. These favorable conditions for mud deposition occur coevally with a humid period over NW-Africa, thus, high river discharge. Sedimentation started preferentially in the northern areas of the mud belt. During mid-Holocene, a marine incursion led to the formation of an embayment. Afterwards, sedimentation in the north was interrupted in association with a remarkable southward shift in the location of the active depocenter as it is reflected by the sedimentary architecture and confirmed by radiocarbon dates. These sub-recent shifts in depocenters location are caused by migrations of the Senegal River mouth. During late Holocene times, the weakening of river discharge allowed the longshore currents to build up a chain of beach barriers which have forced the river mouth to shift southwards.

The O2, pH and Ca2+ Microenvironment of Benthic Foraminifera in a High CO2 World

Ocean acidification (OA) can have adverse effects on marine calcifiers. Yet, phototrophic marine calcifiers elevate their external oxygen and pH microenvironment in daylight, through the uptake of dissolved inorganic carbon (DIC) by photosynthesis. We studied to which extent pH elevation within their microenvironments in daylight can counteract ambient seawater pH reductions, i.e. OA conditions. We measured the O2 and pH microenvironment of four photosymbiotic and two symbiont-free benthic tropical foraminiferal species at three different OA treatments (~432, 1141 and 2151 µatm pCO2). The O2 concentration difference between the seawater and the test surface (delta O2) was taken as a measure for the photosynthetic rate. Our results showed that O2 and pH levels were significantly higher on photosymbiotic foraminiferal surfaces in light than in dark conditions, and than on surfaces of symbiont-free foraminifera. Rates of photosynthesis at saturated light conditions did not change significantly between OA treatments (except in individuals that exhibited symbiont loss, i.e. bleaching, at elevated pCO2). The pH at the cell surface decreased during incubations at elevated pCO2, also during light incubations. Photosynthesis increased the surface pH but this increase was insufficient to compensate for ambient seawater pH decreases. We thus conclude that photosynthesis does only partly protect symbiont bearing foraminifera against OA.

(Table 1) Reduced compounds of sulfur in waters of the Baltic Sea

Concentrations of sulfide, S°, and thiosulfate were determined in waters of the Baltic Sea. Microquantities of these compounds were observed in oxic waters. Concentration levels of reduced sulfur compounds in Baltic oxic waters were very close to levels of the Black Sea oxic zone. Thiosulfate and S° were predominate compounds in oxic water whereas sulfide was a predominant compound of Baltic waters high in hydrogen sulfide. Conclusion was made that during sedimentation in oxic waters anaerobic microorganisms along with aerobic bacteria take part in mineralization of organic matter. They exist on surfaces and in microniches of particles of organic detritus.

Dust fluxes and iron fertilization in Holocene and Last Glacial Maximum climates

Mineral dust aerosols play a major role in present and past climates. To date, we rely on climate models for estimates of dust fluxes to calculate the impact of airborne micronutrients on biogeochemical cycles. Here we provide a new global dust flux data set for Holocene and Last Glacial Maximum (LGM) conditions based on observational data. A comparison with dust flux simulations highlights regional differences between observations and models. By forcing a biogeochemical model with our new data set and using this model's results to guide a millennial-scale Earth System Model simulation, we calculate the impact of enhanced glacial oceanic iron deposition on the LGM-Holocene carbon cycle. On centennial timescales, the higher LGM dust deposition results in a weak reduction of <10?ppm in atmospheric CO2 due to enhanced efficiency of the biological pump. This is followed by a further ~10?ppm reduction over millennial timescales due to greater carbon burial and carbonate compensation.

Biogenic opal and carbonate concentration in late Neogene sediments of ODP Site 114-704

A preliminary composite depth section was generated for Site 704 by splicing Holes 704A and 704B together over the interval 0-350 mbsf (0-9 m.y.). High-resolution carbonate and opal data from the cores were correlated with the calcium and silicon signals from the GST logging run in Hole 704B to identify missing and disturbed intervals in the cores. Paleomagnetic and biostratigraphic age boundaries were then transferred to the composite depth records to obtain an age model, and sedimentation rates were calculated by linear interpolation between datums. Algorithms relating measured dry-bulk density to carbonate content and depth were generated to produce predicted values of density for every sample. Accumulation rates of bulk, carbonate, opal, and terrigenous sediment components were then computed to generate a record of sediment deposition on the Meteor Rise that has a resolution of better than 200,000 yr for the period from 8.6 to 1.0 m.y. From 8.6 to 2.5 m.y., bulk-accumulation rates on the Meteor Rise averaged less than 2 g/cm**2/1000 yr and were dominated by carbonate deposition. The first significant opal deposition (6.0 m.y.) punctuated a brief (less than 0.6 Ma) approach of the Polar Front Zone (PFZ) northward that heralded a period of increasing severity of periodic carbonate dissolution events (terrigenous maxima) that abruptly terminated at 4.8 m.y. (base of the Thvera Subchron), synchronous with the reflooding of the Mediterranean after the Messinian salinity crisis. From 4.8 to 2.5 m.y., carbonate again dominated deposition, and the PFZ was far south except during brief northward excursions bracketing 4.2-3.9, 3.3-2.9, and 2.8-2.7 m.y. At 2.5 m.y., all components of bulk-accumulation rates increased dramatically (up to 15 g/cm2/1000 yr), and by 2.4 m.y., a pattern of alternating, high-amplitude carbonate and opal cyclicity marked the initiation of rapid glacial to interglaci·l swings in the position of the PFZ, synchronous with the "onset" of major Northern Hemisphere glaciation. Both mass-accumulation rates and the amplitude of the cycles decreased by about 2 m.y., but opal accumulation rates remained high up through the base of the Jaramillo (0.98 m.y.). From 1.9 to 1 m.y., the record is characterized by moderate amplitude fluctuations in carbonate and opal. This record of opal accumulation rates is interpreted as a long-term "Polar Front Indicator" that monitors the advance and retreat of the opal-rich PFZ northward (southward) toward (away from) the Meteor Rise in the subantarctic sector of the South Atlantic Ocean. The timing of PFZ migrations in the subantarctic South Atlantic Ocean is remarkably similar to Pliocene-Pleistocene climate records deduced from benthic oxygen isotope records in the North Atlantic Ocean (Raymo et al., 1989, doi:10.1029/PA004i004p00413; Ruddiman et al., 1989, doi:10.1029/PA004i004p00353). These include northward migrations during "cold" intervals containing strong glacial isotope stages (2.4-2.3, 2.1-2.0, 1.95-1.55, 1.45-1.30 m.y. and at about 1.13 and 1.09 m.y.) and southward migrations during "warm" intervals containing weak glacial and/or strong interglacial stages (2.45-2.40, 2.30-2.10, 2.00-1.95, 1.52-1.45, 1.30-1.18, 1.11, and 1.06-0.93 m.y.). Although our preliminary composite record is not continuous (some stages are obviously missing), there is hope that future work will identify these missing intervals in the as yet incomplete Hole 704B and will extend this high-resolution Southern Hemisphere climate record back to 8.6 m.y.

Topographic model of Greenland (elevation lines in PanMap and ASCII format)

In this paper, a new high-resolution elevation model of Greenland, including the ice sheet as well as the ice free regions, is presented. It is the first published full coverage model, computed with an average resolution of 2 km and providing an unprecedented degree of detail. The topography is modeled from a wide selection of data sources, including satellite radar altimetry from Geosat and ERS 1, airborne radar altimetry and airborne laser altimetry over the ice sheet, and photogrammetric and manual map scannings in the ice free region. The ice sheet model accuracy is evaluated by omitting airborne laser data from the analysis and treating them as ground truth observations. The mean accuracy of the ice sheet elevations is estimated to be 12-13 m, and it is found that on surfaces of a slope between 0.2° and 0.8°, corresponding to approximately 50% of the ice sheet, the model presents a 40% improvement over models based on satellite altimetry alone. On coastal bedrock, the model is compared with stereo triangulated reference points, and it is found that the model accuracy is of the order of 25-35 m in areas covered by stereo photogrammetry scannings and between 200 and 250 m elsewhere.