黄绵土不同形态有机氮径流流失规律

利用不同坡度径流小区 ,在自然降水条件下 ,研究侵蚀泥沙不同形态有机氮的流失规律 ,结果表明 :在 4次产流泥沙中 ,除氨基糖氮含量减少外 ,其它有机形态氮均存在增加趋势 ,以氨态氮含量增加最为显著。随坡度的下降 ,水解全氮、氨态氮和氨基酸氮含量呈增加趋势 ;泥沙中水解全氮、氨基酸氮、氨态氮、非酸水解氮均存在不同程度的富集 ,其富集率随坡度的下降而增大 ,以氨基酸氮富集程度高 ,泥沙中氨基糖态氮反而无富集现象存在 ;当坡度分别为 2 5°、2 0°、15°、10°和 5°时 ,水解全氮流失量分别为 1135 .0、76 3.7、485 .5、313.0和 15 4.4kg/ km2 ,而氨基酸氮流失量则为 2 34.8、182 .7、12 1.1、76 .8和 33.9kg/ km2 ,占水解全氮的 2 0 .6 %～ 2 4.9%。氨态氮流失量为 742 .5、5 0 3.3、32 2 .2、2 0 8.9、97.4kg/ km2 ,占水解全氮的 6 3.1%～ 6 6 .7%。氨基糖氮占酸水解氮 1.1%～ 2 .9%。非鉴别氮占水解全氮的 5 .8%～ 12 .6 %。而酸水解氮与非酸水解氮之比分别为 ...

盘锦地区湿地生态系统服务功能价值估算

随着湿地研究的展开和深入 ,湿地生态系统的服务功能价值越来越受到人们的重视。以辽河三角洲盘锦地区湿地为例 ,结合地理信息系统和野外调查及实验 ,综合运用环境经济学、资源经济学、模糊数学等研究方法 ,对该地区的湿地生态系统的服务功能进行了价值评估 ,得到该地区湿地生态系统的服务功能价值为 62 .1 3亿元 ,是该地区国民生产总值的 1 .2倍。并根据估算结果 ,讨论了不同方法在估算过程中存在的优缺点

A new oxidation state of aniline pentamer observed in water-soluble electroactive oligoaniline-chitosan polymer

A novel water-soluble electroactive polymer, aniline pentamer crosslinked chitosan (Pentamer-c-Chi), was prepared by condensation polymerization of the terminal carboxyl groups in aniline pentamer with the amino side groups in chitosan in aqueous solution. The carboxyl groups were activated by N-hydroxysuccinimide (NHS) and N,N'-dicyclohexylcarbodiimide (I)CC). The electrochemical behavior of aniline pentamer in this kind of crosslinked polymer was studied in acidic aqueous solution by means of cyclic voltammetry (CV), UV-vis, and electron spin resonance (ESR) spectroscopy.

Synthesis and enhancement of quantum efficiency of a series of novel PPV derivative copolymers

A series of novel PPV derivative copolymers with good solubility in common organic solvents were synthesized. The emitting color of these copolymers could range from red to blue by adjusting the structures and the compositions of monomers. Investigation on their optical properties showed that the PL quantum efficiency could be increased by energy transfer and conjugation reduction. The PL quantum efficiency of most green/blue copolymer films on slide glass was higher than 80%.

Novel polyaryletherketones containing various pendant groups .1. Synthesis and characterization

Novel high glass transition temperature polyaryletherketones, containing pendant amido, alkyl, and carboxyl groups with reduced viscosity above 0.54 dL/g, were synthesized via solution nucleophilic polycondensation reaction of phenolphthalin, 2',2 ''-diisopropyl-5',5 ''-dimethylphenolphthalin, and 3,3'-bis(4-hydroxyphenyl)isobenzopyrrolidone with bis(4-nitrophenyl)ketone in the presence of potassium carbonate. By ion exchange with Na+ and K+, four ionomers were also prepared. A new monomer simultaneously containing carboxyl and algyl substituents was synthesized by reduction reaction of 2',2 ''-diisopropyl-5',5 ''-dimethyl-phenolphthalein. The resulting polymers were soluble in a few polar aprotic solvents; transparent, colorless, and tough films could easily be cast from DMF or DMSO solution. The mechanical properties of the films were excellent; and their tensile strength, elongation at break, and tensile moduli were in the range of 67.1-97.1 MPa, 7.8-165%, and 1.47-2.27 GPa, respectively. The prepared polymers showed fairly good thermal stability and resonably high glass transition temperatures above 210 degrees C. (C) 1997 John Wiley & Sons, Inc.

氢化物发生石墨炉原子吸收光谱法直接测定高温镍基合金中的硒

在6mol/L盐酸介质和0.1％KBH_4条件下,不但能有效地发生硒的氢化物,而且5mg/ml Ni和3mg/ml Fe都不干扰硒的测定。利用涂钯石墨管作为氢化物的原于化器,直接测定了高温镍基合金中的硒,特征质量为40pg,相对标准偏差在6.1％以内,回收率在97％～110％之间。

SYNTHESIS, PROPERTIES AND MOLECULAR-STRUCTURE OF 5-COORDINATE N,N-DIBENZYLDITHIOCARBAMATE COMPLEXES OF TITANOCENE, ZIRCONOCENE AND HAFNOCENE

The five complexes (RC5H4)2M(S2CNBz2)Cl (R = H, CH3; M = Ti, Zr, Hf; Bz = CH2C6H5) have been prepared by the reaction of (RC5H4)2MCl2 with anhydrous sodium salts of dibenzyldithiocarbamate in refluxing CH2Cl2. These complexes have been characterized by elemental analysis, IR and H-1 NMR. X-ray crystal structure determination of Cp2Zr(S2CNBZ2)Cl shows the molecule has a five-coordinate bent metallocene geometry in which the zirconium atom is attached to two eta-5-C5H5 groups, one bidentate dibenzyldithiocarbamate ligand and one chlorine [Zr-Cl, 2.549(1) angstrom; Zr-S, 2.734(1), 2.667(1); Cl-Zr-S, 137.6(1)-degrees and 73.3(1)-degrees; S-Zr-S, 64.3(1)-degrees]. The catalytic system Cp2Ti (S2CNBZ2)Cl-NaH exhibits high initial catalytic activity of hydrogenation of hexene-1 under mild conditions.

银溶胶的形成及在光度分析中的作用

氢化物与硝酸银反应形成银溶胶的分光光度法,具有操作简便、分析速度快、灵敏度高和应用范围广等特点,深入探讨银溶胶的物理和化学性质对改进此方法的实验条件,增强银溶胶的稳定性和改善方法的重现性,以及提高方法的灵敏度和选择性等都有重要的意义,我们以铅烷与硝酸银的反应产物为研究对象,用X光小角散射仪、透射电子显微镜和光

青藏高原东部生态系统土壤碳排放

在青藏高原探讨不同生态系统碳平衡规律及其影响因子并揭示其对全球含碳温室气体变化的影响与响应 ,有重要的现实意义和理论价值。分别在海北高寒草甸生态站、贡嘎山森林生态站和拉萨农业生态站用静态箱法进行了土壤CO2 排放的试验研究。土壤CO2 排放速率日平均值为草甸215.87～329.68mgCO2m -2h -1 ,森林713.72～2102.56mgCO2m -2h -1 ,农田913.05～1135.83mgCO2m -2h-1。土壤碳排放速率日变化 ,在农田和高寒草甸区表现为单峰型 ,均以地方时8∶00～16∶00最高 ,0∶00～8∶00最低。草甸、农田土壤碳排放随着牧草、作物生长发育的加速而逐渐增加 ,越接近成熟 (或枯黄期 )其值越低 ,林区以6～9月的生长旺季为最高。土壤碳排放与温度之间有较好的相关性 ,温度是影响土壤碳排放的重要因子，全球变暖有可能引起高原土壤碳排放的增加。

喉毛花的胚胎学研究

本文首次系统地记载了喉毛花属的胚胎发育过程,并以此为依据讨论了该属的分类等级和系统位置。喉毛花花药四室;药壁发育属双子叶型;绒毡层单型起源,细胞具单核,属腺质绒毡层;一层中层细胞;花药壁表皮层宿存,纤维状加厚和膨大;药室内壁减缩。小孢子母细胞减数分裂为同时型,四分体的排列为四面体型;成熟花粉为3-细胞型。子房为2心皮、1室,典型的侧膜胎座,胚珠8列,胚珠胎座靠近两心皮腹缝线。薄珠心,单珠被,倒生胚珠。大孢子母细胞减数分裂形成的4个大孢子呈直列式排列,其中合点端的大孢子具功能。胚囊发育为蓼型。极核在受精前融合为次生核。反足细胞宿存、分裂为8～12个,每个细胞均多核和异常膨大,反足细胞形成的吸器明显。异花传粉,珠孔受精。花粉管通过破坏一助细胞进入胚囊。受精作用属于有丝分裂前配子体融合类型。胚乳发育为核型,每核含2～3核仁。胚胎发育为茄型酸浆Ⅰ变型,成熟种子胚只发育至球形胚阶段。反足细胞在合子分裂之后才开始退化,在胚的发育过程中反足细胞在胚乳层之外形成一层染色深、类似“外胚乳”的结构。比较喉毛花、龙胆属、假龙胆属以及肋柱花属的胚胎学特征表明喉毛花与假龙胆属的亲缘关系最近，在分类等级上作为一个独立的属较为合适，在系统位置上它比假龙胆属更为原始。

自动化制造系统的产生与发展

探讨了自动化与制造业的产生和互促发展过程 ,论述了自动化制造系统的形成和不同发展阶段的内涵及重大作用 ,指出自动化技术与制造技术是驱动自动化制造系统发展的两个轮子 ,不能忽视任何一个侧面 ,自动化研究与制造技术研究相结合是发展先进制造技术的必由之路

Taking advantage of an old concept, "illegitimate transcription", for a proposed novel method of genetic diagnosis of McArdle disease

McArdle disease is a metabolic disorder caused by pathogenic mutations in the PYGM gene. Timely diagnosis can sometimes be difficult with direct genomic analysis, which requires additional studies of cDNA from muscle transcripts. Although the "nonsense-mediated mRNA decay" (NMD) eliminates tissue-specific aberrant transcripts, there is some residual transcription of tissue-specific genes in virtually all cells, such as peripheral blood mononuclear cells (PBMCs).We studied a subset of the main types of PYGM mutations (deletions, missense, nonsense, silent, or splicing mutations) in cDNA from easily accessible cells (PBMCs) in 12 McArdle patients.Analysis of cDNA from PBMCs allowed detection of all mutations. Importantly, the effects of mutations with unknown pathogenicity (silent and splicing mutations) were characterized in PBMCs. Because the NMD mechanism does not seem to operate in nonspecific cells, PBMCs were more suitable than muscle biopsies for detecting the pathogenicity of some PYGM mutations, notably the silent mutation c.645G>A (p.K215=), whose effect in the splicing of intron 6 was unnoticed in previous muscle transcriptomic studies.We propose considering the use of PBMCs for detecting mutations that are thought to cause McArdle disease, particularly for studying their actual pathogenicity.

Telev?rit? Hits Britain: Documentary, Drama and the Growth of 16mm Filmmaking in British Television

Sexton, J. (2003). Telev?rit? Hits Britain: Documentary, Drama and the Growth of 16mm Filmmaking in British Television. Screen. 44(4), pp.429-444. RAE2008