Tratamento de águas residuárias de suinocultura em reatores anaeróbios horizontais de alta taxa seguidos de filtro biológico percolador

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Análise da viabilidade do uso de biogás gerado a partir de dejetos bovinos em microturbinas para fins de geração, cogeração e trigeração de energia

The use of digesters has become an important alternative for the proper disposal of organic agricultural wastes, serving as a solution to some environmental and health problems. Furthermore, the process of digestion provides commercially valuable by products such as biogas and bio fertilizer. The generation of biogas from agricultural waste, and its use in power generation systems has aroused great interest in rural areas because it enables supply in whole or in large part the energy demand of ownership by reducing production costs. The advent of technology has brought new forms of energy conversion of biogas, as the use of micro turbines specifies to be fuelled with biogas derived from the decomposition of organic matter in digesters, since it has a low level of methane in its composition, and high degree of impurities such as hydrogen sulphide, which are harmful to equipment and reduce the calorific value of biogas. The use of micro turbines behind other advantages like low emissions, great fuel flexibility and low maintenance. This paper presents an analysis of the feasibility of using biogas generated from cattle manure in micro turbines to generate electricity. Behind also an assessment of the energy potential that each animal has on various uses of biogas, and forms of energy recovery from the exhaust gases of the micro turbine. Also conducts an evaluation of the energy savings that the use of biogas aggregates properties.

Fibra da cana-de-açúcar para suínos pesados em restrição alimentar qualitativa

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Avaliação energética do ciclo de refrigeração por absorção utilizando biogás de aterros sanitários e gás natural

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Inclusão de cana-de-açúcar triturada em biodigestores abastecidos com dejetos de bovinos de corte confinado

The objective of this study was toevaluatethe effect of the co-digestion of triturated sugarcane with beef cattlerfeddlotmanure in continuous digestorsin the amount and quality of biogas and biofertilizer. To do so, the work was divided in three steps. The first and the second part lasted30 days each and evaluated the effect of the additionof 7% of triturated sugarcane in agreement with the followingtreatments:treatment, the digestors were supplied with a mixture of 0,250 kg of manure and 1,750 kg of water ;treatment 2, the digestors were supplied with a mixture of 0,250 kg of manure, 1,610 kg of water, and 0,140 kg of triturated sugarcane. To The third period lasted 30 days and evaluated the effect of adding 3.5% of sugarcane crushed. The data analyses was performed with randomized designusing SAS®program with level of significance of 5%. The digesters with sugarcane produced in the first period respectively 0.79, 0.0127, and 0.102 m3of total production, of biogas production per kilogram of substrate, and of total production per kilogram of manure versus 0.5, 0.0081, and 0.065 m3from the control treatment, respectively..In the thirdperiod,each variable had a total production of 0.76, 0.123, and 0.98 m3and the control treatment yielded 0.51, 0.065, and 0.0082 m3.In the second period,the total production per kilogram of solidand of volatile solids added were higher in the digesters without sugarcane (0.0093 and 0.438 m3) when compared to the digesters that had additionof 7% of cane(0.271 and 0.336 m3).

Co-digestão anaeróbia de dejetos de suínos, níveis de inclusão de óleo de descarte e microrganismos lipolíticos redução do impacto ambiental

The objective of this work for evaluating the potential of biogas and methane productions and still and reductions in levels of total solids (TS), volatile solids (VS) and neutral detergent fiber (NDF) of the co-digestion anaerobic digestion in digesters fed with swine manure plus disposal of oil and lyophilized microorganisms. For assay development substrates were prepared containing 4% TS, consisting of swine manure, disposal oil (the proportions 8, 10 and 12% oil content in relation to the substrate TS), lyophilized microorganisms (Biol-2000 ® - concentrations of 10 g/m3 and 15 g/m3 ), water for dilution of this waste and inoculum for batch digesters supply. There was no significant difference with respect to reductions in TS, VS and NDF constituents, providing very significant reductions in average 54.14; 62.79 and 49.16% respectively. Regarding the potential of biogas production, the highest yields occurred in digesters supplied with 10% oil and 15 g/m3 of Biol®, being 0.43 and 0.54 L of biogas per kg of TS and VS added, respectively, similar results were found when assessed the potential for methane production, with higher values (0.22 and 0.27 L of methane per kg of TS added and VS, respectively) obitidos the same treatment. The inclusion of 15 g/m3 in Biol® substrate composition containing swine manure and 10% of oil improves the yields of biogas and methane.

Addition of lipolytic enzyme in anaerobic co-digestion of swine manure and inclusion levels of waste vegetable oil

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Viabilidade econômica do uso do biogás proveniente da suinocultura em substituição a fontes externas de energia

The swine culture potentially generates waste with high organic load and pollutants, being responsible for the spread of pathogens, contamination of rivers, groundwater and soils, besides it produces foul odors and emit greenhouse gases. However, the high amount of organic matter, which expresses the amount of pollutant load, reflects the energetic potential of these wastes used as raw material in biogas generation through technology of digesters. The properly use of theses digesters provides the production of clean energy and promotes the conservation of the environment. The economic viability of the implantation of an Indian model digester on a small swine farm was verified based on the value from initial investments of deployment, maintenance costs, depreciation, and on the interest and revenues arising from the system. Besides, the amount of biogas produced daily and the average consumption of biogas by the most common used devices such as refrigerator, stove, water heater, and generator of electricity was calculated.. For a backdrop of 10 years, the results of economic indicators NPV of BRL 57,598.95, IRR of 48.38%, Simple Payback of 2.06 years, and Discounted Payback of 2.3 years, demonstrated a favorable outlook for the use of this technology, with the possibility to generate economic, social and environmental benefits.

Avaliação técnica e econômica de um biodigestor de fluxo tubular: estudo de caso do modelo implantado na etec "orlando quagliato" em Santa Cruz do Rio Pardo, SP

Pós-graduação em Agronomia (Energia na Agricultura) - FCA

Procedimento para homologação de sistemas ecoeficientes para obtenção de créditos de carbono

This paper deals with the homologation process for obtaining carbon credits through the Clean Development Mechanism (CDM), that regulates the greenhouse gases reductions under the rules of the Kyoto Protocol. The CDM evaluates projects through a project cycle, which begins with the preparation of the Project Design Document (PDD) until the project certification to receive Certified Emission Reductions (CERs), popularly known as carbon credits. This study analyzed the implementation of the system Burner Recorder System for Low Flows of Biogas (QRBBV), developed by Marcelino Junior & Godoy (2009), in an eco-friendly wastewater treatment mini-plant (miniEETERA), built at the site of UNESP - Guaratinguetá SP. The QRBBV system is low cost and high reliability, developed to burn the methane generated at sites of low and variable production of biogas, which is not economically justified their energy recovery. Currently, almost all wastewater generated at the site of the campus is being treated by miniEETERA and, as a result, the biogas originated by this activity is being released into the atmosphere. Therefore, the project activity aims to capture and burn the biogas generated by miniEETERA, reducing the negative effects caused by the methane emissions into the atmosphere and, thus, claim to receive carbon credits. This work aimed to demonstrate the project applicability under CDM through the study and preparation of the PDD, as well as an analysis of the entire project cycle required for homologation. The result of the work obtained an estimate of only 20 CERs per year and proved to be economically unviable for approval through the CDM, since the spending with the approval process would not be compensated with the sale of CERs, mainly due the low carbon price in the world market. From an environmental standpoint, the project is perfectly... (Complete abstract click electronic access below)

Procedimento para homologação de sistemas ecoeficientes para obtenção de créditos de carbono

This paper deals with the homologation process for obtaining carbon credits through the Clean Development Mechanism (CDM), that regulates the greenhouse gases reductions under the rules of the Kyoto Protocol. The CDM evaluates projects through a project cycle, which begins with the preparation of the Project Design Document (PDD) until the project certification to receive Certified Emission Reductions (CERs), popularly known as carbon credits. This study analyzed the implementation of the system Burner Recorder System for Low Flows of Biogas (QRBBV), developed by Marcelino Junior & Godoy (2009), in an eco-friendly wastewater treatment mini-plant (miniEETERA), built at the site of UNESP - Guaratinguetá SP. The QRBBV system is low cost and high reliability, developed to burn the methane generated at sites of low and variable production of biogas, which is not economically justified their energy recovery. Currently, almost all wastewater generated at the site of the campus is being treated by miniEETERA and, as a result, the biogas originated by this activity is being released into the atmosphere. Therefore, the project activity aims to capture and burn the biogas generated by miniEETERA, reducing the negative effects caused by the methane emissions into the atmosphere and, thus, claim to receive carbon credits. This work aimed to demonstrate the project applicability under CDM through the study and preparation of the PDD, as well as an analysis of the entire project cycle required for homologation. The result of the work obtained an estimate of only 20 CERs per year and proved to be economically unviable for approval through the CDM, since the spending with the approval process would not be compensated with the sale of CERs, mainly due the low carbon price in the world market. From an environmental standpoint, the project is perfectly... (Complete abstract click electronic access below)

Occurrence of Methanogenic Archaea in Highly Polluted Sediments of Tropical Santos-So Vicente Estuary (So Paulo, Brazil)

Little is known about the ability of methanogens to grow and produce methane in estuarine environments. In this study, traditional methods for cultivating strictly anaerobic microorganisms were combined with Fluorescence in situ hybridization (FISH) technique to enrich and identify methanogenic Archaea cultures occurring in highly polluted sediments of tropical Santos-So Vicente Estuary (So Paulo, Brazil). Sediment samples were enriched at 30A degrees C under strict anaerobic and halophilic conditions, using a basal medium containing 2% of sodium chloride and amended with glucose, methanol, and sodium salts of acetate, formate and lactate. High methanogenic activity was detected, as evidenced by the biogas containing 11.5 mmol of methane at 20 days of incubation time and methane yield of 0.138-mmol CH(4)/g organic matter/g volatile suspense solids. Cells of methanogenic Archaea were selected by serial dilution in medium amended separately with sodium acetate, sodium formate, or methanol. FISH analysis revealed the presence of Methanobacteriaceae and Methanosarcina sp. cells.

A Two-Stage Aerobic/Anaerobic Denitrifying Horizontal Bioreactor Designed for Treating Ammonium and H2S Simultaneously

A two-stage bioreactor was operated for a period of 140 days in order to develop a post-treatment process based on anaerobic bioxidation of sulfite. This process was designed for simultaneously treating the effluent and biogas of a full-scale UASB reactor, containing significant concentrations of NH4 and H2S, respectively. The system comprised of two horizontal-flow bed-packed reactors operated with different oxygen concentrations. Ammonium present in the effluent was transformed into nitrates in the first aerobic stage. The second anaerobic stage combined the treatment of nitrates in the liquor with the hydrogen sulfide present in the UASB-reactor biogas. Nitrates were consumed with a significant production of sulfate, resulting in a nitrate removal rate of 0.43 kg N m(3) day(-1) and a parts per thousand yen92 % efficiency. Such a removal rate is comparable to those achieved by heterotrophic denitrifying systems. Polymeric forms of sulfur were not detected (elementary sulfur); sulfate was the main product of the sulfide-based denitrifying process. S-sulfate was produced at a rate of about 0.35 kg m(3) day(-1). Sulfur inputs as S-H2S were estimated at about 0.75 kg m(3) day(-1) and Chemical Oxygen Demand (COD) removal rates did not vary significantly during the process. DGGE profiling and 16S rRNA identified Halothiobacillus-like species as the key microorganism supporting this process; such a strain has not yet been previously associated with such bioengineered systems.

Messa a punto di processi biotecnologici per la produzione di biocombustibili da matrici organiche di rifiuto

The bioproduction of materials and energy from renewable sources (industrial biotechnology) is getting more and more interest in order to improve environmental sustainability of chemical industrial processes and to decrease their dependence from oil. Anaerobic digestion of organic waste matrices (agricultural and industrial wastes, organic fraction of municipal wastes, sewage sludges etc.) may play an important role in the implementation of industrial biotechnology being a well developed strategy in the valorization of complex matrices, as it can mineralize them while producing bioenergy in the form of a biogas rich in methane. In this research the potential of anaerobic digestion in the treatment of polluted sewage sludge was studied by developing three set of anaerobic microcosms with sludges differently contaminated by xenobiotic compounds. The effect of different incubating temperatures and of exogenous carbon and vitamine sources was investigated along with the role of the occurring microbial populations in the pollutant degradation activity. So, while confirming the potential of anaerobic digestion for the biomethanization of sewage sludges, this work proved the effectiveness of this technology in the removal of pollutants too. Moreover, since the degradation of lignocellulose appears to be a limiting step in the anaerobic treatment of a wide range of biomass, the possibility of optimizing anaerobic digestion of lignocellulosic substrates was also studied. To this aim a research was carried out at the BOKUUniversity of Natural Resources and Applied Life Sciences, Department for Agrobiotechnology, IFA - Tulln, where mixed cellulolytic cultures were isolated from biogas plants while assessing the metabolic pathway leading to cellulose degradation and verifying their capability to grow on lignocellulose too, proving that on the long term such bacterial cultures could be used as inoculum in order to improve the hydrolysis of lignocellulose in anaerobic digestion plants.

Biometanazione della frazione organica di rifiuti solidi urbani da raccolta indifferenziata mediante codigestione con refluo zootecnico o addizione di solfuro di sodio

Il presente elaborato è stato finalizzato allo sviluppo di un processo di digestione anaerobica della frazione organica dei rifiuti solidi urbani (FORSU oppure, in lingua inglese OFMSW, Organic Fraction of Municipal Solid Waste) provenienti da raccolta indifferenziata e conseguente produzione di biogas da impiegarsi per il recupero energetico. Questo lavoro rientra nell’ambito di un progetto, cofinanziato dalla Regione Emilia Romagna attraverso il Programma Regionale per la Ricerca Industriale, l’Innovazione e il Trasferimento Tecnologico (PRRIITT), sviluppato dal Dipartimento di Chimica Applicata e Scienza dei Materiali (DICASM) dell’Università di Bologna in collaborazione con la Facoltà di Ingegneria dell’Università di Ferrara e con la società Recupera s.r.l. che applicherà il processo nell’impianto pilota realizzato presso il proprio sito di biostabilizzazione e compostaggio ad Ostellato (FE). L’obiettivo è stato la verifica della possibilità di impiegare la frazione organica dei rifiuti indifferenziati per la produzione di biogas, e in particolare di metano, attraverso un processo di digestione anaerobica previo trattamento chimico oppure in codigestione con altri substrati organici facilmente fermentabili. E’ stata inoltre studiata la possibilità di impiego di reattori con biomassa adesa per migliorare la produzione specifica di metano e diminuire la lag phase. Dalla sperimentazione si può concludere che è possibile giungere allo sviluppo di metano dalla purea codigerendola assieme a refluo zootecnico. Per ottenere però produzioni significative la quantità di solidi volatili apportati dal rifiuto non deve superare il 50% dei solidi volatili complessivi. Viceversa, l’addizione di solfuri alla sola purea si è dimostrata ininfluente nel tentativo di sottrarre gli agenti inibitori della metanogenesi. Inoltre, l’impiego di supporti di riempimento lavorando attraverso processi batch sequenziali permette di eliminare, nei cicli successivi al primo, la lag phase dei batteri metanogeni ed incrementare la produzione specifica di metano.