科尔沁沙地小叶锦鸡儿群落保育土壤作用的研究

以流动沙丘和不同恢复年限的人工和天然小叶锦鸡儿群落为研究对象,从植被重建前后土壤理化性质变化方面分析了小叶锦鸡儿群落保育土壤的作用。结果表明,6 a生、11 a生和22 a生人工小叶锦鸡儿群落对土壤理化性质均有明显的改善作用,且总体上土壤改良效果与恢复年限成正相关。建立人工植被后,土壤中微沙(0.05~0.1 mm)和黏粒(<0.05 mm)的含量增加,表层(0—10 cm)土壤容重减小,孔隙度和饱和含水率增大,土壤持水能力提高;土壤有机碳、全氮、碱解氮、全磷、有效磷和有效钾含量均有不同程度增加,尤以表层增加幅度最大,并且灌丛对养分有明显的富集效应。

黄土丘陵区植被恢复中不同粒级土壤团聚体有机碳分布特征

对黄土丘陵区土壤有机碳在不同粒级团聚体中的分布特征及其对植被恢复的响应进行了研究。结果表明:(1)黄土丘陵区不同植被覆盖条件下,土壤有机碳的分布具有一定的表聚性,0~20 cm土层中有机碳的含量均高于20~40 cm中有机碳的含量,不同植被群落下有机碳的含量大小为:大针茅群落>长芒草群落>铁杆蒿群落>百里香群落;(2)同一深度土壤各粒级团聚体中有机碳的分布特征是:0.5~0.25 mm与1~0.5 mm两个粒级中有机碳的含量最高,>1 mm的团聚体中有机碳的含量有随粒级增大而减小的趋势;(3)恢复年限对不同粒级土壤团聚体中有机碳的含量影响很大,有机碳的含量随恢复年限的增加总体呈上升趋势。黄土高原沟壑区土壤有机碳的积累与土壤团聚体的粒级和植被恢复的类型、年限等有明显的关系。

黄土高原半干旱区苜蓿草地土壤干燥化特征与粮草轮作土壤水分恢复效应

实地测定了黄土高原半干旱区固原不同生长年限苜蓿草地和连作8a苜蓿草地翻耕轮作不同年限粮食作物后深层土壤水分特征,分析了苜蓿草地土壤干燥化特征和粮草轮作对土壤水分的恢复效应。结果表明:(1)苜蓿连作1a、5a、8a和12a等4类苜蓿草地0~1000cm土层平均土壤湿度值为6.6%,平均土壤水分过耗量702.8mm,平均土壤干燥化速率147.1 mm/a,达到强烈干燥化程度,苜蓿连作5a土壤干层深度超过1000cm,苜蓿连作8a土壤干层深度超过1360cm,苜蓿草地合理利用年限为7a。(2)连作8a苜蓿草地翻耕并轮作4~7a和25a粮食作物等5类粮田0~1000cm土层土壤湿度介于6.74%~11.95%,土壤贮水量恢复值介于210.6~887.3mm,平均土壤水分恢复速率为80.8mm/a。轮作6a后粮田土壤干层轻度恢复程度以上深度达到1000cm。通过粮草轮作使苜蓿草地土壤湿度恢复到当地土壤稳定湿度需要13a以上。黄土高原半干旱区适宜的粮草轮作模式为:7a苜蓿→13a粮食作物。

黄土丘陵区土壤团聚体分形特征及其对植被恢复的响应

采用计算分形维数的方法,对黄土丘陵区典型草原带土壤团聚体的分形特征及其对植被恢复的响应进行研究。结果表明:1)在植被恢复初期,土壤>10 mm粒级的团聚体含量在0~20和20~40 cm层次均较高,含量为331.4~525.6 g/kg。随植被恢复年限增加,10~7、7~5、5~3、3~2、2~1 mm粒级的团聚体绝对含量下降差异不明显。1~0.5、0.5~0.25和<0.25 mm小粒级土壤团聚体含量,在植被恢复初期(7 a)较高。2)随着植被恢复年限增加,土壤>5 mm粒级的水稳性团聚体含量相对下降很快,恢复7 a之后,大粒级土壤团聚体表现为上层含量比下层含量低的趋势。相对于干筛结果而言,土壤水稳性团聚体的粒径分布更为均匀、稳定,恢复7 a之后的土壤>0.25mm团聚体含量占到40%~50%,而>5 mm的土壤团聚体则占10%~23%。植被恢复过程中,土壤团聚体由大的团块向小颗粒的土壤团聚体转换,粒径分布更为均匀,土壤结构逐渐改善。3)不同恢复年限土壤团聚体分形维数变化范围为表层2.75~2.86,表下层2.77~2.89,变化范围小,20~40 cm土层的分形维数大于0~20 cm,恢复植被可使土壤分形...

辽西地区水分亏缺与树木生长关系

利用修正的Thornthwaite最大蒸发力公式,计算了辽西地区不同市的水分亏缺量。各市最大潜在蒸发散计算结果是:朝阳1180.6 mm,锦州1146.0 mm,葫芦岛1140.1 mm,阜新1030.3 mm;水分亏缺量计算结果为:朝阳-658.3 mm,锦州-538.4 mill,葫芦岛-544.8 mm,阜新-626.9 mm。利用美国spss数理统计软件计算了油松与蒙古栎的胸径连年生长量和对应的各年1—12月份的月均温、月降雨量、平均相对湿度的回归关系,表明油松生长与温度紧密,蒙古栎生长与水分关系紧密。

紫花苜蓿和短花针茅根系分布与土壤水分研究

以陕北农牧交错带人工草种紫花苜蓿(Medicago sativa L.)和天然草种短花针茅(Stipa breviflora Griseb.)为对象,采用根钻法调查两个草种的根系垂直分布以及刈割后苜蓿根系变化特征,并通过定位观测研究土壤水分动态变化。结果表明:紫花苜蓿和短花针茅根系密度随土壤深度增加而减少,而且均以直径小于等于1 mm的须根为主;0~50 cm土层紫花苜蓿和短花针茅根系量分别占0~100 cm剖面总量的67%和84%。紫花苜蓿和短花针茅根系分布与土壤水分消耗特征吻合。生长旺盛期苜蓿大量消耗0~140 cm土层土壤水分,5-9月平均有效土壤储水不足10 mm;生长季末深层(140~280 cm)土壤储水也逐渐降低,约为裸地储水量的50%。短花针茅0~280cm剖面土壤水分状况明显好于苜蓿地,比苜蓿地多储水100 mm左右;主要消耗浅层(0~50 cm)土壤水分,深层水分利用较少。

土壤条件对PAHs紫外光降解影响及动力学研究

研究紫外照射条件下,土壤厚度对多环芳烃苯并[a]芘、芘光降解的影响及其动力学变化,以及土壤粒径对多环芳烃苯并[a]芘、芘和菲的光解的影响。结果表明,苯并[a]芘和芘的光降解速率与土壤厚度呈负相关,光解速率的顺序为1.0 mm>1.6 mm>2.0 mm>2.4 mm>4.0 mm,通过对实验数据的模拟土壤中苯并[a]芘和芘的光降解符合准一级动力模型;三种不同土壤粒径(分别小于1 mm、0.45 mm、0.25 mm)对多环芳烃苯并[a]芘、芘和菲的光降解有明显影响,在三种粒径范围内,PAHs的降解在小于1 mm土壤中最快,同一粒径中多环芳烃的降解速率:苯并[a]芘>芘>菲。

涡动相关法与波文比-能量平衡法测算森林蒸散的比较研究——以长白山阔叶红松林为例

分别采用涡动相关法与波文比-能量平衡法(BREB法)测算了长白山阔叶红松林2002年9、10月的森林蒸散量。结果表明,9月,涡动相关法与BREB法测算的森林蒸散量分别为83.1和87.9 mm,后者相对于前者的误差不到6%,且两者日蒸散量有较好的相关性(0.78),表明涡动相关法与BREB法在森林蒸散研究中有很好的一致性。10月,随着秋季落叶,林内水汽压梯度减小。涡动相关法测算的森林蒸散量为42.5 mm,BREB法测算的结果为49.1 mm,后者相对于前者的误差达到了16%,两者日蒸散量相关系数为0.53。在水汽压梯度较小时,BREB法会产生较大误差。9月中上旬,森林主要热量消耗是用于蒸散,约占辐射平衡量的71%;落叶后,森林主要热量消耗变为森林-大气间的感热交换,蒸散耗热只占辐射平衡量的40%。

Highly efficient electrochemiluminescence of functionalized tris(2,2 '-bipyridyl)ruthenium(II) enrichment of its co-reactants

An enhanced electrochemiluminescence (ECL) efficiency is obtained from the ruthenium complex tris(2,2'-bipyridyl)ruthenium(II) (Ru(bpy)(3)(2+)) by introduction of an ionic liquid (IL) 1-butyl-3-methylimidazolium tetrafluoroborate (BMImBF(4)). Upon addition of 1% (v/v) BMImBF(4) to 0.1 mm Ru(bpy)(3)(2+) solution, a maximum increase in ECL intensity is obtained both at an indium tin oxide (ITO) electrode (15-fold) and at a glassy carbon (GC) electrode (5- to 64old). Furthermore, upon addition of 1% (v/v) BMImBF4 to 5 pm Ru(bpy)(3)(2+)/100 mm co-reactant systems at a GC electrode, IL adsorption occurs at the electrode surface, which results in a change of the polarity of the electrode surface. Such functionalization greatly improves the functions of both Ru(bpy)(3)(2+) and ionic liquids, as is demonstrated in the sensitive and selective concentration enrichment of the Ru(bpy)(3)(2+) co-reactants.

Mn(II)-monosubstituted polyoxometalates as candidates for contrast agents in magnetic resonance imaging

Two mono-substituted manganese polyoxometalates, K6MnSiW11O39 (MnSiW11) and K8MnP2W17O61 (MnP2W17), have been evaluated by in vivo and in vitro experiments as the candidates of potential tissue-specific contrast agents for magnetic resonance imaging (MRI). T-1-relaxivities of 12.1 mM(-1) s(-1) for MnSiW11 and 4.7 mM(-1) s(-1) for MnP2W17 (400 MHz, 25 degrees C) were higher than or similar to that of the commercial MRI contrast agent (GdDTPA). Their relaxivities in BSA and hTf solutions were also reported. After administration of MnSiW11 and MnP2W17 to Wistar rats, MR imaging showed longer and remarkable enhancement in rat liver and favorable renal excretion capability. The signal intensity increased by 74.0 +/- 4.9% for the liver during the whole imaging period (90 min) and by 67.2 +/- 5.3% for kidney within 20-70 min after injection at 40 +/- 3 mu mol kg(-1) dose for MnSiW11. MnP2W17 induced 71.5 +/- 15.1%. enhancement for the liver in 10-45 min range and 73.1 +/- 3.2% enhancement for kidney within 5-40 min after injection at 39 +/- 3 mu mol kg(-1) dose. In vitro and in vivo study showed MnSiW11 and MnP2W17 being favorable candidates as the tissue-specific contrast agents for MRI.

Direct electrochemical detection of glucose in human plasma on capillary electrophoresis microchips

We developed an electrochemical detector on a hybrid chip for the determination of glucose in human plasma. The microchip system described in this paper consists of a poly(dimethylsiloxane) (PDMS) layer containing separation and injection channels and an electrode plate. The copper microelectrode is fabricated by selective electroless deposition. The fabrication of the decoupler is performed by platinum electrochemical deposition on the metal film formed by electroless deposition. Factors influencing the performance, including detection potential, separation field strength, and buffer concentration, were studied. The electrodes exhibited good stability and durability in the analytical procedures. Under optimized detection conditions, glucose responded linearly from 10 muM to 1 mM. Finally, glucose in human plasma from three healthy individuals and two diabetics was successfully determined, giving a good prospect for a new clinical diagnostic instrument.

Assemble of poly(aniline-co-o-aminobenzenesulfonic acid) three-dimensional tubal net-works onto ITO electrode and its application for the direct electrochemistry and electrocatalytic behavior of cytochrome c

Stable electroactive film of poly(aniline-co-o-aminobenzenesulfonic acid) three-dimensional tubal net-works was assembled on indium oxide glass (ITO) successfully, and the cytochrome c was immobilized on the matrix by the electrostatic interactions. The adsorbed cytochrome c showed a good electrochemical activity with a pair of well-defined redox waves in pH 6.2 phosphate buffer solution, and the adsorbed protein showed more faster electron transfer rate (12.9 s(-1)) on the net-works matrix than those of on inorganic porous or even nano-materials reported recently. The immobilized cytochrome c exhibited a good electrocatalytic activity and amperometric response (2 s) for the reduction of hydrogen peroxide (H2O2). The detection limit for H2O2 was 1.5 mu M, and the linear range was from 3 mu M to 1 mM. Poly(aniline-co-o-aminobenzenesulfonic acid) three-dimensional tubal net-works was proved to be a good matrix for protein immobilization and biosensor preparation.

A novel flow through optical fiber biosensor for glucose based on luminol electrochemiluminescence

A novel flow injection optical fiber biosensor for glucose based on luminol electrochemiluminescence (ECL) is presented. The sol-gel method is introduced to immobilize glucose oxidase (GOD) on the surface of a glassy carbon electrode. After optimization of the working conditions, glucose could be quantitated in the concentration ranges between 50 muM and 10 mM with a detection limit of around 26 muM. Signal reproducibility was about 3.62% relative standard deviation for 11 replicated measurements of 0.1 mM glucose. The ECL biosensor also showed good selectivity and operational stability. The proposed method can be applied to determination of glucose in soft drink samples.

Electrochemical synthesis of polyaniline nanoparticles

Polyaniline nanoparticles were prepared on a highly oriented pyrolytic graphite (HOPG) surface from dilute polyaniline acidic solution (1 mM aniline + 1 M HClO4) using a pulsed potentiostatic method. Electrochemistry, Fourier transform infrared external reflection spectroscopy (FT-IR-ERS), X-ray photoelectron spectroscopy (XPS) and tapping-mode atomic force microscopy (TMAFM) were: used to characterize the composition and structure of the polyaniline nanoparticles. FT-IR-ERS and XPS results revealed that the polyaniline was in its emeraldine form. TMAFM measurement showed that the electropolymerized polyaniline nanoparticles dispersed on the:HOPG surface with a coverage of about 10(10) cm(-2). These nanoparticles were disk-shaped having a height of 10(-30) Angstrom and an apparent diameter varying from 200 to 600 Angstrom. The particle dimensions increased with the electropolymerization charge (Q) over the interval from 5.7 to 19.3 mu C cm(-2) (C) 2000 Elsevier Science S.A. All rights reserved.

Simultaneous determination of both the calibration constant in an electrochemical quartz crystal microbalance and the active surface area of a polycrystalline gold electrode

A novel method is employed for the simultaneous determination of both the calibration constant of an electrochemical quartz crystal microbalance (EQCM) and the active surface area of a polycrystalline gold electrode. A gold electrode: is immersed into a 1 mM KI/1 M H2SO4 solution and on which forms a neutral monolayer. The adsorbed iodine can then be completely oxidized into IO3-. The active surface area of a gold electrode can be obtained from the net electrolytic charge of the oxidation process, and the calibration constant in the EQCM can be calculated from the corresponding frequency shift. The result shows that this method is simple, convenient and valid. (C) 2000 Elsevier Science S.A. All rights reserved.