1000 resultados para Sedimentos silto-argilosos


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Estuaries are environments prone to the input of chemical pollutants of various kinds and origins, including polycyclic aromatic hydrocarbons (PAHs). Anthropogenic PAHs may have two possible sources: pyrolytic (with four or more aromatic rings and low degree of alkylation) and petrogenic (with two and three aromatic rings and high degree of alkylation). This study aimed to evaluate the levels, distribution and possible sources of polycyclic aromatic hydrocarbons in the estuary of the Potengi river, Natal, Brazil. Samples of bottom sediments were collected in the final 12 km of the estuary until its mouth to the sea, where the urbanization of the Great Natal is more concentrated. Sampling was performed on 12 cross sections, with three stations each, totaling 36 samples, identified as T1 to T36. The non alkylated and alkylated PAHs were analyzed by gas chromatography coupled to mass spectrometry (GC / MS). PAHs were detected in all 36 stations with total concentration on each varying 174-109407 ng g-1. These values are comparable to those of several estuarine regions worldwide with high anthropogenic influence, suggesting the record of diffuse contamination installed in the estuary. PAHs profiles were similar for most stations. In 32 of the 36 stations, low molecular weight PAHs (with 2 and 3 ring: naphthalene, phenanthrene and their alkylated homologues) prevailed, which ranged from 54% to 100% of the total PAH, indicating that leaks, spills and combustion fuels are the dominant source of PAH pollution in the estuary. The level of contamination by PAHs in most stations suggests that there is potential risk of occasional adverse biological effects, but in some stations adverse impacts on the biota may occur frequently. The diagnostic ratios could differentiate sources of PAHs in sediments of the estuary, which were divided into three groups: petrogenic, pyrolytic and mixing of sources. The urban concentration of the Great Natal and the various industrial activities associated with it can be blamed as potential sources of PAHs in bottom sediments of the estuary studied. The data presented highlight the need to control the causes of existing pollution in the estuary

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The Potengi river estuary is located in the region of Natal (RN, Brazil), comprising a population of approximately 1,000,000 inhabitants. Besides the dominant urban presence, the estuary has fragments of mangrove forest. The objective of this study is to determine the aliphatic hydrocarbons found in the bottom sediments of this estuary, identifying their levels, distribution and their possible origins through the diagnostic rates, indexes and results comparisons with the local anthropic and natural characteristics. The samples were obtained according to a plan that allowed sampling of the estuary up to 12 km upstream from it as mounth. 36 stations were selected, grouped into 12 cross sections through the course of the river and spaced on average by 1 km. Each section consisted of three stations: the right margin, the deepest point and the left margin. The hydrocarbon n-alkanes from C10 to C36, the isoprenoids pristane and phytane, the unresolved complex mixture (UCM) and the total resolved hydrocarbons were analyzed by gas chromatography. N-alkanes, pristane, phytane and UCM were detected only at some stations. In the other, the concentration was below the detection limit defined by the analytical method (0.1 mg / kg), preventing them from being analyzed to determine the origin of the material found. By using different parameters, the results show that the estuary receives both the input of petrogenic hydrocarbons, but also of biogenic hydrocarbons, featuring a mixture of sources and relatively impacted portions. Based on the characteristics and activities found in the region, it is possible to affirm that petrogenic sources related to oil products enter the estuary via urban runoff or boats traffic, boat washing and fueling. Turning to the biogenic source, the predominant origin was terrestrial, characterized by vascular plants, indicating contribution of mangrove vegetation. It was evident the presence of, at specific points in the estuary, hydrocarbon pollution, and, therefore is recommended the adoption of actions aimed at interrupting or, at least, mitigating the sources potentially capable of damp petrogenic hydrocarbons in the estuary studied.

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This Thesis presents the elaboration of a methodological propose for the development of an intelligent system, able to automatically achieve the effective porosity, in sedimentary layers, from a data bank built with information from the Ground Penetrating Radar GPR. The intelligent system was built to model the relation between the porosity (response variable) and the electromagnetic attribute from the GPR (explicative variables). Using it, the porosity was estimated using the artificial neural network (Multilayer Perceptron MLP) and the multiple linear regression. The data from the response variable and from the explicative variables were achieved in laboratory and in GPR surveys outlined in controlled sites, on site and in laboratory. The proposed intelligent system has the capacity of estimating the porosity from any available data bank, which has the same variables used in this Thesis. The architecture of the neural network used can be modified according to the existing necessity, adapting to the available data bank. The use of the multiple linear regression model allowed the identification and quantification of the influence (level of effect) from each explicative variable in the estimation of the porosity. The proposed methodology can revolutionize the use of the GPR, not only for the imaging of the sedimentary geometry and faces, but mainly for the automatically achievement of the porosity one of the most important parameters for the characterization of reservoir rocks (from petroleum or water)

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Las condiciones oceanográficas y geoquímicas asociadas al azufre inorgánico fueron estudiadas en la bahía de Paracas para determinar su impacto en los procesos de sulfato-reducción, el intercambio de sulfuro de hidrógeno en la interfaz agua-sedimento y su movilización hacia la fracción precipitada. Se establecieron tres estaciones de muestreo al interior de la bahía entre abril y junio de 2015. La variación espacio-temporal de las especies de azufre inorgánico disuelto (H2S y SO4-2) y precipitado (Acid Volatile Sulfide AVS y Chromium-Reducible Sulfur CRS) se analizaron en relación a los factores ambientales: velocidad de vientos, oxígeno disuelto, temperatura, pH e indicadores de materia orgánica fresca (Cl-a) y de preservación de materia orgánica (COT y NT), así como azufre total (ST). A partir de los análisis de correlación cruzada, se infiere que en las estaciones más profundas hay una mayor correlación entre el oxígeno disuelto y la temperatura que en la estación somera, la correlación de estas variables con la velocidad de viento no fue significativa (p>0.05). Las aguas de fondo en la bahía muestran alternancia entre condiciones hipóxicas (<1,43 mL/L) y micróxicas (<0.10 mL/L) durante otoño con períodos prolongados y con máximas concentraciones de H2S (4,966.76 uM) en los primeros 20 cm del sedimento. El análisis de componentes principales sugiere condiciones más favorables para la sulfato reducción en abril y una mayor oxigenación en junio, a pesar de esto hay una tendencia de incremento de AVS y CRS hacia junio, posiblemente como una respuesta en desfase de las condiciones iniciales, ocasionando una mayor precipitación de monosulfuros de hierro y pirita hacia junio. A pesar de esta precipitación significativa de azufreexisten importantes flujos difusivos de H2S (en promedio de 574.76 μmol.m².d-1), colocando a la bahía de Paracas bajo un escenario de fuente de H2S, que podría alcanzar una condición más severa (2824.94 μmol.m².d-1) durante un evento de aguas blancas.

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This study aims to evaluate the contribution of no-till (SD) and cover crops (CC) in mitigating the risk of salinity / sodicity of the soil. We tested whether the increase of soil infiltration rate and the reduction of the direct evaporation, achieved with a high amount of residues on the soil surface from the CC followed by SD, would enable a smaller accumulation of salts during the summer and more leaching of salt during winter. The experiment The experiment included two tillage systems: no-till associated to a winter cover crop (SD / CC) and the conventional system (SC) (chisel and disc harrows), divided into two water regimes and two levels of water salinity (0.7 dS m-1 and 2.0 dS m-1), both with adsorption sodium ratio 3. Contrary to expectations CC showed a tendency to increase salt content in Fall-Winter period, due to the reduction of the fraction available to leaching, but showed advantages in reducing long term salt content due to the improved structure of the B horizon, because decreases the tendency to the reduction of the structure of this horizon, caused typically by the permanent high moisture content during.

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Introdução Caracterização da área de estudo Materiais e métodos O modelo SWAT Dados de chuva, vazão e produção de sedimentos Tipos de solos e determinação dos parâmetros do SWAT Análises Estatísticas Cenários de Uso do Solo Resultados e discussões Estimativa da Vazão Estimativa da produção de sedimentos Modelagem Hidrossedimentológica em Diferentes Cenários Conclusões Referências bibliográficas RESUMO – A erosão dos solos é um dos mais graves problemas ambientais em todo o mundo, principalmente em regiões semiáridas que sofrem com a variabilidade espaço-temporal da precipitação. Este artigo analisou os processos hidrossedimentológicos na Bacia do Rio Cobres, localizada na porção semiárida de Portugal, utilizando o modelo SWAT. Neste estudo foram utilizados dados diários de precipitação, temperatura, umidade do ar, vazão e produção de sedimentos, para o período de 1960 a 2000, mapas digitais de elevação do terreno com resolução espacial de 90 m, uso e ocupação do solo e tipos de solo da bacia. Os resultados demonstraram a eficácia do modelo na calibração da vazão, com Coeficiente de Determinação (R²) = 0,81 e Coeficiente de Nash-Sutcliffe (NS) = 0,63, e também para produção de sedimentos com R² = 0,62 e NS = 0,47. O Cenário 3 (Mata) apresentou o maior decréscimo na vazão média, em relação aos Cenários 1 (Real) e 2 (Pastagem). Conclui-se que o modelo SWAT acoplado ao SIG é uma ferramenta poderosa na análise espaço-temporal do comportamento dos processos hidrossedimentológicos. Palavas-chave: SIG, modelo hidrossedimentológico, erosão ABSTRACT – Effects of Scenarios of Land Use on Runoff and Sediment Yield for Cobres River Basin, Portugal. Soil erosion is a major environmental problem worldwide, mainly in semiarid regions that suffer with rainfall spatial and temporal variability. Thus, this paper analysed the runoff-erosion process at the Cobres River Basin, located in semiarid portion of Portugal, using the SWAT model. In this paper, rainfall, temperature and humidity data from 1960 to 2000, and digital maps of land cover, terrain digital elevation model with spatial resolution of 90 m, soil types were used. The results showed the effectiveness of the model for the runoff calibration, with R² = 0.81 and NS = 0.63, and also for sediment yield with R² = 0.62 and NS = 0.47. Scenario 1 (Forest) had the highest decrease in average streamflow, in relation to the Scenarios 1 (Real) and 2 (Pasture) scenarios. It is concluded that the SWAT model coupled to GIS is a powerful tool in the analysis of temporal and spatial behaviour of runoff-erosion processes.

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Sedimentos de mangue contaminados ou não com produtos derivados do petróleo foram avaliados quanto à atividade microbiana e enzimática. Os maiores valores de C da biomassa microbiana foram obtidos nas áreas mais próximas ao mar, independentemente da contaminação. Os valores obtidos foram, em média, 73% maiores do que o observado para a área mais longe do mar. Os sedimentos da área contaminada não apresentaram menores valores de Cmic/Corg e nem maiores valores de qCO2 o que demonstra o desenvolvimento de uma população de microrganismos bem adaptada às condições reinantes. É interessante que trabalhos posteriores estudem a diversidade destes microrganismos e o possível impacto que estas mudanças poderiam causar no caso de se adotar estratégias para recuperação desta área.

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A respeito do abastecimento de água as discussões e preocupações se intensificam ao longo dos anos, pois a construção de represas para fins de abastecimento, além de alterar o percurso de muitos cursos de água também desperta a atenção para a deposição de sedimentos que ocorre no fundo dos lagos, visto que os sedimentos podem comprometer a vida útil da represa. As principais causas de produção e deposição de sedimentos estão relacionadas diretamente a geomorfologia, associada ao índice de precipitação, ao tipo de cobertura vegetal e o uso do solo. No caso da bacia hidrográfica do rio Pitangui, a exposição dos solos para práticas agrícolas, exploração agropecuária e a presença de algumas moradias, relacionadas à movimentação de terra, permitem que surjam processos erosivos e consequentemente o assoreamento da Represa dos Alagados. Sendo assim, esta pesquisa tem por objetivo caracterizar geomorfológicamente a bacia hidrográfica do rio Pitangui, identificando quais os processos e agentes que contribuem para a produção de sedimentos que são depositados na Represa dos Alagados.

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This paper presents the behavior of three bored piles conducted in diabasic soil submitted to uplift forces. The piles were built at the site for Experimental Studies in Soil Mechanics and Foundations of UNICAMP, located in the city of Campinas, Brazil. Field tests have already been conducted at the site (SPT, CPT, DMT and PMT), as well as laboratory tests by using sample soils taken from a well up to 17 m deep. The water table is not checked until a depth of 17 m. In order to check the behavior of the piles when submitted to uplift forces, slow static load tests were carried out as the recommendations of NBR 12131. The carrying capacity of these piles was also provided by means of theoretical methods, appropriate for uplift forces, and through semi-empirical methods appropriate for compression forces, considering only the portion of lateral resistance. The values estimated by using the considered methods were compared to those obtained by means of load tests. One of the tested piles was extracted from the soil to be the subject of a study on its geometry.

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The Pantanal of Nhecolândia, the world's largest and most diversified field of tropical lakes, comprises approximately 10,000 lakes, which cover an area of 24,000 km² and vary greatly in salinity, pH, alkalinity, colour, physiography and biological activity. The hyposaline lakes have variable pHs, low alkalinity, macrophytes and low phytoplankton densities. The saline lakes have pHs above 9 or 10, high alkalinity, a high density of phytoplankton and sand beaches. The cause of the diversity of these lakes has been an open question, which we have addressed in our research. Here we propose a hybrid process, both geochemical and biological, as the main cause, including (1) a climate with an important water deficit and poverty in Ca2+ in both superficial and phreatic waters; and (2) an elevation of pH during cyanobacteria blooms. These two aspects destabilise the general tendency of Earth's surface waters towards a neutral pH. This imbalance results in an increase in the pH and dissolution of previously precipitated amorphous silica and quartzose sand. During extreme droughts, amorphous silica precipitates in the inter-granular spaces of the lake bottom sediment, increasing the isolation of the lake from the phreatic level. This paper discusses this biogeochemical problem in the light of physicochemical, chemical, altimetric and phytoplankton data.

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Absolute dating methods have been used in chronological studies of geological processes and sedimentary units of Quaternary age in Central Amazonia, Brazil. Although radiocarbon dating has been very useful in archaeological research and soil studies, the temporal interval of this method is inefficient in evaluating the sedimentation aspects and geological events from the beginning of the Quaternary in the Amazon basin. The use of crystal luminescence dating has been one of the most promising tool for determining the absolute dating of Quaternary deposits in the Amazonian region. Optically stimulated luminescence (OSL) dating, following the MAR and SAR protocols, in a tectonic-sedimentary study of Quaternary fluvial deposits in the confluence area of the Negro and Solimões rivers, indicated ages from 1.3 (Holocene) to about 67.4 kyears (Late Pleistocene) for these sediments. Low radioactive isotope concentrations were found about 2ppm for 235U and 238U; 5ppm for 232Th; and the 40K concentrations were almost zero. A comparison was made between MAR and SAR protocols taking into account the fluvial depositional process.

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This work presents a study of selected outcrops from the Pedra das Torrinhas Formation of the Guaritas Group (Cambrian, Camaquã Basin), near the basin bordering Encantadas Fault Zone. The studied succession includes alluvial fan deposits that pass laterally into eolian deposits. Sedimentary facies and architectural element analysis were performed, followed by sedimentary petrography and microscopic porosity analysis, aiming to characterize the porosity of the deposits and its spatial distribution. The main objective was to contribute to a better understanding of the porosity spatial distribution in depositional systems characterized by the interaction between alluvial and eolian processes, with special reference to deposits formed prior to the development of terrestrial plants. Porosity values are related to depositional processes, with higher porosities associated to eolian dune deposits (mean of 8.4%), and lower porosity related to interdunes (mean of 3.4%) and alluvial fans (mean of 4.3%). Architectural elements analysis revealed the spatial relationships of these deposits, a response to the interplay of the eolian and alluvial processes. The integration of porosity data reveals that the interaction of alluvial and eolian processes results in heterogeneous distribution of porosity at the facies association scale. Eolian reworking of alluvial facies increases porosity whereas sheet-flood and other alluvial processes in the interdune areas reduce porosity.